Influence of Co on Strength of Cu-Ni-Co-Si Alloy

Article Preview

Abstract:

The effects of Co on the strength of Cu-Ni-Co-Si alloys have been investigated using Cu-2.0wt%Ni-0.5wt%Si (0%Co), Cu-1.4wt%Ni-0.6wt%Co-0.5wt%Si (0.6%Co) and Cu-1.0wt% Ni-1.0wt%Co-0.5wt%Si (1.0%Co) alloys produced by combining cold rolling to a 25% reduction with aging. Aging the 0.6%Co and 1.0%Co alloys at 525 and 425°C produces orthorhombic (Ni, Co)2Si precipitates that have the same crystal system as Ni2Si precipitates formed in the 0%Co alloy. The larger the amount of Co in the three alloys is, the higher the strength and electrical conductivity of the alloys initially aged at 525°C, rolled to a 25% reduction and re-aged at 425°C become. The increase in strength with increasing Co content is caused by both of the decrease in inter-precipitate spacing and increase in dislocation density. The increase in strength by re-aging at 425°C becomes more pronounced as the Co content increases. This arises because the larger the amount of Co is, the larger the difference between the equilibrium solubilities at 525 and 425°C becomes, the more the volume fraction of precipitates is increased by re-aging at 425°C.

You might also be interested in these eBooks

Info:

Periodical:

Materials Science Forum (Volumes 783-786)

Pages:

2468-2473

Citation:

Online since:

May 2014

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2014 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] H. Shishido, S. Katsura, K. Matsumoto, Y. Ariga, Copper alloy having high strength and excellent bending workability, Japan Patent 2011-052316 (2011).

Google Scholar

[2] N. Era, K. Fukamachi, Development of high strength corson alloy, J. JRICu 44 (2005) 136-139.

Google Scholar

[3] F. N. Mandigo, P. W. Robinson, D. E. Tyler, A. Boegel, H. A. Kuhn, F. M. Keppeler, J. Seeger, Copper alloy containing Co, Ni and Si, U. S. Patent 7, 182, 823 (2007).

Google Scholar

[4] C. Watanabe, H. Hiraide, Z. Zhang, R. Monzen, Microstructure and mechanical properties of Cu-Ni-Si alloys, J. Soc. Mat. Sci. 54 (2005) 717-723.

DOI: 10.2472/jsms.54.717

Google Scholar

[5] T. Kunieda, M. Nakai, Y. Murata, T. Koyama, M. Morinaga, Estimation of the system free energy of martensite phase in an Fe-Cr-C ternary alloy, ISIJ International 45 (2005) 1909-(1914).

DOI: 10.2355/isijinternational.45.1909

Google Scholar

[6] S. A. Lockyer, F. W. Noble, Precipitate structure in a Cu-Ni-Si alloy, J. Mater. Sci. 29 (1994) 218-226.

DOI: 10.1007/bf00356596

Google Scholar

[7] S. A. Lockyer, F. W. Noble, Fatigue of precipitate strengthened Cu-Ni-Si alloy, Mater. Sci. Technol. 15 (1999) 1147-1153.

DOI: 10.1179/026708399101505194

Google Scholar

[8] J. W. Martin, Micromechanisms in Particle-Hardened Alloys, 1st ed., Cambridge University Press in Cambridge, New York, 1980, pp.44-56.

Google Scholar

[9] Y. Takagawa, Y. Tsujiuchi, C. Watanabe, R. Monzen, Improvement in mechanical properties of a Cu-2. 0mass%Ni-0. 5mass%Si-0. 1mass%Zr alloy by combining both accumulative roll-bonding and cryo-rolling with aging, Mater. Trans. 54 (2013) 1-8.

DOI: 10.2320/matertrans.m2012207

Google Scholar

[10] S. Komatsu, Resistivity of copper alloys, its interpretation and application, J. JRICu 41 (2002) 1-9.

Google Scholar

[11] H. Fujiwara, Design of high strength copper alloys based on the crystal structure of precipitate, Furukawa Review, 114 (2004) 32-37.

Google Scholar

[12] J. E. Bailey, P. B. Hirsch, The dislocation distribution, flow stress, and stored energy in cold-worked polycrystalline Ag, Philos. Mag. 5 (1960) 485-497.

DOI: 10.1080/14786436008238300

Google Scholar

[13] T. Narutani, J. Takamura, Grain-size strengthening in terms of dislocation density measured by resistivity, Acta Metall. Mater. 39 (1991) 2037-(2049).

DOI: 10.1016/0956-7151(91)90173-x

Google Scholar

[14] A. J. Ardell, Further application of the theory of particle coarsening, Acta Metall. 15 (1967) 1772-1775.

DOI: 10.1016/0001-6160(67)90073-9

Google Scholar

[15] C. Watanabe, R. Monzen, Coarseing of d-Ni2Si precipitates in a Cu-Ni-Si alloy, J. Mater. Sci. 46 (2011) 4327-4335.

DOI: 10.1007/s10853-011-5261-x

Google Scholar