Preparation and Properties of Modified Boron Nitride/Epoxy Resin Thermal Conductive Composites

Article Preview

Abstract:

Boron nitride (BN) was modified by silane coupling agent (KH560) and used as heat conductive filler to prepare the modified BN (BN560)/epoxy composite. The effect of the BN560 filler content on the thermal conductivity and thermal stability of the epoxy composite was studied. The results show that BN560 can be uniformly dispersed in the epoxy matrix by an ultrasonic disperser. The BN560 added can effectively improve the thermal conductivity of the epoxy composite. With the increase of BN560 content to 20 wt.%, the thermal conductivity of the composite increases accordingly to 0.27 W/(m·K), 50% higher than that of pure epoxy, and a heat conductive network is formed. The BN560 added can improve the thermal stability of the composite. With increasing BN560 content, the thermal decomposition temperature and glass transition temperature of the composite increase. The composite with the BN560 content of 20 wt.% has the weight loss of 10 wt.% at 395.12 °C and the glass transition temperature of 144.59 °C.

You might also be interested in these eBooks

Info:

Periodical:

Materials Science Forum (Volume 1003)

Pages:

173-178

Citation:

Online since:

July 2020

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2020 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] Qi Li, Lei Chen, Matthew R. Gadinskil, et al. Flexible high-temperature dielectric materials from polymer nanocomposites[J]. Nature, 2015, 523(7562): 576-579.

DOI: 10.1038/nature14647

Google Scholar

[2] HUANG X Y, ZHI C Y, JIANG P K, et al. Polyhedral oligosilsesquioxane-modified boron nitride nanotude based epoxy nanocomposites: an ideal dielectric material with high thermal conductivity[J]. Advanced Functional Materials, 2013, 23(14): 1824-1831.

DOI: 10.1002/adfm.201201824

Google Scholar

[3] CHEN Peng, SUN Baolui,JI Feng, Fault mode analysis and accelerated life test method of the saturable reactor prototype for ±1 100kV UHVDC converter valves[J]. High Voltage Engineering, 2016, 42(8): 2612-2617.

Google Scholar

[4] Wang Youyuan, WANG shiyou, HUANG Yanguang, et al. Study on thermal aging characteristics of epory resin of dry-typl transformer[J]. High Voltage Engineering, 2018, 44(1): 187-194.

Google Scholar

[5] Chen Jin, Wang Chunfeng, Wang Yongliang, Han Baozhong, Han Zhidong, et al. Study on the relationship between thermal conductivity and viscosity of Al2O3/BN Epoxy Composite Insulating Materials[J]. Acta Materiae compositae Sinica, 2015, 32(5) : 1286-1293.

Google Scholar

[6] Akherul Md. Islam, Hongjin Lim, et al. Enhanced thermal conductivity of liquid crystalline epoxy resin using controlled linear polymerization[J]. ACS Macro Letters, 2018, 7(10): 1180-1185.

DOI: 10.1021/acsmacrolett.8b00456

Google Scholar

[7] HUANG X, JIANG P, AND TANAKA T, A review of dielectric polymer composites with high thermal conducyivity[J], IEEE Electrical Insulation Magazine, 2011, 27(4): 8-16.

DOI: 10.1109/mei.2011.5954064

Google Scholar

[8] GUO Le, XIAO Chao, WANG Hui, et al. Preparation and proerties of epoxy nanocomposites with excellent thermal conductivity[J]. Polymer Materials Science and Engineering, 2016, 23(11):162-167.

Google Scholar

[9] SHEN Heng, ZHAO Ning, XU Jian. Research progress on boron nitride/polymer thermally conductive composite[J]. Polymer Bulletin, 2016(9): 27-33.

Google Scholar

[10] XU Suichun, ZHAO Chunbao. Preparation and properties study of epoxy /modified boron nitride thermal conductive composites[J]. Insulating Materials, 2017, 50(5): 16-20.

Google Scholar

[11] Shaotao Dai, Teng Zhang, Siming Mo, et al. Study on Preparation, thermal conductivity and electrical insulation properties of Epoxy/AlN[J]. IEEE Transactions on Applied Superconductivity, 2019, PP(99): 1-1.

DOI: 10.1109/tasc.2018.2890752

Google Scholar

[12] Yongcun Zhou, Yagang Yao, Chia-Yun Chen, et al. The use of polyimide-modified aluminum nitride fillers in AlN@PI/Epoxy composites with enhanced thermal conductivity for electronic encapsulation[J]. Scientific Reports, 2014, 4(1): 4779.

DOI: 10.1038/srep04779

Google Scholar

[13] Tianyi Na, Xue Liu, Hao Jiang, et al. Enhanced thermal conductivity of fluorinated epoxy resins by incorporating inorganic filler[J]. Reactive and Functional Polymers, 2018, 128: 84-90.

DOI: 10.1016/j.reactfunctpolym.2018.05.004

Google Scholar

[14] Wancong Bian, Tong Yao, Ming Chen, et al. The synergistic effects of the micro-BN and nano-Al2O3 in micro-nano composites on enhancing the thermal conductivity for insulating epoxy resin[J]. Composites Science and Technology, 2018, 168: 420-428.

DOI: 10.1016/j.compscitech.2018.10.002

Google Scholar

[15] Dianyu Shen, Zhaolin Zhan, Zhiduo Liu, et al. Enhanced thermal conductivity of epoxy composites filled with silicon carbide nanowires[J]. Scientific Reports, 2017, 7(1): 2606.

DOI: 10.1038/s41598-017-02929-0

Google Scholar