Materials Science Forum Vols. 620-622

Abstract: A novel etherified KGM (EKGM) was synthesized with Konjac glucomannan (KGM) and 1-bromopropane in Lithium chloride/dimethyl sulfoxide (LiCl/DMSO). The EKGM was characterized by FT-IR, DSC and TG. The IR of EKGM showed that –OH stretching vibration band decreased and the C–H and C–O–C stretching vibration bands increased comparing with the unmodified KGM, which was indicating that KGM had been etherified. The DSC thermograms showed that an obvious glass transition of EKGM appeared and its glass transition temperature (Tg) decreased with the increasing of Pr/OH ratio. And it was also found that the EKGM had a higher decomposition temperature than unmodified. Meanwhile, it was proved that the EKGM was a good hydrophobic polymer and dissolved in some organic solvent easily.

Abstract: Urban area may be warmer than surrounding regions due to asphalt and concrete for roads, buildings, and other artificial structures. Especially, pavements have become an important contributor to this effect by altering land-cover over significant portions of an urban area. Therefore, researchers have studied ways to reduce the heat island effect such as cooling pavement, porous pavements such as water-retentive or water absorbing pavements. Accordingly, this study aims at the development of water-retention asphalt pavement for urban areas in order to solve problems related to the distortion of water cycle and the heat island phenomena. Experimental results indicated that asphalt pavement using developed water retaining material was effective to decrease its surface temperature compare to other pavements. A correlation between air temperature and surface temperature of the pavement was obtained to estimate the efficiency of the developed pavement materials.

Abstract: Since the non point source is unspecified and estimating the degree of occurrence or identifying causing factors are difficult, it is not easy to control. Road runoff is considered a major source of pollution in developed urban sites. Road surfaces accumulate significant quantities of pollutants including nutrients, heavy metals and polycyclic aromatic hydrocarbons(PAHs). Many studies have characterized the constituents of stormwater. These constituents include polycyclic aromatic hydrocarbons(PAHs). Urban non-point source pollutant reducing treatment System is a part of the road runoff treatment which expanded polypropylene(EPP) media with a large surface area to treating the first flush of stormwater from road in field. Urban non-point source pollutant reducing treatment System consist of a container, a total 8.89m2 volume(3.6m(L), 1.3m(W), 1.9m(H)) which is made up of two element; sedimentation chamber of storage tank and filter tank. Under the operating conditions with 0.55h hydraulic retention time(HRT) and a capable of treating a maximum road runoff of 9.5m3/hr, the mean residual total PAHs were 0.699~1.339 µg /L and the percentage mean removal values were 61.4~69.7%, respectively.

Abstract: The effects of the pair-minerializer (CaSO4,-CaF2) on the burnability of clinker and the formation of mineral are investigated. As experimental results, the addition of F as pair-mineralizer, the burnability of clinker was improved. Especially, the addition of F and SO3 components simultaneously as pair-mineralizer, total amount of free lime in clinker is rapidly decreased compared with the value which mineralizer was added separately. In case of adding K2O only to the raw mixes, the amount of free lime is increased. However, if alkali (K2O) and pair-minerializer (CaSO4,-CaF2) were added simultaneously, the produced amount of clinker mineral is increased due to the formation of stable calcium langbeinite by the combination of alkali (K2O) and sulfate

Abstract: In order to keep the steel with outstanding antibacterial characteristics, the relationship between the anneal temperatures and the amounts of the precipitated Cu-rich phase was investigated in this work. The SEM analysis of annealing specimens indicated that the microstructure changed with the increase of annealing temperature. At 900°C, the martensite phase appeared along the crystal boundary, but the amount of Cu-rich phase was almost no change. At 920°C, the sizes of the Cu-rich precipitates minished and the amounts of the precipitates reduced gradually. At 940°C, there was only martensite phase existing in the ferrite matrix. Therefore, the optimal final annealing temperature range was chosen from 880°C to 900°C to ensure attaining excellent antibacterial properties and favorable mechanical characteristic of copper-bearing stainless steel.

