Solar-to-Hydrogen Conversion Efficiency of Water Photolysis with Epitaxially Grown p-Type SiC

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Abstract:

Solar-to-hydrogen conversion efficiencies of water photolysis with epitaxially grown p-type 4H-, 6H- and 3C-SiC were estimated in the two electrode system. For all the polytypes, the efficiency with a Pt counter electrode in the two electrode system was very low compared with those in the three electrode system. However, when Ni was used as a counter electrode in the two electrode system, photocurrents were as large as the three electrode system. The estimated efficiencies seem to depend on the bandgap of SiC polytypes, and the highest solar-to-hydrogen conversion efficiency was 0.38% with 3C-SiC.

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Materials Science Forum (Volumes 740-742)

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859-862

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January 2013

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© 2013 Trans Tech Publications Ltd. All Rights Reserved

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