Peculiarities of Formation and Annealing of VO-Related Defects in Ge Doped with Tin

Article Preview

Abstract:

The effect of tin on the formation and temperature transformation of VO centers in Ge upon annealing has been investigated. It was found that the doping of Ge with tin leads to a change of reactions involving oxygen and vacancies and the new defect SnVO appears upon VO annealing. Doping Ge with tin gives rise to a considerable decrease in the formation efficiency of divacancies and VO centers and the latter exist in a very narrow temperatures range. VO2 complexes appear only upon annealing of SnVO centers. The assumption is made that the absorption bands situated at 718.9 and 733.6 cm-1 belong to the less stable configuration VO2* and the bands at 731.5 and 771.7 cm-1 correspond to stable configuration of VO2 centers.

You might also be interested in these eBooks

Info:

Periodical:

Solid State Phenomena (Volumes 178-179)

Pages:

166-171

Citation:

Online since:

August 2011

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2011 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] J. A. Baldwin, J. A, Electron paramagnetic resonance in irradiated oxygen-doped germanium, J. Appl. Phys. 36 (1965) 793-801.

Google Scholar

[2] L. Khirunenko, N. Tripachko, V. Shakhovtsov, V. Yashnik, and V. Shumov, EPR and IR absorption of defects in isotopically enriched germanium, Materials Science Forum 196-201 (1995) 167-172.

DOI: 10.4028/www.scientific.net/msf.196-201.167

Google Scholar

[3] P. Vanmeerbeek, P. Clauws, H. Vrielinck, B. Pajot, L. Van Hoorebeke, A. Nyladsted Larsen, High-resolution local vibrational mode spectroscopy and electron paramagnetic resonance study of the oxygen-vacancy complex in irradiated germanium, Phys. Rev. B 70 (2004).

DOI: 10.1103/physrevb.70.035203

Google Scholar

[4] R. E. Whan, Investigations of Oxygen-Defect Interactions between 25 and 700 K in Irradiated Germanium, Phys. Rev. 140 (1965) A690-698.

DOI: 10.1103/physrev.140.a690

Google Scholar

[5] R. E. Whan, Evidence for low-temperature motion of vacancies in germanium, Appl. Phys. Lett. 6 (1965) 221-223.

DOI: 10.1063/1.1754143

Google Scholar

[6] P. Vanmeerbeek and P. Clauws, Local vibrational mode spectroscopy of dimmer and other oxygen-related defects in irradiated and thermally annealed germanium, Phys. Rev. B 64 (2001) 205201-205206.

DOI: 10.1103/physrevb.64.245201

Google Scholar

[7] J. Fage-Pedersen, A. Nyladsted Larsen, and A. Mesli, Irradiation-induced defects in Ge studied by transient spectroscopies, Phys. Rev. B 62 (2000) 10116-10125.

DOI: 10.1103/physrevb.62.10116

Google Scholar

[8] V. P. Markevich, I. D. Hawkins, A. R. Peaker, V. V. Litvinov, L. I. Murin, L. Dobaczewski, J. L. Lindström, Electronic properties of vacancy–oxygen complex in Ge crystals, Appl. Phys. Lett. 81 (2002) 1821-1823.

DOI: 10.1063/1.1504871

Google Scholar

[9] A. Mesli, L. Dobachewski, K. Bonde Nielsen, Vl. Kolkovsky, M. Christian Petersen, and A. Nyladsted Larsen, Phys. Rev. B 78 (2008) 165202(1-16).

Google Scholar

[10] G. D. Watkins, Defects in irradiated silicon: EPR of the tin-vacancy pair, Phys. Rev. B 12 (1975) 4383-4390.

DOI: 10.1103/physrevb.12.4383

Google Scholar

[11] L. I. Khirunenko, O. A. Kobzar, Yu. V. Pomozov, M. G. Sosnin, Peculiarities of vacancy-related defects formation in Si doped with tin, Physica B 340-342 (2003) 541-545.

DOI: 10.1016/j.physb.2003.09.139

Google Scholar

[12] L.I. Murin, J.L. Lindström, I.F. Medvedeva, V.J.B. Torres, J. Coutinho, R. Jones, P.R. Briddon, Metastable VO2 complexes in silicon: experimental and theoretical modeling studies, Solid State Phenomena 108-109 (2005) 223-228.

DOI: 10.4028/www.scientific.net/ssp.108-109.223

Google Scholar

[13] Carvalho, V.J.B. Torres, V.P. Markevich, J. Coutinho, V.V. Litvinov, A.R. Peaker, R. Jones, P.R. Briddon, Identification of stable and metastable forms of VO2 centers in germanium, Physica B 401–402(2007) 192-195.

DOI: 10.1016/j.physb.2007.08.144

Google Scholar