Modification Effects of Sb on Al7SiMg Alloy Measured with Cooling Curve Analysis

Article Preview

Abstract:

The modification mechanism of Sb on eutectic Si phase of Al-Si alloys was not understood very well. In this paper the modification effects of Sb on Al7SiMg alloy were investigated by computer aided cooling curve thermal analysis coupled with microstructure observation. The results show that the addition of Sb with 0.1%~0.25% amount has refining effect on eutectic Si phase, and this modification effect can be recorded by the cooling curve. The addition of Sb decreases the growth temperature of the eutectic solidification (TEG) by 5.0 °C to 7.8 °C, and this indicates that there is an undercooling effect with Sb modification. Moreover, faster cooling rate can obtain more superior morphology of eutectic Si, which can be changed from short rod to nearly granular particles. The morphology of eutectic Si is nearly unchanged with holding time extending from 0.5h to 2.5h, which means Sb has long modification effect for Al-Si alloys.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

2113-2118

Citation:

Online since:

November 2016

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2017 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] O. Uzun, F. Yilmaz, Sb effect on micro structural and mechanical properties of rapidly solidified Al-12Si alloy, Journal of Alloys and Compounds. 509 (2011) 21-26.

DOI: 10.1016/j.jallcom.2010.09.037

Google Scholar

[2] X.G. Qi, J.H. Chen, X.B. Jiang. Heterogeneous nucleation of eutectic silicon modified with Sb, Special Casting & Nonferrous Alloys (in Chinese), 1 (2000) 13-15.

Google Scholar

[3] S. Yaneva, L. Stojanova, N. Stoichev, Z. Kamenova, On the mechanism of Al-Si alloy structure modification by metal antinomy, Crystal Research and Technology. 23 (1988) 475-480.

DOI: 10.1515/9783112485422-002

Google Scholar

[4] S.S. Wu, Y. Zeng, Y.W. Mao, Thermal analysis on modification effect of primary silicon in high-silicon aluminum alloys, Foundry (in Chinese). 58 (2009) 315-318.

Google Scholar

[5] S.H. Lu, A. Hellawell, The mechanism of silicon modification in Aluminum-Silicon alloys: impurity induced twinning, Metal Trans A. 18A (1987) 1721-1733.

DOI: 10.1007/bf02646204

Google Scholar

[6] K. Nogita, S.D. McDonald, A.K. Dahle, Eutectic modification of Al-Si alloys with rare earth metals, Materials Transactions. 45 (2004) 323-326.

DOI: 10.2320/matertrans.45.323

Google Scholar

[7] S.C. Flood, J.D. Hunt, Modification of Al-Si eutectic alloys with Na, Metal Science. 15 (1981) 287-294.

DOI: 10.1179/030634581790426813

Google Scholar