ZrC Oxidization Mechanism in Air

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Abstract:

The ZrC oxidization mechanism in air was carefully investigated by the phase composition and grain morphology through DSC, X-ray diffraction and SEM respectively at different temperature. It was found that the oxidization of ZrC start at about 400°C by oxygen atom entering the interstitial sites to substitute part of Carbon. Zr2O and ZrO2 can be formed at a temperature of about 600°C and 1000°Crespectively. And ZrC will completely transfer to ZrO2 at 1000°C for 5hrs. No obvious grain morphology change was found under 600°C.

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Key Engineering Materials (Volumes 512-515)

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1721-1724

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June 2012

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© 2012 Trans Tech Publications Ltd. All Rights Reserved

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DOI: 10.1007/bf00900860

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