Subsurface Atomic Structure of 4H-SiC (0001) Finished by Plasma-Assisted Polishing

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Abstract:

Plasma-assisted polishing (PAP) was proposed for finishing difficult-to-machine materials, such as single-crystal SiC, reaction-sintered SiC, diamond, and sapphire. In the case of PAP application to the finishing of the 4H-SiC surface, an atomically smooth surface without any scratches was obtained. In this study, we observed 4H-SiC (0001) surfaces processed by water vapor plasma oxidation and PAP using ceria abrasives through cross-sectional transmission electron microscopy (XTEM). Water vapor plasma oxidation was conducted for 1 min, 5 min and 60 min. An intermediate layer located between SiO2 and SiC, which corresponds to silicon oxycarbide, was clearly observed in the case of a short oxidation. As oxidation time increased from 1 min to 60 min, average oxidation rate decreased from 2.7 nm/min to 0.6 nm/min. An atomically smooth 4H-SiC (0001) surface was obtained after PAP for 60 min using ceria abrasives.

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Materials Science Forum (Volumes 740-742)

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435-438

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January 2013

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© 2013 Trans Tech Publications Ltd. All Rights Reserved

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