Combustion Microstructures and Frictional Ignition Resistance of Ti-6Al-4V Titanium Alloy

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The effects of the contact pressure Pfric and the oxygen concentration c0 on the ignition resistance of Ti-6Al-4V were studied by friction in oxygen-enriched atmosphere. The relationship of Pfric-c0 was built to quantitatively describe the ignition resistance, the combustion microstructures were investigated by XRD, SEM and EDS. Further, the principle of improving the ignition resistance was proposed. It indicates that the relationship of Pfric-c0 obeys parabolic law. The c0 decreases by 4% when the Pfric increases from 0.1MPa to 0.25MPa, manifesting that the ignition resistance depends on c0 strongly (or equivalent flow pressure Peq). The ignition resistance of Ti-6Al-4V is 42.9% of that of TB12. When Peq varies from 0.1~0.5MPa, the critical ignition temperature Т* is approximate to 568~461K. Violent sparks form during frictional ignition. The low ignition resistance of Ti-6Al-4V probably results from not only the composite oxides of TiO2, Al2O3 and V2O5 generating during ignition which could not prevent the rapid interaction between Ti and O, but also the Al and V elements in the heat-affected zone which could not stop or slow the massive diffusion of O towards the alloy.

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127-134

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January 2019

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© 2019 Trans Tech Publications Ltd. All Rights Reserved

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[1] Borisova Y A, Sklyarov N M. Aviation materials and technology: Combustion and fire resistance of titanium alloys. Moscow: VIAM, 2007: 5−21.

Google Scholar

[2] Chen G. Structure design and analysis of aero-engine: frequent engine failure induced by titanium fire (2nd edition). Beijing: Beijing University of Aeronautics and Astronautics Press, 2014: 636-640.

Google Scholar

[3] Uihlein T, Schlegel H. Titanium fire in jet engines. Germany: MTU Motoren-Und Turbinen-Union Munchen GmbH, (1995).

Google Scholar

[4] Steve T, Craig W. Light weight, high strength, and corrosion resistance are required of titanium and niobium alloys for aerospace application. Advanced materials and Processes, 1995(4): 23-26.

Google Scholar

[5] Lütjering G, Williams J C. Titanium (2nd edition).New York: Springer Berlin Heidelberg, 2007: 390-391.

Google Scholar

[6] Anderson V, Manty B. Titanium alloy ignition and combustion. Florida: Pratt & Whitney Aircraft Group, Report No. 76083-30 (Naval Air Development Center), 1978: 10-32.

Google Scholar

[7] Mi G B, Huang X, Cao J X, et al. A test method characterizing the fireproof performance of titanium alloys for aero-engine: China Patent, ZL201218003649.0, 2012-09-04.

Google Scholar

[8] Mi G B, Huang X, Cao J X, et al. Ignition resistance performance and its theoretical analysis of Ti-V-Cr type fireproof titanium alloy. Acta Metallurgica Sinica, 2014, 50(5): 575-586.

Google Scholar

[9] Mi G B, Huang X, Cao J X, et al. Frictional ignition of Ti40 fireproof titanium alloys for aero-engine in oxygen-containing media. Trans Nonferrous Met Soc China, 2013, 23(8): 2270-2275.

DOI: 10.1016/s1003-6326(13)62728-4

Google Scholar

[10] Mi G B, Cao C X, Huang X, et al. Ignition resistance performance and its mechanism of TC11titanium alloy for aero-engine. Journal of Aeronautical Materials, 2014, 34(4): 83-91.

Google Scholar

[11] Mi G B, Huang X, Cao J X, et al. Theoretical research on oxide film fracture behavior during titanium ignition. Journal of Aeronautical Materials, 2012, 32(6): 25-31.

Google Scholar

[12] Mi G B, Huang X S, Li P J, et al. Non-isothermal oxidation and ignition prediction of titanium-chromium alloys. Trans Nonferrous Met Soc China, 2012, 22(10): 2409-2415.

DOI: 10.1016/s1003-6326(11)61478-7

Google Scholar

[13] Littman F E, Church F M, Kinderman E M. A Study of metal ignitions .1. the spontaneous ignition of titanium. Journal of the Less-Common Metals, 1961(3): 367-378.

DOI: 10.1016/0022-5088(61)90012-1

Google Scholar

[14] Khaikin B I, Bloshenko V N, Merzhanov A G. On the ignition of metal particles. Combustion, Explosion and Shock Waves, 1970, 6(4): 412-422.

DOI: 10.1007/bf00742774

Google Scholar

[15] Lyakishev N P. State diagram of a binary metal system. Moscow: Engineering, 1996: 397−399.

Google Scholar