Ionic Conductivity of Polycrystalline Li2GexSi1-xO3 (x = 0.0~1.0)

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Abstract:

Polycrystalline Li2GexSi1-xO3 (x = 0.0~1.0) was synthesized by solid state reaction, and its ionic conductivity was studied as a function of x in a temperature range of 500–700 K. The ionic conductivity was found to depend on x and was enhanced at x = 0.2–0.7. Furthermore, the pre-exponential factor and activation energy in the Arrhenius equation were also found to depend on x. These results suggest that lithium ionic conduction in Li2GexSi1-xO3 is strongly influenced by the structure of the framework.

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27-31

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December 2010

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© 2011 Trans Tech Publications Ltd. All Rights Reserved

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[1] S. Furusawa, S. Shimizu, K. Sekine and H. Tabuchi: Solid State Ionics Vol. 167 (2004), p.325.

Google Scholar

[2] S. Furusawa, H. Tabuchi, T. Tsurui: Solid State Ionics Vol. 178 (2007), p.1033.

Google Scholar

[3] S. Furusawa, A. Kamiyama, and T. Tsurui: Solid State Ionics Vol. 179 (2008), p.536.

Google Scholar

[4] S. Furusawa, T. Kasahara, and A. Kamiyama: Solid State Ionics Vol. 180 (2009), p.649.

Google Scholar

[5] S. Furusawa, K. Shimizu and T. Tsurui: J. Phys. Soc. Jpn. Vol. 79 Supplement A (2010) pp.76-79.

Google Scholar

[6] H. Seemann: Acta Cryst. Vol. 9 (1956), p.251.

Google Scholar

[7] K-F. Hesse: Acta Cryst. Vol. B33 (1977), p.901.

Google Scholar

[8] H. Völlenkle and A. Wittmann: Monatshefte für Chemie Vol. 99 (1968), p.244.

Google Scholar