Retarded Oxide Growth on 4H-SiC(0001) Substrates due to Sacrificial Oxidation

Article Preview

Abstract:

The impact of a sacrificial oxidation treatment on subsequent gate oxide formation on 4H-SiC(0001) substrates was investigated. Although x-ray photoelectron spectroscopy (XPS) analysis revealed that the SiC surface after removing a 40-nm-thick sacrificial oxide by diluted HF solution was almost identical to that of an as-grown epilayer, the subsequent dry O2 oxidation resulted in a thinner SiO2 layer for the sample with the sacrificial oxidation in the ultrathin film regime (~3 nm). The metal-oxide-semiconductor (MOS) capacitor with sacrificial oxidation also exhibited a larger frequency dispersion in capacitance-voltage (C-V) characteristics, indicating that interface property had been degraded. However, when the oxide thickness reached about 10 nm, there was no difference in frequency dispersion with and without sacrificial oxidation. This means that the SiO2 growth in the initial stage of oxidation was significantly affected by the sacrificial oxidation treatment.

You might also be interested in these eBooks

Info:

Periodical:

Materials Science Forum (Volumes 778-780)

Pages:

562-565

Citation:

Online since:

February 2014

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2014 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] V.V. Afanas'ev, A. Stesmans, M. Bassler, G. Pensl, M.J. Schulz, C.I. Harris, Elimination of SiC/SiO2 interface states by peroxidation ultraviolet-ozone cleaning, Appl. Phys. Lett. 68 (1996) 2141-2143.

DOI: 10.1063/1.115611

Google Scholar

[2] T. Hosoi, Y. Uenishi, S. Mitani, Y. Nakano, T. Nakamura, T. Shimura, H. Watanabe, Dielectric properties of thermally grown SiO2 on 4H-SiC(0001) substrates, Mater. Sci. Forum 740-742 (2013) 605-608.

DOI: 10.4028/www.scientific.net/msf.740-742.605

Google Scholar

[3] F. Stern, Self-consistent results of n-type Si inversion layers, Phys. Rev. B 5 (1972) 4891-4899.

DOI: 10.1103/physrevb.5.4891

Google Scholar

[4] C. Persson, U. Lindefelt, B.E. Sernelius, Doping-induced effects on the band structure in n-type 3C-, 2H-, 4H-, 6H-SiC, and Si, Phys. Rev. B 60, (1999) 16479-16493.

DOI: 10.1016/s0038-1101(99)00180-x

Google Scholar

[5] H. Watanabe, T. Hosoi, T. Kirino, Y. Kagei, Y. Uenishi, A. Chanthaphan, A. Yoshigoe, Y. Teraoka, T. Shimura, Synchrotron x-ray photoelectron spectroscopy study on thermally grown SiO2/4H-SiC(0001) interface and its correlation with electrical properties, Appl. Phys. Lett. 99 (2011).

DOI: 10.1063/1.3610487

Google Scholar