Study on the Preparation and Properties of Epoxy/PEI/Nano-Attapulgite Nanocomposites

Article Preview

Abstract:

Polyether imides (PEI) and nanoattapulgite particles organically synthesized by the active silane containing epoxide groups (OAT) were used to modify the epoxy resin (ER). The effect of the concentration of OAT on the morphology, thermal and mechanical properties of ER/PEI/OAT nanocomposites was explored in the present work. The microscopic structure of nanocomposites was investigated by Scanning electric microscopy (SEM). The results showed that a homogeneous nanoattapulgite organically-modified by silane in the polymeric matrix was obtained. SEM images showed that the morphology transformation increased with the increase of OAT content, which would lead the improvement of the impact strengths of nanocomposites. The results of mechanical and thermal measurements indicated that the introduction of PEI and OAT into the epoxy resulted in the great improvement of the impact strength and storage module. With the OAT concentration increasing, the glass translation temperature (Tg) value of nanocomposites was gradually increased. Additionally, the results of thermo-gravimetric analysis (TGA) revealed that thermal stability of nanocomposites was apparently improved in comparison to the epoxy resin systems.

You might also be interested in these eBooks

Info:

Periodical:

Materials Science Forum (Volumes 745-746)

Pages:

341-351

Citation:

Online since:

February 2013

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2013 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] H. Ku, F. Cardona, N. Pattarachaiyakoop, M. Trada, Fracture toughness of phenol formaldehyde composites reinforced with E-spheres, Journal of Composite Materials. 43 (2009) 741-754.

DOI: 10.1177/0021998308101296

Google Scholar

[2] J.K. Duan, C. Kim, Y. Zheng, et al., Functionalizing nano-AlN by silane modification for preparation of covalent-integrated Epoxy/poly (ether imide) nanocomposites, Journal of Applied Polymer Science. 115 (2009) 2734 -2746.

DOI: 10.1002/app.29962

Google Scholar

[3] C.K. Riew, A.J. Kinloch, Toughened plastics I: science and engineering, Washingtion DC. ACS, (1993).

Google Scholar

[4] P. Pustkova, J.M. Hutchinson, F. Roma´n, S. Montserrat, Homopolymerization effects in polymer layered silicate nanocomposites based upon epoxy resin: implications for exfoliation, Journal of Applied Polymer Science. 114 (2009)1040-1047.

DOI: 10.1002/app.30697

Google Scholar

[5] J.K. Duan, S. x. Shao, L. Jiang, et al., Nano-attapulgite Functionalization by Silane Modification for Preparation of Covalently-integrated Epoxy/TMPTMA Nanocomposites, Iranian Polymer Journal. 20 (2011) 855-872.

Google Scholar

[6] X. Wang, D.Y.S. Lou, Int J Engine Res. 27 (2003)377-381.

Google Scholar

[7] A.J. Mackinnon, S.D. Jenkins, P.T. McGral, R.A. Petrick, Macromolecules. 25 (1992) 3492-3495.

Google Scholar

[8] M.D.M. Salinas-Ruiz, A.A. Skordos, I.K. Partridge, Rubber-toughened epoxy loaded with carbon nanotubes: structure-property relationships, Journal of Materials Science. 45 (2010) 2633-2639.

DOI: 10.1007/s10853-010-4241-x

Google Scholar

[9] J.K. Duan, C. Kim, Y. Zheng, et al., Effect of external electric field on the microstructures and properties of carbon nanotubes/thermosets nanocomposites, Polymer Composites. 31 (2010) 347-358.

DOI: 10.1002/pc.20812

Google Scholar

[10] W.F. Bradley. The structural scheme of attapulgite. American Mineralogist. 24 (1940) 405–410.

Google Scholar

[11] W.F. Bradley, The structural scheme of attapulgite, American Mineralogist. 24 (1940) 405–410.

Google Scholar

[12] M. Tian, C.D. Qu, Y.X. Feng, et al., Structure and properties of fibrillar silicate/SBR composites by direct blend process, Journal of materials science. 38 (2003) 4917-4924.

DOI: 10.1023/b:jmsc.0000004414.27574.93

Google Scholar

[13] L. Zhao, G. z. Zhan, Y.F. Yu, et al., Influence of attapulgites on cure-reaction-induced phase separation in epoxy/poly(ether sulfone) blends, Journal of Applied Polymer Science. 108 (2008) 953-959.

DOI: 10.1002/app.27416

Google Scholar

[14] K. Hedicke-Hochstotter G.T. Lim, V. Altstadt, Novel polyamide nanocomposites based on silicate nanotubes of the mineral halloysite, Composites Science and Technology. 69 (2009) 330-334.

DOI: 10.1016/j.compscitech.2008.10.011

Google Scholar

[15] B.K. Kuila, A.K. Nandi. Poly(3-dodecyl thiophene)-organically modified montmorillonite clay nanocomposites: Influence of chain regioregularity and preparation condition on physical, mechanical, optical, and conductivity properties, Journal of Applied Polymer Science. 111 (2009).

DOI: 10.1002/app.29074

Google Scholar

[16] K. Kowalczyk, T. Spychaj, Protective epoxy dispersion coating materials modified a posteriori with organophilized montmorillonites, Surface & Coatings Technology. 204 (2009) 635-641.

DOI: 10.1016/j.surfcoat.2009.08.046

Google Scholar

[17] J.K. Duan, C. Kim, P.K. Jiang, On-line monitoring of cycloaliphatic epoxy/acrylate interpenetrating polymer networks formation and characterization of their mechanical properties, Journal of Polymer Research. 16 (2009) 45-54.

DOI: 10.1007/s10965-008-9201-7

Google Scholar

[18] A.S. Luyt, J.A. Molefi, H. Krump, Thermal, mechanical and electric properties of copper powder filled low-density and linear low-density polyethylene composites, Polymer Degradation and Stablity. 91 (2006) 1629-1636.

DOI: 10.1016/j.polymdegradstab.2005.09.014

Google Scholar

[19] O. Becker, R. Varley, G. Simon, Morphology, thermal relaxations and mechanical properties of layered silicate nanocomposites based upon high functionality epoxy resins, Polymer. 43 (2002) 4365-4373.

DOI: 10.1016/s0032-3861(02)00269-0

Google Scholar