TiO2 Nanoparticle-Driven Morphological Modulation to Improve Series Resistance and Trap Energy in Phenosafranine Dye-Based Organic Devices

Article Preview

Abstract:

This study explores the effect of titanium dioxide (TiO₂) nanoparticles on the electrical performance of Phenosafranine (PSF) dye-based organic devices. Composite films were fabricated by blending PSF with TiO₂ nanoparticles in varying weight ratios (1:1 to 1:4), and their structural and electrical properties were systematically analyzed. Scanning Electron Microscopy (SEM) images showed that the nanoparticles were evenly spread out, which is favorable for charge movement. The I–V results, analyzed using the Cheung method and trap energy model, showed that adding a moderate amount of TiO₂ nanoparticles reduced series resistance, ideality factor, and trap energy. These changes lead to enhance carrier mobility and overall device conductivity. However, when the TiO₂ amount was too high (more than 1:3 ratio), the performance started to drop. Overall, this work shows how TiO₂ nanoparticles can help improve the overall performance of organic electronic devices by changing their structure and electrical behavior in a controlled way.

You might also be interested in these eBooks

Info:

Pages:

57-68

Citation:

Online since:

January 2026

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2026 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] H. Shirakawa, E. J. Louis, et al, Synthesis of electrically conducting organic polymers: halogen derivatives of polyacetylene (CH)X, Journal of the Chemical Society, Chemical Communications, (1977), 16 : 578-580

DOI: 10.1039/c39770000578

Google Scholar

[2] S. E. Yoon, J. Park, J. E. Kwon, S. Y. Lee, J. M. Han, C. Y. Go, etc., Improvement of Electrical Conductivity in Conjugated Polymers through Cascade Doping with Small Molecular Dopants. Advanced Materials. (2020), 32 (49): 200512910

DOI: 10.1002/adma.202005129

Google Scholar

[3] M. Eslamian,Inorganic and Organic Solution-Processed Thin Film Devices, Nano Micro Letters. 9 (2017) 1-23.

DOI: 10.1007/s40820-016-0106-4

Google Scholar

[4] S. Ahamad S, Organic semiconductors for device applications: current trends and future prospects, Journal of Polymer Engineering. 34 (2014) 279- 338.

DOI: 10.1515/polyeng-2013-0267

Google Scholar

[5] C. W. Lee, O. Y. Kim, J. Y. Lee, Organic materials for organic electronic devices. Journal of Industrial and Engineering Chemistry, (2014), 20: 1198–1208.

DOI: 10.1016/j.jiec.2013.09.036

Google Scholar

[6] A. K. Chauhan, P. Jha, D. K. Aswal, et al., Organic Devices: Fabrication, Applications, and Challenges, Journal of Electronics Materials, (2022), 51: 447–485

Google Scholar

[7] S. Chakraborty, N. B. Manik, Effect of COOH-functionalized SWCNT addition on the electrical and photovoltaic characteristics of Malachite Green dye based photovoltaic cells,Journal of Semiconductors. 35 (2014) 124004(1-6).

DOI: 10.1088/1674-4926/35/12/124004

Google Scholar

[8] D. P. Hagberg, T. Marinado, K. M. Karlsson, K. Nonomura, P. Qin, etc, Tuning the HOMO and LUMO energy levels of organic chromophores for dye sensitized solar cells,Journal of Organic Chemistry. 72 (2007) 9550–9556.

DOI: 10.1021/jo701592x

Google Scholar

[9] P.K. Das, S. Sen, N. B. Manik, "Effect of Single Walled Carbon Nanotubes on the Series Resistance and Trap Energy of Malachite Green Dye Based Organic Device", Journal of Nano Research 69 (2021) 69, 43-52.

