Effect of Inserting an Intervening Layer on Φb Reduction in TiN Schottky

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Abstract:

This report describes the application of titanium nitride (TiN) with a silicon nitride (SiN) intervening layer as a Schottky electrode in a Schottky barrier diode (SBD) made of 4H-silicon carbide (SiC). This reduced the Schottky barrier height (Φb) to 0.74eV at room temperature, and it was confirmed that the reduction in Φb was due not only to the application of TiN but also to the intervening layer containing SiN at the SiC/TiN interface. Furthermore, TiN with SiN was applied to a device as a Schottky electrode, and the electric field reduction effect was verified by changing the high energy implantation and JBS width. As a result, the forward voltage (Vf) was found to be reduced by a maximum of 0.23 V while suppressing leakage current. The reason for describing the interlayer as “intervening layer containing SiN” is that there may be other substances besides SiN.

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Materials Science Forum (Volume 1159)

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81-86

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September 2025

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[1] K. Tanihira, Y. Hori, Y. Yamamoto, Y. Adachi, T. Ogata, S. Asaba, M. Kobayashi, H. Kono, H. Hayakawa, A. Tsuyuguchi and G. Tchouangue, Improving the VF-IR trade-off in 650-V/1200-V SiC SBD by development of Schottky metal and optimization of device structure, in: PCIM Europe 2022; International Exhibition and Conference for Power Electronics, Intelligent Motion, Renewable Energy and Energy Management, Nuremberg, Germany, 2022, pp.1-6.

DOI: 10.1541/ieejias.144.nl10_4

Google Scholar

[2] L. Stöber, J.P. Konrath, F. Patocka, M. Schneider and U. Schmid, Controlling 4H–SiC Schottky barriers by molybdenum and molybdenum nitride as contact materials, IEEE Trans. Electron Dev. 63 (2016) 578-583.

DOI: 10.1109/ted.2015.2504604

Google Scholar

[3] M. Yoshitake, Examination of work function of transition metal carbides and nitrides, J. Vac. Soc. Jpn. 55 (2012) 349-353.

DOI: 10.3131/jvsj2.55.349

Google Scholar

[4] H.B. Michaelson, The work function of the elements and its periodicity, J. Appl. Phys. 48 (1977) 4729-4733.

DOI: 10.1063/1.323539

Google Scholar

[5] D. Connelly, C. Faulkner, PA. Clifton and D.E. Grupp, Fermi-level depinning for low-barrier Schottky source/drain transistors, Appl. Phys. Lett. 88 (2006) 012105.

DOI: 10.1063/1.2159096

Google Scholar

[6] A. Itoh, T. Kimoto and H. Matsunami, High performance of high-voltage 4H-SiC Schottky barrier diodes, IEEE Electron Dev. Lett. 16 (1995) 280-282.

DOI: 10.1109/55.790735

Google Scholar

[7] M. Yoshitake, How work function is determined, modified and applied for band alignment, Surf. Sci. 29 (2008) 64-69.

DOI: 10.1380/jsssj.29.64

Google Scholar