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HomeMaterials Science FoundationsMaterials Science Foundations Vols. 81-82Crystal-Chemical Aspects of the Stability of the...

Crystal-Chemical Aspects of the Stability of the Ordered Phase B2 in Volume Alloying of TiNi

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Abstract:

The phenomenological approach based on analysis the crystal-chemical parameters and their change depending on concentration of the alloying element for definition of concentration intervals of existence of stable phases with ordered structures in the ternary Titanium Nickelide based alloys is described. It was shown that a comparison of the data of change patterns in crystal-chemical parameters phenomenologically predicted and obtained from experimental data, allows to predict some of the conditions of stabilization in the examined phase, the solubility limits of alloying elements and, consequently, its homogeneity region, as well as formation conditions of multiphase systems. The analysis carried out allows us to make a conclusion regarding the issue that is often discussed in the analysis of phase diagrams of binary and multicomponent systems - what is the ratio of the size and electronic contributions to the stability of the phases. It was shown that the contribution of the size factor to the stabilization of B2 and B19(or В19′) phases is predominant and the role of this factor grows with the increase in the amount of the alloying element.

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Materials Science Foundations (Volumes 81-82)

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554-574

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https://doi.org/10.4028/www.scientific.net/MSFo.81-82.554

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Online since:

March 2015

Authors:

Ludmila Meisner*

Keywords:

Alloying, Atomic Volume, B2-BCC Ordered Structure, Crystal-Chemical Factors, Electron Density, Electronegativity, Hume-Rothery Size Effect, Martensitic Transformation (MT), Ternary TiNi Based Alloys, Titanium Nickelide, Vegard (Zen) Law

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