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HomeMaterials Science ForumMaterials Science Forum Vol. 898Non-Isothermal Crystallization Kinetics of...

Non-Isothermal Crystallization Kinetics of Mg₆₁Zn₃₅Ca₄ Glassy Alloy

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Abstract:

The non-isothermal crystallization kinetics of Mg₆₁Zn₃₅Ca₄ glassy alloy prepared via melt-spinning were studied by using isoconversion method. The crystalline characterization of Mg₆₁Zn₃₅Ca₄ was examined by X-ray diffraction. Different scanning calorimeter was used to investigate the non-isothermal crystallization kinetics at different heating rates (3-60 K/min). The calculated value of Avrami exponent obtained by Matusita method indicated that the crystalline transformation for Mg₆₁Zn₃₅Ca₄ is a complex process of nucleation and growth. The Kissinger-Akahira-Sunose method was used to investigate the activation energy. The activation energy of crystallization varies with the extent of crystallization and hence with temperature. The Sestak-Berggren model was used to describe the non-isothermal crystallization kinetics.

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Periodical:

Materials Science Forum (Volume 898)

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657-665

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https://doi.org/10.4028/www.scientific.net/MSF.898.657

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Online since:

June 2017

Authors:

Dao Zhang*, Wang Shu Lu, Xiao Yan Wang, Sen Yang

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Activation Energy, Metallic Glass, Mg-Zn-Ca, Non-Isothermal Crystallization

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© 2017 Trans Tech Publications Ltd. All Rights Reserved

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