Materials Science Forum Vol. 879

Abstract: The duplex stainless steels (UNS S32304) after solid solution annealing at two different temperature (1323K and 1573K) were subjected to the same cold rolling with ε =3 and subsequent annealing for 230 min at 1323 K . The corresponding interface character distribution (ICD) were determined by electron backscatter diffraction (EBSD). The results show that a larger population of phase boundaries (PB) having K-S orientation relationship (OR) between the neighboring δ and γ grains was introduced and therefore higher intergrannular corrosion resistance (ICR) were resulted in the specimen initially solid-solution annealed at 1573K.

Abstract: Texture evolution in two magnesium alloys, Mg-4%Zn-1%Nd and Mg-1%Zn-1%Nd (weight percentage), was studied after rolling and the subsequent isothermal annealing. The finish rolling was completed in a single pass with a thickness reduction rate of ~30% at 100 °C and a rolling speed of 1000 m/min. After cooling to room temperature, the rolled samples were annealed at 350 °C for different annealing times. Upon annealing, the maximum intensity of the basal pole texture decreases as recrystallization progresses. In the Mg-1Zn-1Nd alloy (with a high Nd/Zn ratio), texture weakening is maintained even after complete recrystallization and grain coarsening, while in the Mg-4Zn-1Nd alloy, texture strengthening occurs after grain coarsening, and a single peak replaces the double split basal peaks. In the Mg-1Zn-1Nd alloy, grain coarsening is accompanied by a bimodal grain size distribution, whereas in the Mg-4Zn-1Nd alloy, the grain coarsening leads to a uniform grain size distribution. TEM investigations show the formation of the Zn and Nd rich clusters at early stage of annealing in both alloys. During recrystallization, these clusters were dissolved in the Mg-4Zn-1Nd alloy, but they are more stable in the Mg-1Zn-1Nd alloy. In our opinion, the formation of these stable clusters is one of the main factors for texture weakening of the Mg-Zn-RE alloys.

Abstract: Microstructural evolution in a 9Cr-3Co-3W-0.2V-0.06Nb-0.05N-0.005B steel crept at T=650°C under an applied stress of 140 MPa up to strains of 1, 3, 5.75 and 12%, which represent primary, secondary and tertiary creep stages and rupture, respectively, was studied. The steel was initially normalized from 1050°C, and finally tempered at 750°C for 3h. After tempering the boundaries of tempered martensite lath structure (TMLS) were decorated by M₂₃C₆ carbides, M₆C carbides and Laves phase particles. The 3% W additives provide the narrow size distribution of the boundary particles excepting M₆C carbides. The depletion of thermodynamically none-equilibrium content of W from the solid solution during creep leads to following events. (i) Continuous precipitation of small Laves phase particles occurs during all creep stages and results in the formation of bimodal size distribution. As a result, the average size of Laves phase particles remains unchanged during creep. (ii) Coarsening of M₂₃C₆ carbides starts to occur only at the transition to tertiary creep. (iii) Transformation of laths to subgrains followed by their growth is observed during all stages of creep. The density of particle located at lath/subgrain boundaries decreases from 5.6 to 2.6 μm^-1 during creep up to rupture. However, no full transformation of TMLS into subgrain structure has been revealed.

Abstract: Thermoplastic polymer matrix composites with continuous carbon fibre reinforcements are of crucial relevance in automotive industry. The mix of high performance and cost effective manufacturing makes them attractive for high volume production. However, it could be shown that production integrated end of line quality control is of strong importance to ensure continuous and traceable part quality. Besides, typical non destructive testing method specifications, higher production volumes additionally require short testing times. Herein, the application of active thermography as end of line quality control in composite production is evaluated and compared with results obtained by X-ray radiometry. It could be revealed that transient pulse phase thermography is a powerful tool to analyse part quality of continuous thermoplastic polymer matrix composites in short testing times.

Abstract: The occurrence of size effects in cobalt was examined by the analysis of mechanical properties of samples with thickness t, in a large range of grain size d giving a number of grains across the thickness t/d. On Hall-Petch plots, from the very beginning of plastic strain, two linear behaviors are notable: the polycrystalline one for higher t/d and the multicrystalline one for lower t/d in which the flow stress is strongly reduced. (t/d)_c is the threshold value between the two behaviors taking a value of around 14. This high value is directly linked to the low stacking fault energy of cobalt. The microstructure of the polycrystalline samples exhibits a strong basal texture and a small proportion of a secondary face-centered cubic phase in a hexagonal close-packed main phase was evidenced. TEM analysis enables to characterize the dislocations and the stacking faults present in the two phases. To complete the analysis, two plasticity stages can be distinguished: stage A corresponding to dislocations gliding and stage B driven by twinning. Size effects in cobalt are found to occur during gliding process and could be related to surface effects as previously shown in face-centered cubic metals.

