Selective Electrolytic Corrosion Behaviours of WC in WC-Co Cemented Carbide

Article Preview

Abstract:

In this work, WC grains in WC-Co cemented carbide were selectively electrolytic corroded and the effects of corrosion time, WC mean grain size and Co content on corrosion rate were systematically investigated. The results showed that corrosion rate decreased with the prolonging of electrolytic corrosion time. The WC-9Co cemented carbides had grain size of 2.9 μm The intensity of Co diffraction peaks was found to exceed the WC diffraction peaks when corroded for 4 hours, and the WC diffraction peaks disappeared when corroded for 8 hours. The corrosion rate increased with the decrease of WC mean grain size and the Co content. As the WC content increased in cemented carbide, it was necessary to increase corrosion time when analyzed Co phase in the cemented carbide by X-ray diffraction.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

1478-1484

Citation:

Online since:

June 2017

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2017 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] L. Yan, C.G. Lin, R.J. Cao, Research status and prospect of nanometer cobalt powder for ultrafine WC-Co hard Alloys, Rare Metals. 35 (2011) 451-457.

Google Scholar

[2] Z.G. Fang, J.W. Eason, Study of nanostructured WC–Co composites, Int. J. Refract. Met. Hard Mater. 13 (1995) 297–303.

Google Scholar

[3] K. Brookes, Some tribulation on the way to a nano future for hard metals, Met. Powder. Rep. 60 (2005) 24–30.

Google Scholar

[4] S.X. Zhao, X.Y. Song, J.X. Zhang, X.M. Liu, Effects of size matching of raw powder particles on properties of spark plasma sintered ultrafine WC–Co cemented carbides, Acta Metall. Sin. 43 (2007) 107–112.

Google Scholar

[5] H.O. Andren, U. Rolander, P. Lindahl, Phase composition in cemented carbides and cermets, Int. J. Refract. Met. H. 12(1993) 107-113.

DOI: 10.1016/0263-4368(93)90059-o

Google Scholar

[6] H.O. Andren, Microstructure development during sintering and heat-treatment of cemented carbide and cermets, Int. J. Refract. Met. H. 67 (2001) 209-213.

Google Scholar

[7] J. Zhou, Structure and property of vacuum heat treatment of cemented carbide and its application, Mat. Sci. Eng. Power. Met. 03 (2000) 222-225.

Google Scholar

[8] H. Jonsson, Studies of the binder phase in WC-Co cemented carbide heat-treated at 650 C, Power Metall. 15 (1972) 1-10.

DOI: 10.1179/pom.1972.15.29.001

Google Scholar

[9] D. Thakur, B. Ramamoorthy, L. Vijayaraghavan, Influence of different post treatments on tungsten carbide–cobalt inserts, Mater. Lett. 62 (2008) 4403-4406.

DOI: 10.1016/j.matlet.2008.07.043

Google Scholar

[10] S.S. Gill, R. Singh, H. Singh, Wear behaviour of cryogenically treated tungsten carbide inserts under dry and wet turning conditions, Int. J. Mach. Tool. Manu. 49 (2009) 256-260.

DOI: 10.1016/j.ijmachtools.2008.11.001

Google Scholar

[11] Z.H. Chen, J. Yong, F. Lian, Influence of cryogenic treatment on microstructure and properties of WC-Co cemented carbides, T. Mater. Heat. Treat. 32 (2011) 26-30.

Google Scholar

[12] H. Zhang, L. Chen, J. Sun, Influence of deep cryogenic treatment on microstructures and mechanical properties of an ultrafine-grained WC-12Co cemented carbide, Acta. Metall. Sin. 27 (2014) 894-900.

DOI: 10.1007/s40195-014-0134-3

Google Scholar

[13] Y. Jiang, D. Chen, Effect of cryogenic treatment on WC–Co cemented carbide, Mat. Sci. Eng. A. 528 (2011) 1735-1739.

Google Scholar

[14] H.Y. Shi, X-ray diffraction of low content of cobalt in cemented carbide-Electrolytic selective etching WC method, Physical Testing and Chemical Analysis(Part A: Physical Testing). 4 (1994) 35-36.

Google Scholar

[15] M.D. Xiao, W. Xiao, J.L. Jiang, Cobalt phase structure of cemented carbide, Mat. Sci. Eng. Power. Met. 15 (2010) 611-614.

Google Scholar

[16] J.S. Huang, X.Y. Wu, J.C. Li, X-ray diffraction method used in measuring the cobalt phase composition in cemented carbide, Cemented Carbide. 20 (2003) 109-112.

Google Scholar

[17] D. Li, Principles of electrochemistry, Third ed., Beijing University of Aeronautics and Astronautics Press, Beijing, (2008).

Google Scholar