Preparation and Properties of Dy Doped La and Sc Solution of BiFeO3 Film

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A series of Dy doped La and Sc solution of BiFeO3 thin films have been prepared by using spin-coating process on conductive indium tin oxide (ITO)/glass substrates, which a simple sol-gel possess is applied and annealed at 500°C. With the increase of content of Dy, the strongest peak (110) of La and Sc solution BiFeO3 film tends to further broaden. There is no second phase existence within the present Dy doping level. Cross section scanning electron microscope (SEM) pictures revealed that the thickness of BiFeO3 film was about 370 nm. For Dy doping level is 0.05, the maximum double remanent polarization 2Pr of as-prepared BiFeO3 thin film is15.44 μC/cm2. Image of atomic force microscopy indicated that the root-mean-square surface roughness value of as-prepared BiFeO3 thin film is 2.11 nm. The dielectric constant of as-prepared films tends to firstly increase and then decrease with the increase of Dy content

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109-113

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January 2013

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© 2013 Trans Tech Publications Ltd. All Rights Reserved

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[1] T. Ahmed, A. Vorobiev, S. Gevorgian, Growth temperature dependent dielectric of BiFeO3 thin films deposited on silica glass substrates, Thin Solid Films 520 (2012), 4470-4474

DOI: 10.1016/j.tsf.2012.02.082

Google Scholar

[2] J. H. Jo, S. G. Lee, S. H. Lee, Structural and pyroelectric properties of sol-gel derived multiferroic BFO thin films, Mater. Res. Bull. 47 (2012), 409-412

DOI: 10.1016/j.materresbull.2011.11.009

Google Scholar

[3] A. R. Damodaran, E. Breckenfeld, A. K. Choquette, et al., Stabilization of mixed-phase structures in highly strained BiFeO3 thin films via chemical-alloying, Appl. Phys. Lett. 100 (2012), 082904-4

DOI: 10.1063/1.3688175

Google Scholar

[4] H. Deng, H. M. Deng, P. X. Yang, J. H. Chu, Effect of Cr doping on the structure, optical and magnetic properties of multiferroic BiFeO3 thin films, J. Mater. Sci. Mater. El. 23 (2012), 1215-1218

DOI: 10.1007/s10854-011-0575-7

Google Scholar

[5] J. G. Wu, J. Wang, D. Q, Xiao, J. G. Zhu, A method to improve electrical properties of BiFeO3 thin films, ACS Appl. Mater. Inter. 4 (2012), 1182-1185

DOI: 10.1021/am300236j

Google Scholar

[6] J. Yu, J. H. Chu, Progress and prospect for high temperature single phased magnetic ferroelectrics, Chinese Science Bulletin, 53 (2008), 2097-2112

DOI: 10.1007/s11434-008-0308-3

Google Scholar

[7] V. E. Wood, A. E. Austin, Possible applications for magnetoelectric materials, Int. J. Magn. 5(1973), 303-315

Google Scholar

[8] Y. Tokura, Multiferroics as quantum electromagnets, Science, 312 (2006), 1481-1482

DOI: 10.1126/science.1125227

Google Scholar

[9] N. A. Spaldin, M. Fiebig, The Renaissance of magnetoelectric multiferroics, Science, 309 (2005), 391-392

DOI: 10.1126/science.1113357

Google Scholar

[10] C. Michel, J. M. Moreau, G. D. Achenbach, R. Gerson, W. J. James, The atomic structure of BiFeO3,Solid State Commun. 7(1969), 701-704

DOI: 10.1016/0038-1098(69)90597-3

Google Scholar

[11] S. H. Han, C. I. Cheon, H. G. Lee, H. W. Kang, H. I. Hwang, Low temperature hydrothermal epitaxy of heteroepitaxial BiFeO3 film, Ceram. Int. 38 (2012), S391-395

DOI: 10.1016/j.ceramint.2011.05.018

Google Scholar

[12] H. R. Liu, Z. L. Liu, Q. Liu, K. L. Yao, Ferroelectric properties of BiFeO3 films grown by sol-gel process, thin solid films 500(2006), 105-109

DOI: 10.1016/j.tsf.2005.11.041

Google Scholar

[13] Y. Wang, C. W. Nan, Integration of BiFeO3 thin film on Si wafer via a simple sol-gel method, thin solid films 517 (2009), 4484-4487

DOI: 10.1016/j.tsf.2009.02.142

Google Scholar

[14] S. Nakshima, Y. Tsujita, H, Fujisawa, T. Kanashima, M. Okuyama, M. Shimizu, Characterization of epitaxial BiFeO3 thin films prepared by ion beam sputtering, Curr. Appl. Phys. 11 (2011), S 244-246

DOI: 10.1016/j.cap.2010.11.066

Google Scholar

[15] S. J. Chiu, Y. T. Liu, H. Y. Lee, G. P. Yu, J. H. Huang, Growth of BiFeO3/SrTiO3 artificial superlattice structure by RF sputtering, J. Cryst. Growth. 334 (2011), 90-95

DOI: 10.1016/j.jcrysgro.2011.08.019

Google Scholar

[16] X. W. Qi, X. Y. Zhang, X. Wang, H. B. Sun, J. Q, Qi, Preparation and characterization of BiFeO3 film via sol-gel spin-coating process, Key Eng. Mater. 492 (2012), 202-205

DOI: 10.4028/www.scientific.net/kem.492.202

Google Scholar