Improvement of Surface Morphology by Solution Flow Control in Solution Growth of SiC on Off-Axis Seeds

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The solution growth of SiC on an off-axis seed is effective on the reduction of threading dislocations. We proposed a novel method to grow a SiC crystal on an off-axis seed by top-seeded solution growth (TSSG). In our previous study, a unidirectional solution flow above a seed crystal is effective to suppress surface roughness in the growth on the off-axis seed. However, it is difficult to apply the unidirectional flow in an axisymmetric TSSG set-up. In this study, the unidirectional flow could be achieved by shifting the rotational axis away from the center of the seed crystal. As a result, the smooth surface was obtained in the wider area where the solution flow direction was opposite to the step-flow direction.

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Materials Science Forum (Volumes 821-823)

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31-34

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June 2015

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© 2015 Trans Tech Publications Ltd. All Rights Reserved

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[1] M. Kado, H. Daikoku, H. Sakamoto, H. Suzuki, T. Bessho, N. Yashiro, K. Kusunoki, N. Okada, K. Moriguchi and K. Kamei, High-speed growth of 4H-SiC single crystal using Si-Cr based melt, Mater. Sci. Forum 740-742 (2013) 73-76.

DOI: 10.4028/www.scientific.net/msf.740-742.73

Google Scholar

[2] Y. Yamamoto, S. Harada, K. Seki, A. Horio, T. Mitsuhashi, T. Ujihara, Low-dislocation-density 4H-SiC crystal growth utilizing dislocation conversion during solution method, Appl. Phys. Express 7 (2014) 065501.

DOI: 10.7567/apex.7.065501

Google Scholar

[3] Y. Yamamoto, S. Harada, K. Seki, A. Horio, T. Mitsuhashi, T. Ujihara, High-efficiency conversion of threading screw dislocations in 4H-SiC by solution growth, Appl. Phys. Express 5 (2012) 115501.

DOI: 10.1143/apex.5.115501

Google Scholar

[4] K. Kamei, K. Kusunoki, N. Yashiro, N. Okada, T. Tanaka, A. Yauchi, Solution growth of single crystalline 6H, 4H-SiC using Si–Ti–C melt, J. Cryst. Growth 311 (2009) 855-858.

DOI: 10.1016/j.jcrysgro.2008.09.142

Google Scholar

[5] C. Zhu, S. Harada, K. Seki, H. Zhang, H. Niinomi, M. Tagawa and T. Ujihara, Influence of solution flow on step bunching in solution growth of SiC crystals, Cryst. Growth Des. 13 (2013) 3691-3696.

DOI: 10.1021/cg400706u

Google Scholar

[6] Information on http: /www. openfoam. com.

Google Scholar

[7] F. Mercier, J. M. Dedulle, D. Chaussende, M. Pons, Coupled heat transfer and fluid dynamics modeling of high-temperature SiC solution growth, J. Cryst. Growth 312 (2010) 155-163.

DOI: 10.1016/j.jcrysgro.2009.10.007

Google Scholar

[8] G. G. Tyagunov, B. A. Baum, P. V. Gel'd, Kinematic viscosity of liquid chromium – carbon alloys, Sov. Phys. J. 14(8) (1971) 1163-1164.

DOI: 10.1007/bf00820094

Google Scholar

[9] T. Saito, Y. Shiraishi, Y. Sakuma, Trans. ISIJ 9 (1969) 118-126.

Google Scholar