Growth and Characterization of “IsoPure” Epitaxial Layers for Quantum Applications

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Abstract:

This paper compares ethene and methane precursors for homoepitaxial 4H-SiC growth in planetary reactors with regards to their impact on growth rate and defectivity of the epilayers. Therefore, a comprehensive experimental study has been performed in AIXTRON G10-SiC and G5WW C planetary reactors using a standard process based on ethene and trichlorosilane precursors with conventional 150 mm n-type 4H-SiC substrates from 3 different international suppliers. Methane substituted ethene as precursor in many experiments. It was found that methane precursor can compete with ethene in terms of growth rate, epilayer thickness, and defectivity of the epilayers. By using isotopically enriched methane, Si12C epilayers with a 12C concentration of 99.96 % have been grown which can be used for SiC-based quantum technology.

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