Solid Oxide Fuel Cell - A Future Source of Power and Heat Generation

Article Preview

Abstract:

Fuel cells are devices for electrochemically converting the chemical energy of a fuel gas into electrical energy and heat without the need for direct combustion as an intermediate step. The main advantages of fuel cells are that they rely on the high conversion efficiency and low environmental impact than traditional energy conversion systems. One promising fuel cell type, Solid oxide Fuel Cell, has all the components in the solid phase utilises nano-ceramic composite materials and operates at elevated temperatures in the range 500-1000°C. It has suitable perspectives to replace their classical counterparts for the distributed generation of electrical energy with small and medium power sources. The inherent advantages of such high temperature fuel cells are internal reforming of methane and waste heat production at high temperatures which lower the demands on the fuel processing system and lead to higher efficiency compared with low temperature fuel cells. Using natural gas as feed, an electric efficiency of more than 88% has been predicted. On the other hand, considerable research is going on to reduce the operating temperatures between 600°C to 800°C to increase life-time and thereby reduce costs. These can be achieved only by using electrolytes with proper ionic conductivity at the intermediate temperatures. In addition, this technology does not produce significant amounts of pollutants such as nitrogen oxides compared with internal combustion engines. Solid oxide fuel cells are seen as ideal energy sources in transport, stationary, and distributed power generators.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

217-241

Citation:

Online since:

May 2013

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2013 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] S. C. Singhal and K. Kendall (editors), High Temperature Solid Oxide Fuel Cells: Fundamentals, Design and Applications, Elsevier, Oxford, 2003.

Google Scholar

[2] L. Navadol, W. Wiyaratan, W. Kiatkittipong, Review of solid oxide fuel cell technology, Engineering Journal, 3 Issue1 (Jan. 2009).

Google Scholar

[3] J. Larminie and D. Andrew, Fuel Cell Systems Explained, John Wiley & Sons Ltd, 2003.

Google Scholar

[4] H. Mahcene, H. Ben Moussa, H. Bouguetaia, B. Bouchekima and D. Bechki, Losses effect on solid oxide fuel cell stack performance, Fuel Cells Journal, (2006).

DOI: 10.1615/ichmt.2008.cht.1400

Google Scholar

[5] S. McIntosh and R. J. Gorte, Direct hydrocarbon solid oxide fuel cells, Chem. Rev. 104 (2004) 4845-4865.

DOI: 10.1021/cr020725g

Google Scholar

[6] K. Eguchi, S. C. Singhal, H. Yokokawa, and J. Mizusaki (editors), Solid oxide fuel cells 10 (SOFC-X)  ECS, Pennington, 7, No. 1 (2007).

Google Scholar

[7] N. P. Brandon, Materials engineering for solid oxide fuel cell technology, Materials Science Forum Trans Tech Publications, Switzerland 539-543 (2007) 20-27.

DOI: 10.4028/www.scientific.net/msf.539-543.20

Google Scholar

[8] S. C. Singhal, Advances in solid oxide fuel cell technology,  Solid State Ionics 135, (2000) 305-313.

DOI: 10.1016/s0167-2738(00)00452-5

Google Scholar

[9] L. Yixin, S. Laura, L. Peiwen, Numerical simulation of heat transfer and fluid flow of a flat-tube high power density solid oxide fuel cell, Journal of Fuel Cell Science and Technology 2 (2005) 65-69 .

DOI: 10.1115/1.1843120

Google Scholar

[10] J. Yuan, G. Yang, M. Addersson and B. Sundén, Analysis of chemical reacting heat transfer in SOFCs, 5th European Thermal-Sciences Conference, The Netherlands, (2008).

Google Scholar

[11] A. Atkinson, S. Barnett, R. J. Gorte, J. T. S. Irvine, A. J. McEvoy, M. Mogensen, S. C. Singhal, and J. Vohs, Advanced anodes for high-temperature fuel cells,  Nature Materials 3, No. 1, (2004) 17-27.

DOI: 10.1038/nmat1040

Google Scholar

[12] A. Bieberle, The Electrochemistry of Solid Oxide Fuel Cell Anodes: Experiments, Modeling, and Simulations, Thesis for PhD in Technical Sciences, Swiss Federal Institute Tech., ZÜRICH.

Google Scholar

[13] M. Lo Faro, D. La Rosa, V. Antonucci and A. S. Arico, Intermediate temperature solid oxide fuel cell electrolytes, Journal of the Indian Institute of Science 89 (2009).

DOI: 10.1002/chin.201137207

Google Scholar

[14] S. C. Singhal, Science and technology of solid oxide fuel cells, Materials Research Bulletin 25 (2000) 16-21.

Google Scholar

[15] Y. Tanaka, A. Momma, K. Takano, T. Kato, Performance evaluation of anode-supported planar SOFC with precisely-simulated reformate gases, IOP conf. Series: Materials Science and Engineering 18 (2011) 132008.

DOI: 10.1088/1757-899x/18/13/132008

Google Scholar

[16] Y. Hao, Numerical study of heterogeneous reactions in an SOFC anode with oxygen addition, Journal of the Electrochemical Society, 155 (7) (2008) B666-B674.

DOI: 10.1149/1.2907763

Google Scholar

[17] J. H. Myuing, Performance improvement of oxide catalyst-doped anode-supported SOFCs for methane fuel, Electrochemical and Solid-State Letters, 13(4) (2010) B43-B45.

DOI: 10.1149/1.3302459

Google Scholar

[18] Y. Hao, Numerical modeling of single-chamber SOFCs with hydrocarbon fuels, Journal of The Electrochemical Society, 154 (2) (2007) B207-B217.

