Wet Anisotropic Etching Characteristics of Si{100} in TMAH+Triton at near the Boiling Point

Article Preview

Abstract:

The anisotropic silicon etching characteristics of TMAH(tetramethyl ammonium hydroxide)+Triton at near the boiling point were investigated. The etch rate of Si {100}, the convex corners, and the roughness of the etched surface contact with the fabrication of bulk microstructures and thus micromechanical devices in silicon. This study presents that the etch rate of Si {100} in 25 wt.% TMAH with 0.1% Triton at near boiling point (112°C) is 1.37μm/min, it is three times higher than it at 80°C. The surface roughness and convex corners of Si {100} after etching at different temperature were investigated by optical microscope, scanning electron microscope (SEM) and atomic force microscope (AFM). The etching rate and smoothness of an etched surface can be improved simultaneously at near boiling point, meanwhile, the undercutting on convex corner should be accepted.

You might also be interested in these eBooks

Info:

Periodical:

Key Engineering Materials (Volumes 645-646)

Pages:

58-63

Citation:

Online since:

May 2015

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2015 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] P. Pal, M. A. Gosálvez, K. Sato, Etched profile control in anisotropic etching of silicon by TMAH+Triton, Journal of micromechanics and microengineering. 22 (2012) 065013.

DOI: 10.1088/0960-1317/22/6/065013

Google Scholar

[2] I. Zubel, M. Kramkowska, The effect of alcohol additives on etching characteristics in KOH solutions, Sens. Actuators A. 101 (2002) 255-261.

DOI: 10.1016/s0924-4247(02)00265-0

Google Scholar

[3] M. Sekimura, Anisotropic etching of surfactant-added TMAH solution, IEEE Int. Conf. Micro Electro Mech. Syst., Tech. Dig. Institute of Electrical and Electronics Engineers, New York, N. Y. 12 (1999) 650-655.

DOI: 10.1109/memsys.1999.746904

Google Scholar

[4] A. Merlos, M. Acero, M. H Bao, J. Bausells, J. Esteve, TMAH/IPA Anisotropic Etching Characteristics, Sensors and Actuators A. 37-38 (1993) 737-743.

DOI: 10.1016/0924-4247(93)80125-z

Google Scholar

[5] P. Pal, K. Sato, Various shapes of silicon freestanding microfluidic channels and microstructures in one step lithography, J. Micromech. Microeng. 19 (2009) 055003.

DOI: 10.1088/0960-1317/19/5/055003

Google Scholar

[6] B. Tang, M. Shikida, K. Sato, P. Pal, H. Amakawa, H. Hida, K. Fukuzawa, Study of surfactant-added TMAH for applications in DRIE and wet etching-based micromachining, J. Micromech. Microeng. 20 (2010) 065008.

DOI: 10.1088/0960-1317/20/6/065008

Google Scholar

[7] M. A. Gosálvez, B. Tang, P. Pal,K. Sato,Y. Kimura, K. Ishibashi, Orientation- and concentration-dependent surfactant adsorption on silicon in aqueous alkaline solutions: explaining the changes in the etch rate, roughness and undercutting for MEMS applications, J. Micromech. Microeng. 19 (2009).

DOI: 10.1088/0960-1317/19/12/125011

Google Scholar

[8] B. Tang, P. Pal, M. A. Gosalvez, M. Shikida, K. Sato, H. Amakawa, S. Itoh, Ellipsometry study of the adsorbed surfactant thickness on Si{110} and Si{100} and the effect of pre-adsorbed surfactant layer on etching characteristics in TMAH, Sensors and Actuators A. 156 (2009).

DOI: 10.1016/j.sna.2009.10.017

Google Scholar