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Surface Oxidation Modification and Performance of Activated Carbon Electrode Material
Abstract:
Commercial activated carbon was modified by surface treatment using nitric acid, The modified carbons were characterized by X-ray photoelectron spectroscopy (XPS). The resultant carbon electrode-based electric double-layer capacitors (EDLCs) were assembled with 1 mol/L (NH4)2SO4 as the electrolyte. The influence of introduced functional groups, such as hydroxyl and carbonyl, on the performance of EDLCs was studied by Constant current charge-discharge. These functional groups significantly improved the wettability of AC. As a result, the specific capacitance of the carbon modified with 40wt.%HNO3 achieved a specific capacitance of 223.45 F/g at a current density of 5mA/cm2, which is 100.9% higher than that of original AC.
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3456-3458
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Online since:
October 2011
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© 2012 Trans Tech Publications Ltd. All Rights Reserved
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