Formation of Hydrogen-Related Shallow Donors in Ge1-xSix Crystals Implanted with Protons

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It is found that shallow hydrogen-related donors are formed in proton-implanted dilute Ge1-хSiх alloys (0 ≤ x ≤ 0.031) as well as in Si-free Ge samples upon heat-treatments in the temperature range 225-300oC. The maximum concentration of the donors is about 1.5×1016 cm-3 for a H+ implantation dose of 1×1015 cm-2. The temperature range of formation of the protonimplantation- induced donors is the same in Ge1-xSix samples with different Si concentration. However, the increase in Si content results in a decrease of the concentration of the hydrogenrelated donors. It is argued that the H-related donors could be complexes of Ge-self-interstitials with hydrogen atoms. The observed decrease in the concentration of the donors with an increase in Si content in the Ge1-xSix samples is associated with interactions of mobile hydrogen atoms with Si impurity atoms. Such interactions reduce the number of implanted hydrogen atoms that can be involved in defect reactions resulting in the formation of H-related shallow donors.

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Solid State Phenomena (Volumes 131-133)

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131-136

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October 2007

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© 2008 Trans Tech Publications Ltd. All Rights Reserved

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[1] S.J. Pearton, J.W. Corbett and M. Stavola: Hydrogen in Crystalline Semiconductors (Springer, Berlin 1992).

Google Scholar

[2] S.K. Estreicher: Materials Science and Engineering Vol. R14 (1995) p.314.

Google Scholar

[3] B. Aspar, M. Bruel, H. Moriceau, C. Maleville, T. Poumeyrol, A.M. Papon, A Claverie, G. Benassayag, A.J. Auberton-Herve and T. Barge.: Microelectronic Engineering Vol. 36 (1997) P. 233.

DOI: 10.1016/s0167-9317(97)00055-5

Google Scholar

[4] Q. -Y. Tong, K. Gutjahr, S. Hopfe, U. Gösele and T.H. Lee: Appl. Phys. Lett. Vol. 70 (1997) p.1390.

Google Scholar

[5] T. Akatsu et al.: Materials Science in Semiconductor Processing Vol. 9 (2006) p.444.

Google Scholar

[6] L. Dobaczewski, K. Bonde Nielsen, N. Zangenberg, B. Bech Nielsen, A.R. Peaker and V.P. Markevich: Phys. Rev. B Vol. 69 (2004) p.245207.

DOI: 10.1103/physrevb.70.079901

Google Scholar

[7] Ju.M. Pokotilo, A.N. Petukh, V.V. Litvinov, V.P. Markevich and N.M. Kazuchits: Materials Science in Semiconductor Processing Vol. 9 (2006) p.629.

DOI: 10.1016/j.mssp.2006.08.012

Google Scholar

[8] L. Dobaczewski, A.R. Peaker and K. Bonde Nielsen: J. Appl. Phys. Vol. 96 (2004) p.4689.

Google Scholar

[9] K. Bonde Nielsen, B. Bech Nielsen, J. Hansen, E. Andersen and J.U. Andersen: Phys. Rev. B Vol. 60 (199) p.1716.

Google Scholar

[10] C. Herring, N.M. Johnson and C.G. Van de Walle: Phys. Rev. B Vol. 64 (2001) p.125209.

Google Scholar

[11] C.G. Van de Walle and J. Neugebauer: Nature Vol. 423 (2003) p.626.

Google Scholar

[12] N.V. Abrosimov, S.N. Rossolenko, W. Thieme, A. Gerhardt and W. Schröder: J. Cryst. Growth Vol. 174 (1997) p.182.

Google Scholar

[13] D.V. Lang: J. Appl. Phys. 45 (1974) 3023.

Google Scholar

[14] A.R. Peaker, V.P. Markevich, F.D. Auret, L. Dobaczewski and N.V. Abrosimov: J. Phys.: Condens. Matter 17 (2005) p. S2293.

DOI: 10.1088/0953-8984/17/22/018

Google Scholar

[15] B.N. Mukashev, Kh.A. Abdullin and Yu.V. Gorelkinskii: Physics-Uspekhi Vol. 2 (2000) p.143.

Google Scholar

[16] Ju.M. Pokotilo, A.N. Petukh, V.V. Litvinov and B.G. Tsvirko: Semiconductors Vol. 7 (2005) p.768.

Google Scholar

[17] M. Budde, B. Bech Nielsen, P. Leary, J. Goss, R. Jones, P.R. Briddon, S. Öberg and S.J. Breuer: Phys. Rev. B Vol. 57 (1998) p.4397.

DOI: 10.1103/physrevb.57.4397

Google Scholar

[18] M. Budde, B. Bech Nielsen, J.C. Keay and L.C. Feldman: Physica B Vol. 273-274 (1999) p.208.

DOI: 10.1016/s0921-4526(99)00448-2

Google Scholar

[19] V.P. Markevich, I.D. Hawkins, A.R. Peaker, V.V. Litvinov, L.I. Murin, L. Dobaczewski and J.L. Lindström: Appl. Phys. Lett. 81 (2002) 1821.

DOI: 10.1063/1.1504871

Google Scholar

[20] V.P. Markevich, I.D. Hawkins, A.R. Peaker, K.V. Emtsev, V.V. Emtsev, V.V. Litvinov, L.I. Murin, L. Dobaczewski: Phys. Rev. B. 70 (2004) 235213.

DOI: 10.1103/physrevb.70.235213

Google Scholar

[21] J. Coutinho, R. Jones, V.J.B. Torres, M. Barroso, S. Öberg and P.R. Briddon: J. Phys.: Condens. Matter 17 (2005) L521.

DOI: 10.1088/0953-8984/17/48/l02

Google Scholar

[22] J. Coutinho, S. Öberg, V.J.B. Torres, M. Barroso, R. Jones and P.R. Briddon: Phys. Rev B 73 (2006) 235213.

Google Scholar

[23] J. Coutinho, V.J.B. Torres, R. Jones, A. Carvalho, S. Öberg and P.R. Briddon: Appl. Phys. Lett. 88 (2006) 091919.

DOI: 10.1063/1.2181202

Google Scholar

[24] R.N. Pereira, B. Bech Nielsen, J. Coutinho, V.J.B. Torres and P.R. Briddon: Appl. Phys. Lett. Vol. 88 (2006) p.142112.

DOI: 10.1063/1.2193802

Google Scholar