Argon Plasma Treatment of 4H-SiC Surface before Nickel Ohmic Contacts Formation by UV Laser Annealing

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Abstract:

Laser Thermal Annealing (LTA) is a necessary fabrication step to improve the 4H-SiC devices by reducing their ON-state resistance. Because the LTA annealing is achieved at the end of the front-end fabrication, the classical Radio Corporation of America cleaning (RCA) cannot be used without affecting the material deposited on the frontside. Therefore, in this study, we investigate the argon (Ar) plasma surface treatment, achieved in our sputtering tool, before the ohmic contact fabrication, as an alternative surface preparation to the RCA sequence. As the Ar plasma modifies the SiC surface morphology, it affects its wetting properties. That can play a key role in the ohmic contact formation by LTA since the nickel turns into liquid phase during the laser irradiation. For an Ar plasma treatment of 30 min, a specific contact resistance of 5.0×10-5 Ω.cm2 has been obtained for an annealing at 5.0 J.cm2, which is in the same range than the contact fabricated by LTA involving a classical RCA cleaning.

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Materials Science Forum (Volume 1159)

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31-36

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September 2025

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[1] T. Kimoto and J. A. Cooper, "Fundamentals of Silicon Carbide Technology: growth, characterization, devices and applications", Wiley, Singapore, 2014.

DOI: 10.1002/9781118313534

Google Scholar

[2] S. Rascunà, P. Badalà, C. Tringali, C. Bongiorno, E. Smecca, A. Alberti, S. Di Franco, F. Giannazzo, G. Greco, F. Roccaforte, M. Saggio, "Morphological and electrical properties of Nickel based Ohmic contacts formed by laser annealing process on n-type 4H-SiC", Mater. Sci. Semicond., vol. 97, p.62, 2019.

DOI: 10.1016/j.mssp.2019.02.031

Google Scholar

[3] M. De Silva, T. Kawasaki, T. Miyazaki, T. Koganezawa, S. Yasuno and S.-I. Kuroki, "Formation of epitaxial Ti-Si-C Ohmic contact on 4H-SiC C face using pulsed-laser annealing", Appl. Phys. Lett., vol. 110, no. 25, p.252108, 2017.

DOI: 10.1063/1.4987136

Google Scholar

[4] C. Berger, D. Alquier, M. Bah and J.-F. Michaud, "Electrical, morphological and structural properties of Ti ohmic contacts formed on n-type 4H–SiC by laser thermal annealing", Mater. Sci. Semicond., vol. 151, p.106983, 2022.

DOI: 10.1016/j.mssp.2022.106983

Google Scholar

[5] P. Badalà, S. Rascunà, B. Cafra, A. Bassi, E. Smecca, M. Zimbone, C. Bongiorno, C. Calabretta, F. La Via, F. Roccaforte, M. Saggio, G. Franco, A. Messina, A. La Magna, A. Alberti, "Ni/4H-SiC interaction and silicide formation under excimer laser annealing for ohmic contact", Materialia, vol. 9, p.100528, 2020.

DOI: 10.1016/j.mtla.2019.100528

Google Scholar

[6] J. F. Michaud, C. Berger and D. Alquier, "Nickel Ohmic Contacts Formed on 4H-SiC by UV Laser Annealing", Solid State Phenomena, vol. 359, p.91, 2024.

DOI: 10.4028/p-xqh9xB

Google Scholar

[7] C. Berger, D. Alquier and J.-F. Michaud, "How to Accurately Determine the Ohmic Contact Properties on n-Type 4H-SiC", Electronics, vol. 13, no. 1, p.217, 2024.

DOI: 10.3390/electronics13010217

Google Scholar

[8] J. G. Kim, W. S. Yoo, J. Y. Park and W. J. Lee, "Quantitative Analysis of Contact Angle of Water on SiC: Polytype and Polarity Dependence", ECS J. Solid State Sci. Technol., vol. 9, no. 12, p.123006, 2020.

DOI: 10.1149/2162-8777/abcd0b

Google Scholar