Defect and Diffusion Forum Vols. 273-276

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Abstract: Research and applications of magnetically stabilized and fluidized beds begun several decades ago, and have maintained their rate of interest during all these years. During last years their applications was diversified, and the application of these beds in the processing of biological materials and in environmental issues has nowadays focused the main attention within this area. In this work we present a brief review of magnetically fluidized and stabilized beds, mainly concerning their theoretical background, heat and mass transfer topics, some industrial and laboratorial setups and applications.
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Abstract: An analytical approach of transient heat conduction in a two layered material, in finite dimensions within imperfect thermal contact, subjected to a moving Gaussian laser beam was achieved. The result of this study allows on the one hand an easy access to the distribution and the evolution of the temperature in both layers of the workpiece; on the other hand permits to clarify the influence of the contact quality on the temperature gap at the interface. The effect of a porous grannular deposit layer was also considered in this study. A design of electronic tracks by laser cladding was studied as an application example in the surface treatment area; this model can be also used to estimate the thermal contact resistance between layers.
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Abstract: Electrical steels are used in flux carrying machines, divided in grain oriented and non oriented electrical steels mainly used in transformers and electrical motors, respectively. Their industrial production is not always easy due to the alloying elements which produce brittle order structures in the steel. Therefore hot dipping was found to be an alternative way of producing electrical steel with a high concentration of Al and/or Si: in a first series of experiments different steel substrates were coated by immersion in an Al + 23 m.-% Si hypereutectic alloy, followed by a high temperature diffusion annealing. The present contribution reports on the growth kinetics of Al-Si-Fe intermetallics formed during the dipping process in a hypoeutectic Al – 5 m.-% Si bath of Fe-substrates with 3 m.-% Si, previously cold rolled to different thickness. This bath composition allows a liquid phase at temperatures lower than the hypereutectic one with 23 m.-% Si and also less amount of eutectic formation. No Na-addition was made to the bath (the occurrence of a needle-like morphology of the Al-Si eutectic was not relevant for these experiments), furthermore this element might lower the magnetic properties of the steel. The preheating of samples and bath temperatures were not varied and set to 670°C. Short dipping times of 1 to 60 sec. were applied. The different layers formed were characterised by Scanning Electron Microscopy (SEM), using the Back Scattered Electron (BSE) detector and Energy Dispersive Spectroscopy (EDS).
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Abstract: The addition of aluminium (and of silicon) to steel increases its electrical resistivity and reduces therefore the power losses in electrical devices. There is also a favourable effect on magnetostriction. Nevertheless, these additions make the steel extremely brittle and very difficult to process through a conventional thermomechanical route. The authors developed an innovative processing route, avoiding the rolling of a brittle steel sheet. The used process consists of the hot dipping of a steel substrate in a pure aluminium bath, followed by a diffusion annealing treatment. In order to study the reaction of the aluminium with the substrates and the diffusion process during further annealing, two substrates (ultra low carbon steel (ULC) and a Fe + 3.4 m.-% Si steel) were used for immersion in a pure aluminium bath. Dipping times and temperatures were varied in the range of 700 to 750 °C and 5 to 1000 sec., respectively. The different surface layers formed during dipping and after annealing were characterised with an Elcometer, by Scanning Electron Microscopy (SEM) and by Energy Dispersive Spectroscopy (EDS). The results show that the chemical composition of the layers obtained is strongly dependant on the initial substrate composition. Diffusion gradients of Al and Si in the steel after hot dipping and diffusion annealing are shown and discussed. Samples with a concentration gradient of Si and Al over the thickness have been produced. There is only a light reduction of the power losses for the substrate with 3.4 m.-% Si. The ultra low carbon substrate presents worse power losses after the processing. Further improvement of the processing is still required.
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Abstract: Non oriented electrical steels are soft magnetic materials used in the core of electrical motors. No preferential anisotropy of the electrical texture in the rolling plane is desired. Nowadays these special steels are mainly alloyed with Si, Al and some additives to improve the magnetic properties and to reach a good of formability. For (Si, Al)-concentrations higher than 2 wt.% the α- γ-α phase transformation is suppressed, resulting in a bcc crystalline structure from liquidus to room temperature. These electrical steels, which will be discussed in the paper, exhibit the lowest values of the magnetic losses. Hot rolling of FeSi electrical steels has been found to be one of the fundamental steps in producing these materials with optimum properties. The resulting properties, as well known, are determined by the type of magnetic textures and the structural inhomogeneities. Electron Backscattered Diffraction (EBSD) is a reliable tool for microstructural and texture characterization of different materials. Two compositions of electrical steel are studied by optical microscopy and EBSD, with special attention paid to characterize the grain morphology and its texture through thickness.
