Formation Mechanism and Reduction of Surface Pits on 4H-SiC Epitaxial Layer

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Surface pits in silicon carbide (SiC) epitaxial layers have a significant impact on various types of SiC devices, potentially causing electric field concentration and degrading device performance. The formation mechanism of surface pits remains unclear. In this work, the mechanism was investigated through the molten KOH etching experiments, and we confirmed that surface pits originate from dislocation defects in the substrate, particularly TSDs. The dislocations negatively impacted the step-flow growth of epitaxy, leading to pit formation. Further investigations into the effects of growth temperature, C/Si ratio, and epitaxial-layer thickness on pit formation revealed that low temperatures and silicon-rich conditions could effectively suppress pit formation. Both the density and size of surface pits increased significantly with the increase in epitaxial layer thickness. Therefore, this work proposes a model for the formation mechanism of surface pits, where the competition between step-flow growth and spiral growth is a key factor in controlling the size of surface pits.

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9-14

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May 2026

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