Fabrication and Characterization of SiC-Coated Multi-Walled Carbon Nanotubes Reinforced Reaction Bonded SiC Composite

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SiC-coated multi-walled carbon nanotubes (SiC-coated MWNTs) made by RF magnetron sputtering were introduced into the SiC suspensions to enhance the mechanical behaviors of reaction bonded silicon carbide ceramics. The composites were prepared by the epoxy resin curing and liquid silicon infiltration at 1550°Cfor 60min. The distribution, morphology, and reinforcing behaviors of MWNTs were investigated. X-ray diffraction (XRD) reveals that the MWNTs were reserved during the reaction sintering. The flexural strength and fracture toughness increase with MWNTs ranging from 0wt% to 0.5wt%, reaching the peaks value of 347MPa and 4.3MPam1/2 respectively at the MWNTs fraction of 0.5 wt%. This improvement derives from the MWNTs pullout. The consequent decline at MWNTs fraction of 1wt% is resulted from the corrosion of agglomerated MWNTs and the increase of residual silicon.

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176-180

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June 2014

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© 2014 Trans Tech Publications Ltd. All Rights Reserved

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[1] Q. W. Huang, L. H. Zhu, High-temperature strength and toughness behaviors for reaction-bonded SiC ceramics below1400 ℃, Mater. Lett. 59 (2005) 1732–1735.

DOI: 10.1016/j.matlet.2005.01.049

Google Scholar

[2] M. Wilhelm, M. Kornfeld, W. Wruss, Development of SiC-Si composites with fine grained SiC microstructures, J. Eur. Ceram. Soc. 19 (1999) 2155-2163.

DOI: 10.1016/s0955-2219(99)00029-1

Google Scholar

[3] G. I. Babayants, A.G. Lanin, Thermal stress resistance and heat-induced damage of silicon carbide materials for laser mirrors, J. Eur. Ceram. Soc. 20 (2000) 1515–1520.

DOI: 10.1016/s0955-2219(00)00017-0

Google Scholar

[4] G. Amirthan, A. Udaya kumar, M. Balasubramanian, Thermal conductivity studies on Si/SiC ceramic composites, Ceram. Int. 37 (2011) 423–426.

DOI: 10.1016/j.ceramint.2010.09.003

Google Scholar

[5] S. Suyama, T. Kameda, Y. Itoh, Development of high-strength reaction-sintered silicon carbide, Diam. Relat. Mater. 12 (2003) 1201–1204.

DOI: 10.1016/s0925-9635(03)00066-9

Google Scholar

[6] S. Aroati, M. Cafri, H. Dilman, M.P. Dariel, N. Frage, Preparation of reaction bonded silicon carbide (RBSC) using boron carbide, J. Eur. Ceram. Soc. 31 (2011) 841–845.

DOI: 10.1016/j.jeurceramsoc.2010.11.032

Google Scholar

[7] R. Voytovych, V. Bougiouri, N.R. Calderon, J. Narciso, N. Eustathopoulos, Reactive infiltration of porous graphite by NiSi alloys, Acta Mater. 56 (2008) 2237–2246.

DOI: 10.1016/j.actamat.2008.01.011

Google Scholar

[8] A. Peigney , Ch. Laurent, E. Flahaut, A. Rousset, Carbon nanotubes in novel ceramic matrix nanocomposites, Ceram. Int. 26 (2000) 677-683.

DOI: 10.1016/s0272-8842(00)00004-3

Google Scholar

[9] Z. Xia, L. Riester, W. A. Curtin, Direct observation of toughening mechanisms on carbon nanotubes ceramic matrix composites, Acta Mater. 52 (2004) 931–944.

DOI: 10.1016/j.actamat.2003.10.050

Google Scholar

[10] A.R. Boccaccini, D.R. Acevedo, G. Brusatin, P. Colombo, Borosilicate glass matrix composites containing, J. Eur. Ceram. Soc. 25 (2005) 1515–1523.

DOI: 10.1016/j.jeurceramsoc.2004.05.015

Google Scholar

[11] J.L. Li , G.Z. Bai, J.W. Feng, W. Jiang, Microstructure and mechanical properties of hot-pressed carbon nanotubes compacted by spark plasma sintering, Carbon 43 (2005) 2649–2653.

DOI: 10.1016/j.carbon.2005.04.035

Google Scholar

[12] K. Hernadi, E. Ljubovic, J.W. Seo, L. Forro, Synthesis of MWNT-based composite materials with inorganic coating, Acta Mater. 51(2003) 1447-1452.

DOI: 10.1016/s1359-6454(02)00539-6

Google Scholar

[13] N Song, H Liu, Y. T. Yuan, X Li, J. Z. Fang, Fabrication and corrosion resistance of SiC-coated multi-walled carbon nanotubes, J. Mater. Sci. Thechol. 29 (2013) 1146-1150.

DOI: 10.1016/j.jmst.2013.10.006

Google Scholar

[14] X. H. Zhang, C. Q. Hong, J. C. Han, H. X. Zhang, S. H. Meng, W. Qu, Preparation and properties of titanium diboride ceramic matrix reinforced by carbon nanotubes, J. Inor. Mater. 21 (2006) 899-904.

Google Scholar