Electrical/Mechanical Properties of Porous Low-k Thin Films by Using Various Supramolecule Based Porogen

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The porous SSQ (silsesquioxane) films were prepared by using alkoxy silyl substituted cyclodextrin (sCD) and methyl substituted cyclodextrin (tCD) based porogen. The mechanical and electrical properties of these deposited films were investigated for the applications as low dielectric materials. The mechanical properties of porous film by using sCD are worse than those by using tCD due to its high pore interconnection length. sCD templated porous films show almost constant pore diameter as a function of porogen concentration due to strong linear polymerization of the sCD molecules through polycondensation.

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Solid State Phenomena (Volumes 124-126)

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185-188

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June 2007

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© 2007 Trans Tech Publications Ltd. All Rights Reserved

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[1] J. L Hedrick, R. D. Miller, C. J. Hawker, K. R. Carter, W. Volksen, D. Y. Yoon, M. Trollsas, Adv. Mater. Vol. 10 (1998), p.1049.

Google Scholar

[2] J. H. Yim, M. R. Baklanov, D.W. Gidley, H. Peng, H. D. Jeong, and Y.S. Pu, J. Phys. Chem. B. Vol. 108 (2004), p.8953.

Google Scholar

[3] S. Yang, P. A. Mirau, C. Pai, O. Nalamasu, E. Reichmanis, J. C. Pai, Y. S. Obeng, J. Seputro, E. K. Lin, H. Lee, J. Sun, D. W. Gidley, Chem. Mater. Vol. 14(2002), p.369.

DOI: 10.1021/cm010690l

Google Scholar

[4] J. H. Yim, H. D. Jeong, Y. S. Pu, Thin Solid Films Vol. 476 (2005), 46.

Google Scholar

[5] J. H Yim, Y. Y. Lyu, H. D. Jeong, S. A. Song, I. S. Hwang, J. Hyeon-Lee,; S. K. Mah, S. Chang, J. G. Park, Y. F. Hu, J. N. Sun, D. W. Gidley, Adv. Funct. Mater. Vol. 13/5 (2003), 382.

DOI: 10.1002/adfm.200304287

Google Scholar

[6] J. H. Yim, J. B. Seon, H.D. Jeong, Y. S. Pu, M. R. Baklanov, D. W. Gidley, Adv. Funct. Mater. Vol. 14/3 (2004), p.277.

DOI: 10.1002/adfm.200305019

Google Scholar

[7] J. B. Lambert, C. Liu, M. T. Boyne, A. P. Zhang, and Y. Yin, Chem. Mater. Vol. 15 (2003), p.131.

Google Scholar

[8] J. H. Yim, Y. Y. Lyu, H. D. Jeong, S. K. Mah, J. Hyeon-Lee, J. H. Hahn, G. S. Kim, S. Chang., J. G. Park, J. Appl. Polym. Sci. Vol. 90 (2003), p.626.

Google Scholar

[9] Y. Y. Lyu, J. H. Yim, Y. Byun, S. Y. Lee, I. S. Jung, L. S. Pu, Euro. Polym. J. Vol. 40 (2004), p.2505.

Google Scholar

[10] D. W. Gidley, W. E. Frieze, T. L. Dull, J. Sun, A. F. Yee, C. V. Nguyen and D. Y. Yoon, Appl. Phys. Lett. Vol. 76/10 (2000), p.1282.

DOI: 10.1063/1.126009

Google Scholar

[11] W. C. Oliver, G. M. Pharr, J. Mat. Res. Vol. 7 (1992), p.1564.

Google Scholar