Preparation of Poly(Vinylbenzyl Chloride)@Lead Sulfide (PVBC@PbS) Core-Shell Nanospheres and Adsorption of Phenol

Jian Ye; Lan Ping Sun; Sheng Ping Gao

doi:10.4028/www.scientific.net/AMR.704.270

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HomeAdvanced Materials ResearchAdvanced Materials Research Vol. 704Preparation of Poly(Vinylbenzyl Chloride)@Lead...

Preparation of Poly(Vinylbenzyl Chloride)@Lead Sulfide (PVBC@PbS) Core-Shell Nanospheres and Adsorption of Phenol

Abstract:

We have demonstrated the fabrication of novel poly(vinylbenzyl chloride)@lead sulfide (PVBC@PbS) core-shell nanospheres via the atom transfer reversible polymerization (ATRP) of lead dimethacrylate (Pb(MA)₂) initiated from methyl chloride groups on surfaces of PVBC nanoparticles and subsequent reaction with ethanethioamide. The chemical structure of the PVBC@PbS nanospheres was confirmed by the fourier transform infrared (FTIR) spectroscopy, and the morphology of the nanospheres were investigated by scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The average size of the nanospheres was determined to be about 100 nm. The PVBC@PbS nanospheres were able to absorb phenol in the solution, and the balanced adsorption capability of phenol to nanospheres could reach to 7.2 μg/mg.

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2013 Spring International Conference on Material Sciences and Technology (MST-S)

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Periodical:

Advanced Materials Research (Volume 704)

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270-274

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https://doi.org/10.4028/www.scientific.net/AMR.704.270

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June 2013

Authors:

Jian Ye, Lan Ping Sun, Sheng Ping Gao

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Adsorption, PbS, Phenol, Poly(Vinylbenzyl Chloride)

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References

[1] M. Lu, B. He, L. Wang, Preparation of polystyrene-polyisoprene core-shell nanoparticles for reinforcement of elastomers. Composites: Part B 43 (2012) 50-56.

DOI: 10.1016/j.compositesb.2011.04.030

Google Scholar

[2] Y. Yuan, L.Y. Chen, R.K. Yang, Solid-state synthesis and characterization of core-shell CoFe2O4-carbon composite nanoparticles from a heterometallic trinuclear complex. Mater. Lett. 71 (2012) 123-126.

DOI: 10.1016/j.matlet.2011.12.043

Google Scholar

[3] D.B. Qin, E.W. Yan, J.H. Yu, Synthesis of polymer/zirconium hydroxide coreeshell microspheres and the hollow porous zirconium oxide microspheres. Mater. Chem. Phys. 136 (2012) 688-697.

DOI: 10.1016/j.matchemphys.2012.07.043

Google Scholar

[4] R.Q. Bai, T. Qiu, F. Han, Preparation and characterization of inorganic-organic trilayer core-shell polysilsesquioxane/polyacrylate/polydimethylsiloxane hybrid latex particles. Appl. Surf. Sci. 258 (2012) 7683-7688.

DOI: 10.1016/j.apsusc.2012.04.121

Google Scholar

[5] K. Matyjaszewski, P.J. Miller, N. Shukla, Polymers at Interfaces: Using atom transfer radical polymerization in the controlled growth of homopolymers and block copolymers from silicon surfaces in the absence of untethered sacrificial initiator. Macromolecules 32 (1999) 8716-8724.

DOI: 10.1021/ma991146p

Google Scholar

[6] J.L. Machol, F.W. Wise, R.C. Patel, Vibronic quantum beats in PbS microcrystallites. Phys. Rev. B 48 (1993) 2819-2822.

DOI: 10.1103/physrevb.48.2819

Google Scholar

[7] S.H. Wang, S.H. Yang, Preparation and characterization of oriented PbS crystalline nanorods in polymer films. Langmuir 16 (2000) 389-397.

DOI: 10.1021/la990780t

Google Scholar

[8] Y.K. Albert Lau, D.J. Chernak, M.J. Bierman, S. Jin, Formation of PbS nanowire pine trees driven by screw dislocations. J. Am. Chem. Soc. 131 (2009) 16461-16471.

DOI: 10.1021/ja906499a

Google Scholar

[9] G. J. Zhou, M.K. Lü, Z.L. Xiu, S.F. Wang, H.P. Zhang, Y.Y. Zhou, S.M. Wang, Controlled synthesis of high-quality PbS star-shaped dendrites, multipods, truncated nanocubes, and nanocubes and their shape evolution process. J. Phys. Chem. B 110 (2006) 6543-6548.

DOI: 10.1021/jp0549881

Google Scholar