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Key Engineering Materials Vols. 330-332
Paper Title Page
Abstract: In this study, CaSiO3 (CS)/Ca3(PO4)2 (TCP) composites with 50% CS and 50% TCP
sintered at different temperatures (1100oC, 1200oC and 1300oC) were prepared. The formation of
bone-like apatite on CS-TCP composites was investigated by soaking the ceramics in simulated
body fluid (SBF), and the presence of bone-like apatite layer on the composite surface after soaking
in SBF was determined by X-ray diffraction (XRD) and field emission scanning electron
microscopy (FESEM). The results showed that the bone-like apatite was formed on all the CS-TCP
composites sintered at different temperatures after 7 days of immersion. In addition, the degradation
of CS-TCP composites prepared at different temperatures was evaluated by measurement of weight
loss of the ceramics in Tris-HCl buffer solution at 37oC, and the results showed that there was no
difference in degradation rate between the samples. In vitro cell experiments indicated that the
osteoblasts proliferated faster on the CS-TCP ceramics sintered at higher temperature, and cells on
the CS-TCP ceramics sintered at 1300oC showed highest proliferation rate. These results provide
valuable information for designing CS-TCP composite bioceramics for bone regeneration
applications.
451
Abstract: This study was focused on evaluating the bactericidal and anti-adhesive efficacy of
silver-hydroxyapatite/ titania nanocomposites (nAg-HA/TiO2) coating on titanium against oral
bacteria. Porphyromonas gingivalis, Prevotella intermedia and Fusohacterium nucleatum and
Streptococcus mutans were used. Antibacterial activity of nAg-HA/TiO2 coating was investigated
quantitatively using film applicator coating method and titanium plates incubated with bacteria were
prepared for SEM to observe the adherence of oral bacteria. The viability of each type of bacteria on
the antibacterial film was suppressed to about 10% after anaerobic incubation for 3 hours. Image of
SEM demonstrated that bacteria on sandblasting surfaces were relatively confluent whilst on coated
surfaces fewer bacteria were observed. Adherence of bacteria on nAg-HA / TiO2-coated surfaces
compared with uncoated surfaces was remarkably decreased.
455
Abstract: Hydroxyapatite (HA)-granule-implanted cylindrical titanium composites, which uniformly
have HA granules on the curved surface, were formed by a hot pressing using HA-granuleimplantation
system under the conditions of 1023 K, 1 h, 1960 N in vacuo. Cracks were not observed
in the HA granules. The HA-granule-implanted titanium samples were implanted in a mandible of a
dog. After 1 year, new thin bones like pillars were selectively structured on the HA granules with bone
induction ability. The HA-granule-implantation technique is expected to be useful for designing shape
of bone around titanium implant in order to match living bones.
459
Abstract: Nano-hydroxyapatite/polyamide66/chitosan composite (n-HA/PA66/CS) was prepared by
a co-precipitation method, and was characterized by TG/DTG, TEM, IR, XRD and Universal
mechanical testing machine. TEM test showed that some rod like crystals were formed and
distributed uniformly into polymer matrix, with a size of about Φ30nm×80nm. IR and XRD
analysis showed that some chemical bonds and electrostatic interaction existed between n-HA and
polymers. TG/DTG curves indicated that the composites possessed a talent of high heat-resistance.
The compressive strength of composite changed with different content of three compounds, the
maximum compressive strength of composite (70MPa) could be acquired.
463
Abstract: Apatite nuclei were precipitated in the pores of the porous polyethylene matrix in 2.0SBF.
Apatite was induced by the apatite nuclei inside the pores and on the surface of the composite and
grew to the surface of the composite by a soak in 1.0SBF. The formed apatite showed high adhesive
strength to the composite probably due to a mechanical interlocking effect between the matrix and the
apatite.
467
Abstract: A unique composite consisted of nano-hydroxyapatite (n-HA), poly (vinyl alcohol) (PVA)
and gelatin (Gel), was prepared and characterized by Fourier transform infrared absorption
spectroscopy (FT-IR), X-ray diffraction (XRD), scanning electron microscopy (SEM) and burning
test. The homogenicity of the composite was evaluated, and the presence of interior chemical bond
was confirmed and discussed. Mechanical strength and water absorption of the prepared composite
were investigated, respectively. The results show that n-HA/PVA/Gel composite has good
homogeneity, similar mechanical properties to natural cartilage and excellent in vivo
biocompatibility.
471
Abstract: In this work, a new kind of bioactive PVA/HA hydrogels use as artificial cartilage were
prepared by in situ sol-gel synthesis method. Simulated experiments were performed to evaluate and
compare the bioactive ability and properties of the hydrogels in simulated body solution. PVA/HA
Cartilage implants were developed and used to repair articular cartilage defect in rabbit knee. The
macroscopic and histological observation of animal experiments displayed that the implanted
hydrogels combined tightly to ambient tissues, and some bone-like tissue grew into the bottom of the
implants from the base-bone to form more deep-set binding.
475
Abstract: The ability of apatite to form on the surface of biomaterials in simulated body fluid (SBF)
has been widely used to predict the bone-bonding ability of bioceramic and bioceramic/polymer
composites in vivo. Porous β-tricalcium phosphate/poly(L-lactic acid) (β-TCP/PLLA) composite
scaffold was synthesized by new method. The ability of inducing calcium phosphate (Ca-P)
formation was compared in static simulated body fluid(sSBF) and dynamic simulated body fluid
(dSBF). The Ca-P morphology and crystal structures were identified using SEM, X-ray diffraction
and Fourier transform infrared (FT-IR) spectroscopy. The results showed that the typical features of
bone-like apatite formation on the surface and the inner pore wall of β-TCP/PLLA. Ca-P formation
on scaffold surfaces in dSBF occurred slower than in sSBF and was more difficult with increasing
flow rate of dSBF. The ability of apatite to form on β-TCP/PLLA was enhanced by effect of each
other that has different degradable mechanism. Porous β-TCP/PLLA composite scaffold indicates
good ability of Ca-P formation in vitro.
483
Abstract: Mercapto group controls the adsorption and release of insulin, which is one of the
proteins for enhancing the osteoblast proliferation. Silicon-ion-species were reported to stimulate
the bone-forming ability of osteoblasts. The present paper describes doping with mercapto groups
and silicon-ion-species in a calcium carbonate/poly (lactic acid) composite membrane, which is
prepared by a sol-gel method using 3-mercaptopropyltrimethoxysilane. The membrane was
amorphous and showed high flexibility. A quantitative analysis by thiol-disulfide exchange reaction
using 2, 2-dipyridyl disulfide reagent showed that the amount of mercapto group existing on
membrane surface was estimated to be about 5.51μmol/cm2. A trace amount of silicon-ion-species
was released from the membrane after soaking in tris (hydroxymethyl) aminomethane buffer
solution at 37 oC. The membrane is expected to have high bone-forming ability.
487