Synthesis and Electrochemical Performance of LiFe1-xMnxPO4/C Cathode Material

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Abstract:

Olivine LiFe1−xMnxPO4/C composites were prepared by high temperature solid phase method using MnO2, NH4H2PO4, Li2CO3, FeC2O4•2H2O, glucose as the starting materials. XRD, SEM and constant-current charging/discharging tests were used to study the structure and electrochemical properties of the material. The result showed that when x=0.2 the material exhibited the optimal electrochemical performance, with a higher specific energy of 484.94 Wh/kg.

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Advanced Materials Research (Volumes 347-353)

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3434-3438

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October 2011

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© 2012 Trans Tech Publications Ltd. All Rights Reserved

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[1] A.K. Pahdi, K.S. Najundaswamy, J.B. Goodenough: J Electrochem. Soc. Vol. 144 (1997), p.1188

Google Scholar

[2] S.Y. Chung, J.T. Bloking, Y.M. Chiang: Nat. Mater. Vol.1 (2002), p.123

Google Scholar

[3] C. Delacourt, P. Poizot, J.M. Tarascon, C. Masquelier: Nat. Mater. Vol. 4 (2005), p.254

Google Scholar

[4] M. Thackeray: Nat. Mater. Vol. 1 (2002), p.81

Google Scholar

[5] P.P. Prosini, M. Lisi, D. Zane, M. Pasquali: Solid State Ionics Vol.148 (2002), p.45

Google Scholar

[6] L.J. Li, X.H. Li, Z.X. Wang, L. Wu, J.C. Zheng, H.J. Guo: J Phys. Chem. Solids Vol. 70 (2009), p.238

Google Scholar

[7] C.H. Chen, J.T. Vaughey, A.N. Jansen, D.W. Dees, A.J. Kahaian, T. Goacher, and M.M. Thackeray: J Electrochem Soc. Vol. 148 (2001), p. A102

DOI: 10.1149/1.1344523

Google Scholar

[8] G.H. Li, Ikuta H, Uchida T, Wakihara M.: J Electrochem Soc. Vol.143 (1996), p.178

Google Scholar

[9] Padhi A.K. Nanjundaswamy K.S. Masquelier C., S. Okada, J.B. Goodenough: J Electrochem. Soc. Vol. 144 (1997), p.1609

Google Scholar

[10] P.P. Prosini, D.Zane, M. Pasquali: Electrochim Acta Vol. 46 (2001), p.3517

Google Scholar

[11] Andersson A S, Kalska B., Haggstrom L.: Solid State Ionics, 2000, 130, (1-2): 41

Google Scholar

[12] K.W. Nam, X.J. Wang, W.S. Yoon, H. Li, X.J. Huang, O. Haas, J.M. Bai, X.Q. Yang, Electrochem. Commun. Vol. 11 (2009), p.913

Google Scholar