Abstract: The recovery of precious metals is necessary for environmental and economic reasons. Spent catalysts from automotive industry containing precious metals are very attractive recyclable material because as the devices. they have to be periodically renovated and eventually replaced. Among automotive catalysts withdrawn from use, these with metallic carrier constitute quite a big group. Metallic carriers are usually obtained from steel FeCrAl , which is covered by a layer of PGM acting as a catalyst. World literature describes a number of pyro-or hydrometallurgical methods used for recovery of platinum from used automobile catalytic converters. However, all methods, available in the literature, are used to recover platinum from ceramic carrier. This paper presents the new method of removing platinum from the spent catalytic converters applying lead as a collector metal in a device used to wash out platinum by using mangetohydrodynamic pump. The article includes the description of the methods used in modelling magnetohydrodynamic phenomena (coupled analysis of the electromagnetic, temperature and flow fields) occurring in this particular device for this kind of waste. The general phenomena and ways of coupling the various physical fields for this type of calculation have also been described. The basic computational techniques with a discussion of their advantages and disadvantages have been presented.

Abstract: Rotary friction welding (RFW) was used in the current study to join the dissimilar metals AA7020-T6 aluminium alloy and 316L steel. Neutron diffraction was performed to investigate the texture gradient around the weld line and to map the residual stress over the whole specimen. The texture analysis showed a weak shear component near the bond line of AA7020-T6-T6 side which indicated a plastic deformation of AA7020-T6 during welding. The shear bands were also observed in optical microstructures. Relatively high tensile residual stresses were observed near the bond line on the AA7020-T6 side, which were in-homogeneously distributed from the perimeter to the rod centre, while high compressive residual stresses were found in the sample centre at the bond line in the 316L steel.

Abstract: Residual stress measurements were successfully performed on the representative IN718 fatigue specimens by X-Ray Diffraction. All surface residual stresses were found to be compressive. A stress gradient normal to the surface was observed on all specimens. The residual stresses tended to become less compressive with increasing depth into the parts. Residual stress measurement is the special requirement for NADCAP CRITERIA AC 7101/7. In this paper, residual stress measurements were successfully performed on two IN718 low cycle fatigue test specimens.

Abstract: As late as fifteen years ago the intracardiac catheter was only used for diagnostic purposes. Since then it has also been established as a therapeutic method. The latest studies have shown that the reduction in convalescence that normally follows a catheter-interventional implantation of aortic valves by transcatheter aortic valve implantation is less significant in comparison to that of a cardiac surgery operation. It is expected that such minimal-invasive technologies will grow to a great extent, also helping to reduce socio-economic costs for the European health care system. Patients of higher ages with acquired cardiac defects or children with congenital cardiac defects of heart valves, especially of the pulmonary valve, are currently the main target groups. We present an alternative and optimized mechanism for stent placement and similar therapeutical interventions. This project focuses on the manipulation unit and tube system. It carries out a highly precise and repeatable linear motion. Ergonomic requirements are taken into account. Furthermore a possibility to support the linear motion by minimal strain is presented. The product is designed for disposable applications but is generally also suitable for long-term applications.

Abstract: The various technologically important properties of metallic glasses are intimately connected to their amorphous structure that lacks the archetypical structural defects of polycrystalline metals and alloys, i.e. dislocations and grain boundaries. However, the amorphous structure also limits the application potential of this class of materials because of a macroscopically brittle behavior and size limitations. Consequently, with some exceptions, at least one dimension for technological products is limited to a few millimeters or even less. With the presented technological approach this drawback will be addressed. Our first results on several alloys show that with a dedicated instrumentation amorphous granulates can be successfully produced. By hot pressing in the supercooled liquid region, these granulates can be compacted into bulk shapes in the cm range. Further, due to the low viscosity of the supercooled liquid state, this technology disposes of a high formability. It is demonstrated that not only compact samples but also complex shapes in near net shape geometry can be produced. Results on the mechanical properties and microstructure will be discussed and related to important processing issues. Even though this technological approach does not directly address the second drawback of bulk metallic glasses, i.e. catastrophic failure due to highly localized shear bands, it is believed that this route offers possible pathways to improve this issue as well and, most important, to offer a technological route for implementing bulk metallic glasses into products of rather arbitrary shape and larger size.