Analysis of Ohmic Contacts Simultaneously Formed on both n-Type and p-Type 4H-SiC

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Abstract:

In this paper, various annealing conditions using Al-based (Ti/Al/Ti/Au=70nm/100nm /5nm/120nm) and Ni-based (Ti/Ni/Ti/Au=20nm/90nm/5nm/120nm) metal contacts to n-type and p-type ion-implanted 4H-SiC epi layers have been studied in the effort to optimize simultaneous ohmic contact formation with the lowest specific contact resistance (SCR) values. Values of 1.091×10-4 Ω∙cm2 and 1.158×10-5 Ω∙cm2 were achieved using Al-based Ohmic metal contacts for p-type and n-type 4H-SiC, respectively, at an annealing temperature of 950°C and under vacuum for 90 sec. Ohmic formation mechanisms were analyzed using the X-Ray Diffraction (XRD) surface analysis method, indicating Ti3SiC2 alloys to be the key intermediate layer formed at SiC/Ti interface, responsible for Ohmic properties to p-type SiC. The paper summarizes the metal process combinations possible for the formation of Ohmic contacts to both n-type and p-type 4H-SiC, offering various options in either using the same metal materials and/or common annealing conditions.

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[1] Matsunami, H., "Fundamental research on semiconductor SiC and its applications to power electronics", Proceedings of the Japan Academy. Series B, Physical and biological sciences vol. 96,7 (2020): 235-254

DOI: 10.2183/pjab.96.018

Google Scholar

[2] Shimbori, A., and Huang, A., "Cost-Effective Formation of Ti/Ni/Ti/Au Ohmic Contacts to n-type SiC Using SiO2 Encapsulation Layer during Phosphorous Implant Activation", 2022 ECS Trans. 109 41

DOI: 10.1149/10908.0041ecst

Google Scholar

[3] Kuchuk, A. V., Borowicz, P., Wzorek, M., Borysiewicz, M., Ratajczak, R., Golaszewska, K., Kaminska, E., Kladko, V., and Piotrowska, A., "Ni-Based Ohmic Contacts to n-Type 4H-SiC: The Formation Mechanism and Thermal Stability", Advances in Condensed Matter Physics, 2016, 9273702, 26 pages, 2016

DOI: 10.1155/2016/9273702

Google Scholar

[4] Tsukimoto, S., Onishi, T., Ito, K., and Murakami, M., "Simultaneous Formation of Ohmic Contacts for Both N- and P-Type 4H-Sic Using Nial-Based Contact Materials", MRS Proceedings, vol. 911, p.0911-B11-05, 2006

DOI: 10.1557/PROC-0911-B11-05

Google Scholar

[5] Vivona, M., Greco, G., Giannazzo, F., Lo Nigro, R., Rascunà, S., Saggio, M., and Roccaforte, F., "Thermal stability of the current transport mechanisms in Ni-based Ohmic contacts on n- and p-implanted 4H-SiC", Semiconductor Science Technology, vol. 29, no. 7, Art. no. 075018, IOP, 2014.

DOI: 10.1088/0268-1242/29/7/075018

Google Scholar

[6] Ito, K., Onishi, T., Takeda, H. et al. "Simultaneous Formation of Ni/Al Ohmic Contacts to Both n- and p-Type 4H-SiC", J. Electron. Mater. 37, 1674–1680 (2008)

DOI: 10.1007/s11664-008-0525-1

Google Scholar

[7] Kragh-Buetow, K. C., Okojie, R. S., Lukco, D., and Mohney, S. E., "Characterization of tungsten-nickel simultaneous Ohmic contacts to p- and n-type 4H-SiC", Semiconductor Science Technology, vol. 30, no. 10, Art. no. 105019, IOP, 2015

DOI: 10.1088/0268-1242/30/10/105019

Google Scholar

[8] Okojie, R. S., and Lukco, D., "Simultaneous ohmic contacts to p- and n-type 4H-SiC by phase segregation annealing of co-sputtered Pt-Ti", J. Appl. Phys. 7 December 2016; 120 (21): 215301

DOI: 10.1063/1.4968572

Google Scholar

[9] Johnson, B., and Capano, M., "Mechanism of ohmic behavior of Al/Ti contacts to p-type 4H-SiC after annealing", J. Appl. Phys. 15 May 2004; 95 (10): 5616–5620

DOI: 10.1063/1.1707215

Google Scholar

[10] Buchholt, K., Ghandi, R., Domeij, M., Zetterling, C.-M., Lu, J., Eklund, P., Hultman, L., and Lloyd Spetz, A., "Ohmic contact properties of magnetron sputtered on Ti3SiC2 n- and p-type 4H-silicon carbide", Appl. Phys. Lett. 24 January 2011; 98 (4): 042108

DOI: 10.1063/1.3549198

Google Scholar