Abstract: Collapse-type shrinkage in plantation-grown Eucalyptus cells is a bottleneck to severely restrict its high-effective utilization as environment-friendly solid-wood products. So, measurement of collapse-shrinkage parameters on seven species of Eucalypts (Eucalyptus urophylla, E.grandis, E.urophylla×grandis, E.grandis ×urophylla, E. dunnii, E. cloeziana and E. pellita) have been carried out under three kinds of treated patterns (heating, steaming and combined treatment) by means of image analysis technique. The results indicated that the total shrinkage and residual collapse increase obviously with heating temperature and steaming time for five species of low-density eucalypts(E.urophylla, E.grandis, E.urophylla×grandis, E.grandis ×urophylla and E. dunnii), while increase slightly for other two species of higher-density Eucalypts (E.cloeziana and E.pellita). Combined treatment has not made the total shrinkage and residual collapse take on the additive trend, especially for higher-density Eucalyptus. Therefore, the results will provide the important practical significance for the reasonable processing of plantation-grown eucalypt wood.

Abstract: In this work, the physical & chemical properties of bottom ash generated from power plant are analyzed. Characteristic mortar property and thermal conductivity for building material were investigated with content of added bottom ash. According to the analytic result of bottom ash, chemical compositions of bottom ash is similar to those of fly ash and compressive strength after 7days related to pozzolanic activity shows 2.5N/cm2 and it is confirmed that bottom ash possess a certain amount of moisture activity. Although the fluidity of cement mortar is rapidly decreased with increasing addition of bottom ash, compressive strength for 3 and 7days is increased. The thermal conductivity is not sensitive to the addition of bottom ash.

Abstract: Zeolite are used as adsorbent, catalyst and ionexchang material. But it limited to extend the usage of the zeolite since almost zeolite synthesized by hydrothermal method. The purpose of this study was to synthesis zeolite by calcination at high temperature due to extend the application of zeolite, as ceramics process. The effect of aging temperature and time, crystallization temperature on the synthesis of zeolite has been studied. Aging was performed at room temperature~70°C during 0~3days. After aging, zeolite precursor sinter for 1 hours at 300, 400, 500°C in furnace. The resulting materials were characterized by XRD, TG, SEM When the aging time is less than 1 day zeolite was not synthesized. But zeolite A obtained from precursor of aging time is more than 1 day at all firing temperature. As a result the aging time and aging temperature is increased, the zeolite synthesis time is decreased. Therefore aging is benefit process on synthesis of zeolite at high temperature.

Abstract: Zeolite has been used as catalyzer, absorbent, ion-exchange matter and dehydrating agent due to its excellent catalytic property and ion-exchange. In recent years, many studies have been conducted to apply zeolite as new materials such as zeolite membranes and zeolite sensor films. To introduce properties of zeolite, it should be examined how zeolite could be reacted other materials. In this study, it is investigated whether zeolite is successfully synthesized or not when clay and/or sewage sludge coexist with zeolite precursor. Zeolite precursor was made of liquid sodium silicate and sodium aluminate. Mixing ratio of caly and/or sewage sludge is 0-10%(wt.). To compare two processes, the mixture was synthsized by hydrothermal method and high temperature sintering process. It is synthesized by hydrothermal with sintering at high temperature process. The resulting materials were characterized by XRD and SEM. As a result, various type of zeolite such as zeolite X, zeolite A and zeolite P1 was successfully synthesized by hydrothermal method when clay and/or sewage coexist with zeolite precursor. However, zeolite was rarely synthesized by high temperature sintering process. Therefore, when preperation of zeolite material mixed with other material such as clay and sewage sludge, hydrothermal method is more effective than sintering at high temperature process.

Abstract: The investigation of the plunge stage of the tool during friction stir welding (FSW) is the basis of understanding the nature of FSW, which is especially important for friction stir spot welding. In this study, the plunge stage of FSW tool was numerically examined by dynamic explicit finite element method with more attention to the temperature evolution. It was found that the high temperature region around the stirred zone extended with increasing the rotation speed. The heat affected zone expanded with the increase of inserting time, but the highest temperature around the stirred zone changed little. The range of the stirred zone changed little with the variations of the rotation speed and inserting time. The simulation result on the temperature field was in comparable agreement with the experimental one.