Preparation of EVA Emulsion Self-Healing Capsules for Concrete and Evaluation of Healing Properties

Article Preview

Abstract:

The self-healing capsule was prepared with paraffin as wall and EVA (ethylene vinyl acetate) emulsion as core through melting condensation dispersion method. The morphology and chemical structure of capsules were characterized by optical microscope and Fourier transform infrared spectroscopy (FTIR). The influence of the stirring rate and emulsion to paraffin ratio on core content of the capsule was investigated. The flexural strength of mortar incorporated with capsules was tested to assess the effect of capsule on mechanical property. In addition, the compressive strength of the mortar was tested before and after self-healing to evaluate the healing efficiency of the capsule. The result showed that the highest core content of the capsule can reach up to 55% under the conditions that stirring rate was 400 rpm and emulsion to paraffin ratio was 1:1. FTIR and optical micrograph of the capsule indicated that the EVA emulsion was contained in paraffin successfully. The dosage of capsules had little effect on mechanical properties of mortar when it was less than 5 wt%. The healing efficiency of mortar for compressive strength was up to 99% at capsule content of 5 wt%, preload of 60% fmax and curing time of 7 days, which meant that the microcracks can be healed efficiently with the EVA emulsion capsule.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

736-744

Citation:

Online since:

January 2019

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2019 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] Chen M C, Wang K, Xie L. Deterioration of cement-concrete cementitious materials under acid rain attack and its evaluation—effect of Acid Rain Components [J]. Building Science, 28 (2012) 20-24.

Google Scholar

[2] Zhang S, Dong X, Zhang H, et al. Research on deterioration mechanism of concrete materials in an actual structure [J]. Advances in Materials Science & Engineering, 2014 (2014) 1-6.

DOI: 10.1155/2014/306459

Google Scholar

[3] Hori M, Morihiro H. Micromechanical analysis on deterioration due to freezing and thawing in porous brittle materials [J]. International Journal of Engineering Science, 36 (1998) 511-522.

DOI: 10.1016/s0020-7225(97)00080-3

Google Scholar

[4] Zha Y, Yu J, Wang R, et al. Improvement on freeze-Thaw resistance of cement-based materials by functional admixtures[C]. Chinese Materials Conference. Springer, Singapore, (2017) 617-626.

DOI: 10.1007/978-981-13-0158-2_63

Google Scholar

[5] Mihashi H, Nishiwaki T. Development of engineered self-healing and self-repairing concrete-state-of-the-art report [J]. ACT, 10 (2012) 170-184.

DOI: 10.3151/jact.10.170

Google Scholar

[6] Jiang Z, Li W, Yuan Z. Influence of mineral additives and environmental conditions on the self-healing capabilities of cementitious materials [J]. Cement & Concrete Composites, 57 (2015) 116-127.

DOI: 10.1016/j.cemconcomp.2014.11.014

Google Scholar

[7] Kondō A. Microcapsule processing and technology [M]. Dekker, New York, (1979).

Google Scholar

[8] White S R, Sottos N R, Geubelle P H, et al. Autonomic healing of polymer composites [J]. 415 (2002) 817-817.

DOI: 10.1038/415817a

Google Scholar

[9] Ming Z, Chen L K, Feng X, et al. Study on properties of microcapsule system for self-healing cementitious composite[J]. Journal of Building Materials, 16 (2013) 903-907.

Google Scholar

[10] Dong B, Han N, Zhang M, et al. A microcapsule technology based self-healing system for concrete structures [J]. Journal of Earthquake & Tsunami, 7 (2013) 135-137.

DOI: 10.1142/s1793431113500140

Google Scholar

[11] Li W, Zhu, et al. Preparation and properties of melamine urea-Formaldehyde microcapsules for self-Healing of cementitious materials [J]. Materials, 9 (2016) 152.

DOI: 10.3390/ma9030152

Google Scholar

[12] Li W, Jiang Z, Yang Z, et al. Self-healing efficiency of cementitious materials containing microcapsules filled with healing adhesive: mechanical restoration and healing process monitored by water absorption [J]. Plos One, 8 (2013) 78-83.

DOI: 10.1371/journal.pone.0081616

Google Scholar

[13] Lv L, Yang Z, Chen G, et al. Synthesis and characterization of a new polymeric microcapsule and feasibility investigation in self-healing cementitious materials[J]. Construction & Building Materials, 105 (2016) 487-495.

DOI: 10.1016/j.conbuildmat.2015.12.185

Google Scholar

[14] Chen X, Wu S, Zhou J. Influence of porosity on compressive and tensile strength of cement mortar[J]. Construction & Building Materials, 403 (2013) 869-874.

DOI: 10.1016/j.conbuildmat.2012.11.072

Google Scholar