DOI: 10.4028/www.scientific.net/jnanor.69.43

Google Scholar

[10] I. Khan, K. Saeed and I. Khan, Nanoparticles: Properties, applications and toxicities, Arabian Journal of Chemistry, (2019),12(7): 908-931

DOI: 10.1016/j.arabjc.2017.05.011

Google Scholar

[11] P. K. Das, S. Bhunia,N. B. Manik, Effect of Trap Energy on Series Resistance of Phenosafranine Dye Based Organic Diode in Presence of TiO2 and ZnO Nanoparticles, Advanced Materials Research. 1159(2020) 112 - 123

DOI: 10.4028/www.scientific.net/amr.1159.112

Google Scholar

[12] R. Li, T. Li and Q. Zhou, Impact of Titanium Dioxide (TiO2) Modification on Its Application to Pollution Treatment—A Review, Catalysts (2020), 10(7): 804

DOI: 10.3390/catal10070804

Google Scholar

[13] S. Sagadevan, etc., Investigation on Optical, Dielectric and Invitro Anti-Inflammatory Responses of Titanium Dioxide (TiO2) Nanoparticles. Digest Journal of Nanomaterials and Biostructures. (2018), 13(3): 641 - 652

Google Scholar

[14] A. Y. Khan, B. Saha, G. S. Kumar, Phenazinium dyes safranine O and phenosafranine induce self-structure in single stranded polyadenylic acid: Structural and thermodynamic studies, Journal of Photochemistry and Photobiology B: Biology, (2014), 132: 17-26

DOI: 10.1016/j.jphotobiol.2014.01.014

Google Scholar

[15] A. K. Jana, Solar cells based on dyes, Journal of Photochemistry and Photobiology A: Chemistry, (2000), 132: 1-17

Google Scholar

[16] Dr. M. Nasr, Dr. C. Eid, Prof. R. Habchi, Prof. Dr. P. Miele, Dr. M. Bechelany, Recent Progress on Titanium Dioxide Nanomaterials for Photocatalytic Applications, Chem sus Chem, (2018), 11: 3023-3047

DOI: 10.1002/cssc.201800874

Google Scholar

[17] S Sen, and N. B. Manik, Study on the Effect of 8 nm Size Multi Walled Carbon Nanotubes (MWCNT) on the Barrier Height of Malachite Green (MG) Dye Based Organic Device', International Journal of Advanced Science and Engineering, (2020), 6: 23-27

DOI: 10.29294/ijase.6.s2.2020.23-27

Google Scholar

[18] S. K. Cheung, N. W. Cheung, Extraction of Schottky diode parameters from forward current‐voltage characteristics, Applied Physics Letters, (1986), 49: 85-87

DOI: 10.1063/1.97359

Google Scholar

[19] S. Okur, F. Yakuphanoglu, M. Ozsoz, P. Kara Kadayifcilar, Electrical and interface properties of Au/DNA/n-si organic-on-inorganic structures, Microelectron, (2009), 86: 2305-2311

DOI: 10.1016/j.mee.2009.04.017

Google Scholar

[20] P. K. Das, N. B. Manik, "Tuning of series resistance by reducing the trap energy of methyl red dye-based organic devices in the presence of ZnO nanoparticles", International Journal of Renewable Energy Technology (2021) 12 (2), 118-129

DOI: 10.1504/ijret.2021.115280

Google Scholar

[21] F. Yakuphanoglu, Controlling of silicon–insulator–metal junction by organic semiconductor polymer thin film, Synthetic Metals., (2010), 160: 1551-1555

DOI: 10.1016/j.synthmet.2010.05.024

Google Scholar

[22] H. F. Haneef , A. M. Zeidell and O. D. Jurchescu, Charge carrier traps in organic semiconductors: A review on the underlying physics and impact on electronic devices, Journal of Materials Chemistry C, (2020), 8(3): 759-787

DOI: 10.1039/c9tc05695e

Google Scholar

[23] V. Coropceanu, et. al, Charge transport in organic semiconductors, Chemical Reviews, (2007), 107(4) : 926-952

Google Scholar

[24] N. Sergeeva, Investigation of Trap States in Organic Semiconductors for Organic Solar Cells Applications, Technische Universit at Dresden, (2022)

Google Scholar

[25] S. A. Moiz, I. A. Khan, W. A. Younis, K. S. Karimov, Space Charge–Limited Current Model for Polymers Provisional chapter Space Charge–Limited Current Model for Polymers, (2016), ISBN: 978-953-51-2691

DOI: 10.5772/63527

Google Scholar

[26] P. K. Das, S. Sen, N. B. Manik "Study on the series resistance of crystal violet dye-based organic photovoltaic device in presence of single walled carbon nanotubes", Indian Journal of Physics,(2021) 1-9

DOI: 10.1007/s12648-021-02051-y

Google Scholar