Functional Nanostructured Tribotechnical Materials

Abstract:

The paper describes the tribotechnical properties of thin-film coatings obtained by the tribotechnical modification of 40X grade steel with different organic and inorganic tribotechnical materials (natural inorganic and artificial polymers), as well as with composite materials based on vermiculite. Comparative tribotechnical investigations revealed that composites possess better tribotechnical properties than single-component materials. The most promising materials for the tribotechnical modification of steel friction surfaces are vermiculite-based nanostructured composites that provide minimal friction coefficient and high wear resistance under the conditions of boundary friction. The tribotechnical properties of polymagnesiumphenylsiloxane are a little worse than that of the materials based on vermiculite. Polymagnesiumphenylsiloxane and nanostructured composites based on vermiculite can be used as additives to motor oils and solid lubricants, as well as for the modification of friction surfaces during manufacturing or reconditioning of machine parts to increase their durability.

• Periodical: Solid State Phenomena (Volume 265)
• Pages: 410-415
• DOI: https://doi.org/10.4028/www.scientific.net/SSP.265.410
• Online since: September 2017
• Authors: L.B. Leontiev*, Nikolai Shapkin, V.N. Makarov
• Keywords: Coating, Composite, Friction, Modification, Vermiculite, Wear

References

[1] V.V. Zuyev, Usage of minerals as friction modifiers, J. Obogascheniye rud., 3 (1993) 33-37.

[2] S.Y. Lazarev, S.B. Tokmanev, V.B. Khmelevskaya, Criteria for selection of natural minerals and other substances for coatings of various purposes, J. Metalworking, 33 (2006) 29-35.

[3] L.I. Pogodayev, A.A. Kuzmin, Structure-Energy Models for Reliability of Materials and Equipment, Saint-Petersburg State University for Waterway Communications, Saint-Petersburg, (2010).

[4] D.N. Lyubimov, K.N. Dolgopolov, A.T. Kozakov, A.V. Nikolsky, Improvement of performance characteristics of lubricants, J. Friction and Wear, 6 (2011) 585-595.

[5] L.B. Leont'ev, N.P. Shapkin, A.L. Leont'ev, A.G. Toklikishvili, Optimization of composition of mineral and organic-mineral materials for modification of friction surfaces of machine parts, J. Metalworking, 4 (2012) 74-78.

[6] L.B. Leont'ev, N.P. Shapkin, A.L. Leont'ev, N.V. Makarov, Peculiarities of formation of wear-resistant metal-ceramic coating on friction surfaces of steel parts, J. Metalworking, 6 (2014) 41-51.

[7] N.P. Shapkin, L.B. Leont'ev, A.L. Leont'ev, et al., Organo-modified aluminum silicates as geomodifiers of friction, Journal of Applied Chemistry, 85 (2012) 1509-1513.

[8] O.Y. Golubeva, E.N. Korytkova, V.V. Gusarov, Hydrothermal Synthesis of Magnesium Silicate Montmorillonite for Polymer-Clay Nanocomposites, Journal of Applied Chemistry, 78(1) (2005) 26-32.

DOI: 10.1007/s11167-005-0225-z

[9] O.Y. Golubeva, O.S. Domanova, V.L. Ugolkov, V.V. Gusarov, Hybrid nanostructures on the basis of layered silicates and nitrogen-containing organic compounds, Journal of General Chemistry, 77(2) (2007) 246.

DOI: 10.1134/s1070363207020065

[10] M. Jaber, J. Miehe-Brenble, M. Roux, A new Al-Mg-Organoclay, New Journal of Chemistry, 26 (2002) 1597-1600.

[11] T.F. Grigoryeva, T.A. Vorsina, A.P. Barinova, V.V. Boldyrev, Mechanochemical synthesis of dispersive layered composites on the basis of kaolinite and some organic and inorganic acids, J. Inorganic Materials, 32 (1996) 214-220.

[12] N.P. Shapkin, V.Y. Mayorov, L.B. Leontyev, Investigation of sorption properties of modified layered silicate, J. Colloid Journal, 76(6) (2014) 798.

[13] N.P. Shapkin, I.G. Khalchenko, V.I. Razov, Investigation of structure of modofied vermiculites by various physical and chemical methods, J. Chemical Industry Today, 9 (2014) 10.

[14] S. Sinha Ray, M. Bousmina, Biodegradable polymers and their layered silicate nanocomposites, J. Progress in Materials Science, 50 (2005) 962.

DOI: 10.1016/j.pmatsci.2005.05.002

[15] O. Collart, P. Vander Voort, E.F. Vansant, E. Gustin, A. Bouwen, D. Schoemarkos, R.R. Rao, B.M. Weckhuysen, R.A. Schoonheydt, Spectroscopic characterization of an MoOx layer on the surface of silica. An evaluation of the molecular designed dispertion method, J. Phys. Chem., 1 (1999).

DOI: 10.1039/a903110c

[16] S. Chang, R. Doong, Chemical-composition-dependent metastability of tetragonal ZrO2 in sol- gel derived films under different calcinations conditions, J. Chem. Mater, 17 (2005) 4837-4844.

DOI: 10.1021/cm051264t

[17] G.E. Selutin, A.P. Puzyr, V.A. Voroshilov, V.S. Bondar, The application of modified nanodiamonds to increase the time of work of friction, J. Proceedings of Russian scientific-research technological Institute of repair and operation mashinno-tractor Park, Moscow, 106 (2010).

[18] Y.A. Shchipunov, A. Kojima, T. Jmae, Polysaccharides as template for silicate generated by sol-gel processes, J. Colloid Interface Sci., 285 (2005) 574–579.

DOI: 10.1016/j.jcis.2004.11.026

[19] F. Li, X.M. Li, S.S. Zhang, One-pot preparation of silica-supported hybrid immobilized metal affinity adsorbent with macroporous surface based on surface impritting coating technique combained with polysaccharide incorporated sol-gel process, J. Chromatography A., 1129 (2006).

DOI: 10.1016/j.chroma.2006.07.009

[20] O. Yu. Golubeva, O.S. Domanova, V.L. Ugolkov, V.V. Gusarov, Hybrid nanostructures based on layered silicates and nitrogen-containing organic compounds, Journal of General chemistry, 2(77) (2002) 246-251.

DOI: 10.1134/s1070363207020065

[21] T. Iton, N. Ohta, T. Shichi, T. Yui, K. Tagaki, The self-assembling properties of stearate ions in hydrotalcite clay composites, J. Langmuir, 19 (2003) 9120-9126.

DOI: 10.1021/la0302448

[22] P. Vander Voort, M.B. Mitchell, E.F. Vansant, The uses of polynuclear complexes to develop designed dispersions of supported metaloxides, J. Interface Science, 5 (1997) 169-197.

[23] N.P. Shapkin, A.A. Kapustina, S.V. Gardionov, I.G. Khalchenko, Interation of polyphenylsiloxane, Russian Journal of General Chemistry, 6(85) (2015) 1487-1490.

DOI: 10.1134/s1070363215060225

[24] N.P. Shapkin, J.N. Kulchin, V.I. Razov, S.S. Voznesensky, Investigation of polyphenyl-polyvinilsiloxanes of methods X-ray diffraction, positron annihilation spectroscopy NMRSi29 and study of coating based on them, Izvestua of Academy of Sciences RF, Chemistry, 8 (2011).