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Abstract: Precipitation effects in ultra fine grained (UFG) lightweight Mg-based alloys were studied in the present work by means of positron lifetime spectroscopy, transmission electron microscopy, and microhardness. The UFG samples with grain size around 100 nm were fabricated by high pressure torsion (HPT). The UFG structure contains a significant volume fraction of grain boundaries and exhibits a high number of lattice defects (mainly dislocations) introduced by severe plastic deformation during the HPT processing. A high dislocation density and volume fraction of grain boundaries enhance the long range diffusion of solute elements. Moreover, dislocations and grain boundaries act as nucleation centers for precipitates. As a consequence, the precipitation effects are facilitated in the UFG alloys compared to the conventional coarse-grained samples. This phenomenon was examined in this work by comparison of the precipitation sequence in Mg alloys with UFG structure and solution treated coarse-grained alloys.
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Abstract: Defect studies of neutron-irradiated Cr-Mo-V (VVER-440) type reactor pressure vessel steels were performed in the present work. The steels were irradiated in the nuclear power plant reactor under the conditions of a regular operation. Characterization of the irradiation induced defects was performed by two complementary techniques of positron annihilation spectroscopy: (i) positron lifetime spectroscopy was used for identification of defects and determination of defect densities, (ii) coincidence Doppler broadening was employed for investigation of Cu atom aggregates. Long range diffusion of Cu atoms is assisted by the irradiation induced vacancies. The solute Cu atoms form small clusters in the irradiated steels. Subsequent isochronal annealing of the irradiated steel leads to vacancy assisted clustering of Cu atoms and formation of small precipitates. The Cu clusters exhibit maximum diameter at 400oC. Above this temperature the clusters dissolve again in the matrix.
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Abstract: In the present work, a three dimensional model examining the fluid flow along with the fundamental transport phenomena occurring in a typical polymer electrolyte fuel cell (PEMFC), i.e. heat transfer, mass transport and charge transfer, has been developed. The flow field was simulated according to the well known Navier-Stokes equations, while the heat transfer was described by the typical conduction/convection equation and the mass transport by the convection/diffusion one. Furthermore, reaction kinetics were studied by the Butler-Volmer equation for the heterogeneous reactions occurring at the porous electrodes. The developed model was numerically solved by using the commercially available CFD package CFD-RC©, which is based on the multi-step finite volume method. The fuel cell performance in terms of velocity, temperature, mass fractions of active compounds and electric field has been investigated as well.
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Abstract: Vacancies and interstitials in semiconductors play a fundamental role in both high temperature diffusion and low temperature radiation and implantation damage. In Ge, a seri- ous contender material for high-speed electronics applications, vacancies have historically been believed to dominate most diffusion related phenomena such as self-diffusivity or impurity mi- gration. This is to be contrasted with silicon, where self-interstitials also play decisive roles, despite the similarities in the chemical nature of both materials. We report on density func- tional calculations of the formation and properties of vacancy-donor complexes in germanium. We predict that most vacancy-donor aggregates are deep acceptors, and together with their high solubilities, we conclude that they strongly contribute for inhibiting donor activation levels in germanium.
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Abstract: Solid state reactions between amorphous Si and crystalline Co have been investigated by 4W electrical resistance and TEM. Multilayered (with 10 periods of 5nm a-Si/5nm Co and 10 nma- Si/10nm Co layers) as well as tri-layered samples (20nm a-Si/3nmCoSi/6nm Co) were produced by magnetron sputtering and isothermally heat treated at different temperatures between 473 and 523K. From the time evolution of the normalized resistance the kinetics of the process were determined by fitting a power law, tk, and k was between 0.8 and 1. Possibility of the interface reaction control and/or the effect of the diffusion asymmetry (which was recently published for the non-parabolic interface shifts on the nanoscale) will be discussed.
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