Lab-Based X-Ray Topography Characterization of Axial Samples from 4H-SiC Boules Grown by PVT Method

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Abstract:

Axial sliced samples from 4H-SiC boules grown by PVT method were characterized by lab-based X-ray topography systems. Valuable information about dislocation behaviors during crystal growth was revealed. TSD/TMD propagation during PVT growth was studied. The different TSD/TMD propagation directions inside and outside the facet region were identified as the direct cause of the reduced TSD/TMD density at the facet boundary on some c-plane wafers. A defect reduction mechanism was proposed based on this discovery. It was observed that TSDs/TMDs were emitted by a void structure formed during crystal growth, which explained the elevated TSD/TMD density in the center regions of some wafers. The formation mechanism of such defect is different from the previous studies and remains under investigation.

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[1] B. Raghothamachar, M. Dudley, X-Ray Topography, Materials Characterization, ASM International 2019.

Google Scholar

[2] T. Ailihumaer, H. Peng, Y. Liu, B. Raghothamachar, M. Dudley, Characterization of Dislocations in 4H-SiC Single Crystals at the Initial Growth Stage by Synchrotron X-ray Topography, ECS Transactions 98(6) (2020) 125.

DOI: 10.1149/09806.0125ecst

Google Scholar

[3] Q. Cheng, T. Ailihumaer, H. Peng, Y. Liu, B. Raghothamachar, M. Dudley, Analysis of Dislocations in PVT-Grown 6H-SiC through Grazing-Incidence X-Ray Topographic Images and Ray-Tracing Simulation, ECS Transactions 98(6) (2020) 133.

DOI: 10.1149/09806.0133ecst

Google Scholar

[4] H. Peng, Y. Liu, T. Ailihumaer, B. Raghothamachar, M. Dudley, K. Sampayan, S. Sampayan, Investigation of Dislocations in 6H-SiC Axial Samples Using Synchrotron X-Ray Topography and Ray Tracing Simulation, ECS Transactions 104(7) (2021) 147-155.

DOI: 10.1149/10407.0147ecst

Google Scholar

[5] Q.Y. Cheng, H.Y. Peng, S.S. Hu, Z.Y. Chen, Y.F. Liu, B. Raghothamachar, M. Dudley, Ray-Tracing Simulation Analysis of Effective Penetration Depths on Grazing Incidence Synchrotron X-Ray Topographic Images of Basal Plane Dislocations in 4H-SiC Wafers, Materials Science Forum, Trans Tech Publ, 2022, pp.366-370.

DOI: 10.4028/p-2kzz01

Google Scholar

[6] H. Peng, Y. Liu, Z. Chen, Q. Cheng, S. Hu, B. Raghothamachar, M. Dudley, K. Sampayan, S. Sampayan, Synchrotron X-ray topographic characterization of dislocations in 6H-SiC axial samples, Journal of Crystal Growth 579 (2022) 126459.

DOI: 10.1016/j.jcrysgro.2021.126459

Google Scholar

[7] Z. Chen, Y. Liu, Q. Cheng, S. Hu, B. Raghothamachar, M. Dudley, Analysis of strain in ion implanted 4H-SiC by fringes observed in synchrotron X-ray topography, Journal of Crystal Growth 627 (2024) 127535.

DOI: 10.1016/j.jcrysgro.2023.127535

Google Scholar

[8] S. Hu, Y. Liu, Q. Cheng, Z. Chen, X. Tong, B. Raghothamachar, M. Dudley, Investigation of defect formation at the early stage of PVT-grown 4H-SiC crystals, Journal of Crystal Growth 628 (2024) 127542.

DOI: 10.1016/j.jcrysgro.2023.127542

Google Scholar

[9] G. Dhanaraj, B. Raghothamachar, M. Dudley, Growth and Characterization of Silicon Carbide Crystals, in: G. Dhanaraj, K. Byrappa, V. Prasad, M. Dudley (Eds.), Springer handbook of crystal growth, Springer Science & Business Media 2010, p.797.

DOI: 10.1007/978-3-540-74761-1_23

Google Scholar

[10] F.Z. Wu, H.H. Wang, S.Y. Byrapa, B. Raghothamachar, M. Dudley, E. Sanchez, D.M. Hansen, R. Drachev, S.G. Mueller, M.J. Loboda, Synchrotron X-ray Topography Studies of the Propagation and Post-Growth Mutual Interaction of Threading Growth Dislocations with c-component of Burgers Vector in PVT-Grown 4H-SiC, Materials Science Forum, Trans Tech Publ, 2012, pp.343-346.

DOI: 10.4028/www.scientific.net/msf.717-720.343

Google Scholar

[11] T.A. Kuhr, E.K. Sanchez, M. Skowronski, W.M. Vetter, M. Dudley, Hexagonal voids and the formation of micropipes during SiC sublimation growth, Journal of Applied Physics 89(8) (2001) 4625-4630.

DOI: 10.1063/1.1355716

Google Scholar

[12] T. Fujimoto, H. Tsuge, M. Katsuno, S. Sato, H. Yashiro, H. Hirano, T. Yano, A possible mechanism for hexagonal void movement observed during sublimation growth of SiC single crystals, Materials Science Forum, Trans Tech Publ, 2013, pp.577-580.

DOI: 10.4028/www.scientific.net/msf.740-742.577

Google Scholar

[13] A. Arora, A. Patel, B.S. Yadav, A. Goyal, O.P. Thakur, A.K. Garg, R. Raman, Study on evolution of micropipes from hexagonal voids in 4H-SiC crystals by cathodoluminescence imaging, Microscopy and Microanalysis 27(1) (2021) 215-226.

DOI: 10.1017/s1431927621000039

Google Scholar