DOI: 10.1149/1.2404895

Google Scholar

[19] Y. Hag Koh, J. Jae Sun, W. Young Choi, H. Ee Kim, Design and fabrication of three-dimensional solid oxide fuel cells, Journal of Power Sources 161 (2006) 1023–1029.

DOI: 10.1016/j.jpowsour.2006.05.043

Google Scholar

[20] Li Zhou, Performance of an anode-supported tubular solid oxide fuel cell (SOFC) under pressurized conditions, Electrochemica Acta 53 (2008) 5195–5198.

DOI: 10.1016/j.electacta.2008.02.032

Google Scholar

[21] K. Chen, Fabrication and performance of anode-supported YSZ films by slurry spin coating, Solid State Ionics 177 (2007) 3455–3460.

DOI: 10.1016/j.ssi.2006.10.003

Google Scholar

[22] D. Dong, J. Gao, X. Liu, G. Meng, Fabrication of tubular NiO/YSZ anode-support of solid oxide fuel cell by gelcasting, Journal of Power Sources 165 (2007) 217–223.

DOI: 10.1016/j.jpowsour.2006.10.098

Google Scholar

[23] T. X. Ho, P. Kosinski, A. C. Hoffmann, A. Vik, Numerical analysis of a planar anode-supported SOFC with composite Electrodes, Int. J. Hydrogen Energy 34 (2009).

DOI: 10.1016/j.ijhydene.2009.02.016

Google Scholar

[24] Tanaka, Performance evaluation of anode-supported planar SOFC with precisely-simulated reformate gases, IOP conf. Series: Materials Science and Engineering 18 (2011) 132008.

DOI: 10.1088/1757-899x/18/13/132008

Google Scholar

[25] P. Chinda, Micro–scale modeling of an anode–supported planar solid oxide fuel cell, Fuel Cells 11 (2011) 184-199.

DOI: 10.1002/fuce.201000121

Google Scholar

[26] J. Yuan, Simulation and analysis of multi-scale transport phenomena and catalytic reactions in SOFC anodes, Chemical Product and Process Modeling 5 Iss. 1, Article 12.

DOI: 10.2202/1934-2659.1450

Google Scholar

[27] P. W. Li, M. K. Chyu, Simulation of the chemical/ electrochemical reactions and heat/mass transfer for a tubular SOFC in a stack, Journal of Power Sources 124 (2003) 487-498.

DOI: 10.1016/j.jpowsour.2003.06.001

Google Scholar

[28] M. M Hussain., Multi-Component and multi-dimensional mathematical modeling of solid oxide fuel cells, PhD thesis, (2008) Waterloo, Ontario, Canada.

Google Scholar

[29] F. Calise, M. Dentice d'Accadia, G. Restuccia, A detailed one dimensional finite-volume simulation model of a tubular SOFC and a pre-reformer, Int. J. of Thermodynamics 10 (No. 3) ( Sept. 2007) 87-96,.

Google Scholar

[30] D. Larrain, J. Van herle, D. Favrat, Simulation of SOFC stack and repeat elements including interconnect degradation and anode reoxidation risk, Journal of Power Sources 161 (2006) 392–403.

DOI: 10.1016/j.jpowsour.2006.04.151

Google Scholar

[31] B. Sundén, Modeling of heat and mass transfer and other transport phenomena in fuel cells, Frontiers in Heat and Mass Transfer (FHMT), 1, 013008 (2010).

DOI: 10.5098/hmt.v1.1.3008

Google Scholar

[32] L. Yixin, S. Laura, L. Peiwen, Numerical Simulation of Heat Transfer and Fluid Flow of a Flat-Tube High Power Density Solid Oxide Fuel Cell, Journal of Fuel Cell Science and Technology 2 (2005) 65-69.

DOI: 10.1115/1.1843120

Google Scholar

[33] S. C. Singhal, Solid oxide fuel cells for stationary, mobile, and military applications,  Solid State Ionics 152-153, (2002) 405-410.

DOI: 10.1016/s0167-2738(02)00349-1

Google Scholar

[34] E. Riensche, E. Achenbach, D. Froning, M. R. Haines, W. K. Heidug, A, Clean combined-cycle SOFC power plant-cell modelling and process analysis Journal of Power Sources, 86 (2000) 404-410.

DOI: 10.1016/s0378-7753(99)00490-5

Google Scholar

[35] K. Oulmi, H. Ben moussa, D. Haddad, Electrochemical energy conversion and storage (fuel cells), the 56th International society of electrochemistry, Bexco, Busan, Korea Sept 25–30 (2005).

Google Scholar

[36] S. Kakaç, A. Pramuanjaroenkij, X. Yang Zhou, A review of numerical of solid oxide fuel cells, International Journal of Hydrogen Energy, 18 (2006) 1-26.

Google Scholar

[37] SOFC mathematical model for systems simulations. Part one: from a micro-detailed to macro-blackbox model, International Journal of Hydrogen Energy, 30 (2005) 181-187.

DOI: 10.1016/j.ijhydene.2004.04.008

Google Scholar

[38] M. Andersson, J. Yuan, B. Sundén, Review on modeling development for multiscale chemical reactions coupled transport phenomena in solid oxide fuel cells, Applied Energy 87 (2010) 1461–1476.

DOI: 10.1016/j.apenergy.2009.11.013

Google Scholar

[39] M. Andersson, H. Paradis, J. Yuan, B. Sundén, Modeling analysis of different renewable fuels in an anode supported SOFC, Journal of Fuel Cell Science and Technology 8 (2011) 031013-1.

DOI: 10.1115/1.4002618

Google Scholar

[40] S. R. Pakalapati, A new reduced order model for solid oxide fuel cells, PhD thesis, Dept. Mechanical & Aerospace Engineering, West Virginia University (2006).

Google Scholar