Influence of Sintering Conditions on Electric Performance of Textured 92BNT-6BT-2KNN Ceramics

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Abstract:

0.92(Bi0.5Na0.5)TiO3-0.06BaTiO3-0.02(K0.5Na0.5)NbO3(92BNT-6BT-2KNN) is a high-stain material due to the volume change which come from antiferroelectric-ferroelectric (AFE-FE) phase transformation. Textured 92BNT-6BT-2KNN with a Lotgering factor of 67% was obtained by templated grain growth (TGG) method using plate-like (Bi0.5Na0.5)TiO3(BNT)particles as templates. The influences of sintering process on Lotgering factor and strain were investigated. It was found that the Lotgering factor increased as sintering temperature increase and then decreased with further temperature increase. The changing tendency of polar and unipolar strain did not keep the same accordance with that of Lotgering factor. The maximum of Lotgering factor (79%) and polar strain (0.36%) was obtained when the sintering temperature was 1240°C and 1220°C, respectively, due to the decrease of density when high sintering temperature was employed. Also it was found that the lotgering factor and polar strain reached its highest values when the soaking time was 4h. All these proved that the density and grain orientation codetermined the strain of 92BNT-6BT-2KNN ceramics.

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Key Engineering Materials (Volumes 512-515)

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1380-1384

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June 2012

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© 2012 Trans Tech Publications Ltd. All Rights Reserved

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[1] G.H. Haertling, Ferroelectric ceramics: History and technology, J. Am. Ceram. Soc. 82 (1999) 797-818.

Google Scholar

[2] S. J. Zhang, R. Xia, and T. R. Shrout, Lead-Free Piezoelectric Ceramics vs. PZT, 2006 15th IEEE International Symposium on Applications of Ferroelectrics. (2007) 171-177.

DOI: 10.1109/isaf.2006.4349278

Google Scholar

[3] C. G. Xu, D. M. Lin, and K. W. Kwok, Structure, electrical properties and depolarization temperature of (Bi0.5Na0.5)TiO3-BaTiO3 lead-free piezoelectric ceramics, Solid State Sci. 10 (2008) 934-940.

DOI: 10.1016/j.solidstatesciences.2007.11.003

Google Scholar

[4] S. C. Zhao, G. R. Li, A. L. Ding, T. B. Wang, and Q. R. Yin, Ferroelectric and piezoelectric properties of (Na, K)0.5Bi0.5TiO3 lead free ceramics, J Phys D Appl Phys. 39 (2006) 2277-2281.

DOI: 10.1088/0022-3727/39/10/042

Google Scholar

[5] Y. M. Li, W. Chen, J. Zhou, Q. Xu, H. Sun, and R. X. Xu, Dielectric and piezoelecrtic properties of lead-free (Na0.5Bi0.5)TiO3-NaNbO3 ceramics, Mat Sci Eng B-Solid. 112 (2004) 5-9.

DOI: 10.1016/j.mseb.2004.04.019

Google Scholar

[6] J. Shieh, K.C. Wu, C.S. Chen, Switching characteristics of MPB compositions of (Bi0.5Na0.5)TiO3- BaTiO3-(Bi0.5K0.5)TiO3 lead-free ferroelectric ceramics, Acta Mater. 55 (2007) 3081-3087.

DOI: 10.1016/j.actamat.2007.01.012

Google Scholar

[7] X. Y. Zhou, H. S. Gu, Y. Wang, W. Li, and T. S. Zhou, Piezoelectric properties of Mn-doped (Na0.5Bi0.5)0.92Ba0.08TiO3 ceramics, Materials Letters. 59 (2005) 1649-1652.

DOI: 10.1016/j.matlet.2005.01.034

Google Scholar

[8] W. Jo, S. T. Zhang, A. B. Kounga, and J. Rodel, Lead-Free Piezoceramics with a Giant Strain for Actuator Applications, Ieee Int Ferro. (2008) 387-388.

DOI: 10.1109/isaf.2008.4693817

Google Scholar

[9] S. T. Zhang, A. B. Kounga, W. Jo, C. Jamin, K. Seifert, T. Granzow, J. Rodel, and D. Damjanovic, High-Strain Lead-free Antiferroelectric Electrostrictors, Advanced Materials. 21 (2009) 4716-+.

DOI: 10.1002/adma.200901516

Google Scholar

[10] W. Jo, T. Granzow, E. Aulbach, J. Rodel, and D. Damjanovic, Origin of the large strain response in K0.5Na0.5NbO3-modified Bi0.5Na0.5TiO3-BaTiO3 lead-free piezoceramics, J. Appl. Phy. 105 (2009).

DOI: 10.1063/1.3121203

Google Scholar

[11] T. Kimura, Y. Sakuma, and M. Murata, Texture development in piezoelectric ceramics by templated grain growth using heterotemplates, Journal of the European Ceramic Society. 25 (2005) 2227-2230.

DOI: 10.1016/j.jeurceramsoc.2005.03.036

Google Scholar

[12] T. Takeuchi, T. Tani, and Y. Saito, Piezoelectric properties of bismuth layer-structured ferroelectric ceramics with a preferred orientation processed by the reactive templated grain growth method, Jpn. J. Appl. Phys. Part 1-Regular Papers Short Notes & Review Papers. 38 (1999) 5553-5556.

DOI: 10.1143/jjap.38.5553

Google Scholar

[13] K. Watari, B. Brahmaroutu, G. L. Messing, et al., Epitaxial growth of anisotropically shaped, single-crystal particles of cubic SrTiO3, Journal of Materials Research. 15 (2000) 846-849.

DOI: 10.1557/jmr.2000.0121

Google Scholar

[14] D. Liu, Y. K. Yan, and H. P. Zhou, Synthesis of micron-scale platelet BaTiO3, Journal of the American Ceramic Society. 90 (2007) 1323-1326.

DOI: 10.1111/j.1551-2916.2007.01525.x

Google Scholar

[15] A. Hussain, C.W. Ahn, H.J. Lee, et al., Anisotropic electrical properties of Bi0.5(Na0.75K0.25)0.5TiO3 ceramics fabricated by reactive templated grain growth, Curr. Appl. Phys. 10 (2010) 305-310.

DOI: 10.1016/j.cap.2009.06.013

Google Scholar