Stability of Dye Sensitized Solar Cells with Glass Frit Sealant

Article Preview

Abstract:

Glass frit sealant was prepared under different conditions, including the ratios of each composition, grinding method of the sealants drying temperature, and sintering process. When the ratio of glass frit, terpineol and ethyl cellulose was fixed at 5:4:1, a uniform sealant film without any pore or crack was obtained. The rates of weight loss for the cells filled with water and electrolyte sealed with the glass frit films were investigated. The drying temperature of 25°C and sintering at 560°C with temperature gradients led to the smallest rate of weight loss both for water and electrolyte. Furthermore, the optimized sealant was fabricated into solar cells, which exhibited best stability by retaining 80% of their initial conversion efficiency, accompanying an electrolyte leakage rate as small as 0.12% after 800 hours tracking test at room temperature.

You might also be interested in these eBooks

Info:

Periodical:

Key Engineering Materials (Volumes 512-515)

Pages:

1619-1624

Citation:

Online since:

June 2012

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2012 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] H. Gruenspecht and D. Administrator. R.U.S. Energy Information Admanistration(2010)

Google Scholar

[2] H. Lin, The opportunities and challenges of the low cost dye-sensitized solar cells. J. Ad. Mater. In. 199(2010) 40-44.

Google Scholar

[3] A.Yella, H.W. Lee, H.N. Tsao, M.Grätzel, Porphyrin-sensitized solar cells with cobalt (II/III)–based redox electrolyte exceed 12 percent efficienc. J. Sci. 334(2011) 629-633.

DOI: 10.1126/science.1209688

Google Scholar

[4] L. C. Li, C. F.Tang , S. J.Wang, Study on the preparation and properties of long-term weatherability eva films used in a solar cell. J. Sol. Energy (2010)75-77.

Google Scholar

[5] D.G. Lee, J.T. Hong, G.C.Xu, et al., A simpledye-sensitized solar cell sealing technique using a CO2 laser beam excited by 60Hz AC discharges. J. Optics & Laser Tech.42 (2010) 934–940.

DOI: 10.1016/j.optlastec.2010.01.011

Google Scholar

[6] T. Kitamural, K.Okada, H. Matsui, N. Tanabe. Durability of dye-sensitized solar cells and modules. J. Journal of Sol. Energy Engineering 132(2010) 51–57.

DOI: 10.1115/1.4001152

Google Scholar

[7] I. Lee, S.J. Hwang, H.S. Kim, Reaction between oxide sealant and liquid electrolyte in dye-sensitized solar cells. J. Sol. Energy Mater. Sol. Cells 95 (2011) 315–317.

DOI: 10.1016/j.solmat.2010.04.052

Google Scholar

[8] Z. Tachan, S. Ruhle, A. Zaban. A new solar cell design for efficient current collection and improved cell sealing [J]. Sol. Energy Mater. Sol. Cells 94 (2010) 317–322.

DOI: 10.1016/j.solmat.2009.10.006

Google Scholar

[9] L.Wang, X.M. Fang, Zh.G.Zhang, Design methods for large scale dye-sensitized solar modules and the progress of stability research. J. Renew.Sust. Energy Reviews. 14 (2010) 3178–3184.

DOI: 10.1016/j.rser.2010.06.019

Google Scholar

[10] S.E. Lin, Y.R. Cheng, W.C.J. Wei. Synthesis and long-term test of borosilicate-based sealing glass for solid oxide fuel cells. J. Journal of the Eur. Cera. Soc.31 (2011) 1975–1985.

DOI: 10.1016/j.jeurceramsoc.2011.04.017

Google Scholar

[11] H.Matsui, K.Okada, T.Kitamura, N.Tanabe. The normal stability of dye-sensitized solar cells with current collecting grid. J. Sol. Energy Mater. Sol. Cells 93 (2009) 1110–1115.

DOI: 10.1016/j.solmat.2009.01.008

Google Scholar

[12] Sh. Noda, K. Nagano, T. Nakashima, M. K.Yoshino. Development of large size dye-sensitized solar cell modules with high temperature durability. J. Syn. Metals 159 (2009) 2355–2357.

DOI: 10.1016/j.synthmet.2009.10.002

Google Scholar

[13] H.Pettersson, T.Gruszecki, Long-term stability of low-power dye-sensitised solar cells prepared by industrial methods. J. Sol. Energy Mater. Sol. Cells 70( 2001) 203–212.

DOI: 10.1016/s0927-0248(01)00025-3

Google Scholar

[14] P.T. Nguyen, A.R. Andersen, E.M. Skou, T. Lund. Dye stability and performances of dye-sensitized solar cells with different nitrogen additives at elevated temperatures. J. Sol. Energy Mater. Sol. Cells 94 (2010) 1582–1590.

DOI: 10.1016/j.solmat.2010.04.076

Google Scholar

[15] N. Kato, K.Higuchi, H.Tanaka, J.Nakajima, T.Toyoda. Improvement in long-term stability of dye-sensitized solar cell for outdoor use. J. Sol. Energy Mater. Sol. Cells 95 (2011) 301–305.

DOI: 10.1016/j.solmat.2010.04.019

Google Scholar

[16] R. Sastrawan, J. Beier, U. Belledin, S. Hemming, et al., W. Hoffmann. New Interdigital Design for Large Area Dye Solar Modules Using a Lead-free Glass Frit Sealing. J. Prog. Photovolt: 14 (2006) 697–709.

DOI: 10.1002/pip.700

Google Scholar

[17] W.J. Lee, E.Ramasamya, D. Y. Lee, J. S. Song. Glass frit overcoated silver grid lines for nano- crystalline dye sensitized solar cells. J. Journal of Photochem. Photobio.A 183 (2006) 133–137.

DOI: 10.1016/j.jphotochem.2006.03.006

Google Scholar

[18] Md. K. Nazeeruddin, R. Splivallo, P. Liska, P. Comte and M. Grätzel. A swift dye uptake procedure for dye sensitized solar cells. J. Chem. Commun. , 2003, 1456–1457.

DOI: 10.1039/b302566g

Google Scholar