Characterization of Deep Levels Introduced by Energy Filtered Ion Implantation with DLTS and MCTS in 4H-SiC

Article Preview

Abstract:

The extensive study of point defects in 4H-SiC over the past two decades has led to a comprehensive understanding of their influence on device performance. Specifically, the dominant defects Z1/2 and EH6/7 have been well-quantified and are now formally assigned to specific states of the carbon vacancy. Building upon this foundational knowledge, our study investigates the defect landscape created by the novel process of Energy-Filtered Ion Implantation (EFII). Using DLTS and MCTS measurements conducted within the temperature range of 50−650 K, we analyzed the trap levels created by 19 MeV Nitrogen implantation in as-grown 4H-SiC epitaxial wafer. The majority carrier (electrons) trap with DLTS measurements reveal the presence of prominent peaks associated with carbon complexes, labeled as ON0a (Ec - 0.586 eV) and ON0b / Z1/2 at (Ec - 0.681 eV), along with smaller peaks in the shallow region and a broader peak identified as EH6/7 at (Ec - 1.53 eV) as the deepest peak. Notably, the close proximity of the ON0b peak to the well-known Z1/2 peak poses a significant challenge, preventing the definitive assignment of a defect structure to the known carbon complexes. On the contrary, minority carrier (holes) trap detection with MCTS reveal B-center at (EV + 0.24 eV) and (EV + 0.33 eV) and a negligible shallow peak at (EV + 0.22 eV) assigned as X center. There was no indication of D-center formation in the EFII implanted samples.

You have full access to the following eBook

Info:

* - Corresponding Author

[1] Tsunenobu Kimoto. Fundamentals of Silicon Carbide Technology. Wiley-IEEE Press, (1st), November 2014.

Google Scholar

[2] J. Erlekampf, M. Rommel, K. Rosshirt-Lilla, B. Kallinger, P. Berwian, J. Friedrich, and T. Erlbacher. Lifetime limiting defects in 4H-SiC epitaxial layers: The influence of substrate originated defects. Journal of Crystal Growth, 560–561:126033, April 2021.

DOI: 10.1016/j.jcrysgro.2021.126033

Google Scholar

[3] Koutarou Kawahara, Giovanni Alfieri, and Tsunenobu Kimoto. Detection and depth analyses of deep levels generated by ion implantation in n- and p-type 4H-SiC. Journal of Applied Physics, 106(1):013719, July 2009.

DOI: 10.1063/1.3159901

Google Scholar

[4] Constantin Csato, Florian Krippendorf, Shavkat Akhmadaliev, Johannes Von Borany, Weiqi Han, Thomas Siefke, Andre Zowalla, and Michael Rüb. Energy filter for tailoring depth profiles in semiconductor doping application. Nuclear Instruments and Methods in Physics Research Sec-tion B: Beam Interactions with Materials and Atoms, 365:182–186, December 2015.

DOI: 10.1016/j.nimb.2015.07.102

Google Scholar

[5] Marianne Etzelmüller Bathen, Margareta Linnarsson, Misagh Ghezellou, Jawad Ul Hassan, and Lasse Vines. Influence of Carbon Cap on Self-Diffusion in Silicon Carbide. Crystals, 10(9):752, August 2020.

DOI: 10.3390/cryst10090752

Google Scholar

[6] Marianne Etzelmüller Bathen, Robert Karsthof, Augustinas Galeckas, Piyush Kumar, Andrej Yu. Kuznetsov, Ulrike Grossner, and Lasse Vines. Impact of carbon injection in 4H-SiC on de-fect formation and minority carrier lifetime. Materials Science in Semiconductor Processing, 176:108316, June 2024.

DOI: 10.1016/j.mssp.2024.108316

Google Scholar

[7] Franziska C. Beyer. Deep Levels in SiC. Department of Physics, Chemistry and Biology, Linköping University, Linköping, 2011.

Google Scholar

[8] O. V. Feklisova, E. E. Yakimov, and E. B. Yakimov. Study of single-layer stacking faults in 4H–SiC by deep level transient spectroscopy. Applied Physics Letters, 116(17), April 2020.

DOI: 10.1063/5.0004423

Google Scholar

[9] Robert Karsthof, Marianne Etzelmüller Bathen, Augustinas Galeckas, and Lasse Vines. Conver-sion pathways of primary defects by annealing in proton-irradiated n -type 4 H -SiC. Physical Review B, 102(18):184111, November 2020.

DOI: 10.1103/physrevb.102.184111

Google Scholar

[10] M. E. Bathen, A. Galeckas, J. Müting, H. M. Ayedh, U. Grossner, J. Coutinho, Y. K. Frodason, and L. Vines. Electrical charge state identification and control for the silicon vacancy in 4H-SiC. npj Quantum Information, 5(1):111, December 2019.

DOI: 10.1038/s41534-019-0227-y

Google Scholar

[11] Tihomir Knežević, Tomislav Brodar, Vladimir Radulović, Luka Snoj, Takahiro Makino, and Ivana Capan. Distinguishing the EH1 and S1 defects in n-type 4H-SiC by Laplace DLTS. Ap-plied Physics Express, 15(10):101002, September 2022.

DOI: 10.35848/1882-0786/ac8f83

Google Scholar

[12] J. Erlekampf, B. Kallinger, J. Weiße, M. Rommel, P. Berwian, J. Friedrich, and T. Erlbacher. Deeper insight into lifetime-engineering in 4H-SiC by ion implantation. Journal of Applied Physics, 126(4):045701, July 2019.

DOI: 10.1063/1.5092429

Google Scholar

[13] Takafumi Okuda, Giovanni Alfieri, Tsunenobu Kimoto, and Jun Suda. Oxidation-induced ma-jority and minority carrier traps in n- and p-type 4H-SiC. Applied Physics Express, 8(11):111301, October 2015.

DOI: 10.7567/apex.8.111301

Google Scholar

[14] Marianne Etzelmüller Bathen, Robert Karsthof, Ulrike Grossner, and Lasse Vines. Stabil-ity, Evolution and Diffusion of Intrinsic Point Defects in 4H-SiC. Materials Science Forum, 1062:371–375, 2022.

DOI: 10.4028/p-ryui6b

Google Scholar

[15] Marianne Etzelmüller Bathen, Piyush Kumar, Misagh Ghezellou, Manuel Belanche, Lasse Vines, Jawad Ul-Hassan, and Ulrike Grossner. Dual configuration of shallow acceptor levels in 4H-SiC. Materials Science in Semiconductor Processing, 177:108360, July 2024.

DOI: 10.1016/j.mssp.2024.108360

Google Scholar

[16] A. A. Lebedev. Deep level centers in silicon carbide: A review. Semiconductors, 33(2):107–130, February 1999.

DOI: 10.1134/1.1187657

Google Scholar

[17] Vitor J. B. Torres, Capan Ivana, and José Coutinho. Theory of shallow and deep boron defects in 4H-SiC. Physical Review B, 106(22), 2022.

Google Scholar