Materials Science Forum Vol. 879

Abstract: Structural adhesives methods for joining multi material sheets have been focus of studies and researches for the last years. The most common and widely known type of test is the tensile test of single lap joints (SLJ). However, there are opportunities for analyzing the mechanical performance of such method in SLJ with materials of different properties, such as ductile structural aluminum alloys and high strength steels. It’s also known that the stress state of SLJ, when stressed longitudinally, generates secondary forces. One of them is known as cleavage force which initially leads to the failure of bonded joints. The aim of this work is to analyze the stress state of similar and dissimilar materials SLJ submitted to tensile stresses and also the influence of some variables, such as overlap length, adhesive film thickness and adherend yield limit, over the stress strength of the samples. As adherend materials it was selected the structural aluminum alloy AA 5083 H111 and the high strength steel DP600. At the end of this work it is expected to understand the proper stress state of the SLJ when using similar and dissimilar materials, identifying stress concentrators that bring the structure to fail, using the Digital Image Correlation (DIC) method. It was discovered that the yield strength associated with the overlap length highly influences the SLJ strength, by leading it to a close to pure adhesive shear stress state.

Abstract: The conventional sheet metal forming processes, such as deep drawing and stretch forming, are used to produce large batches of parts, however they incur in higher initial manufacturing costs attributed to the use of a large amount of tooling. The application of conventional and incremental forming processes combined in the same metal sheet is called hybrid forming. This hybrid process is enacted by pre-forming the sheet through the stretch forming process followed by the final manufacture using the incremental process. The objective of this work is to analyze the influence of the pre-strain imposed during the conventional process on the DC04 steel relative to the maximum strain obtained. A numerical simulation was used to define the parameters for the conventional process and to evaluate the experimental results. The higher major true strains are inversely proportional to the pre-strain in both experimental and simulated results.

Abstract: Fatigue crack propagation has been measured in flow formed Inconel 718 (IN718). Test pieces were extracted from a flow formed tubular structure in the longitudinal direction, retaining the tube curvature across their width. Crack growth rates (da/dN) were measured at 20, 300, and 400oC. For comparison, tests were repeated on specimens with an identical geometry but machined from conventionally forged IN718. Detailed metallurgy of the flow formed material is presented.

Abstract: The mechanical properties of Al alloys are strongly affected by their microstructure: the size and shape of precipitates, their homogeneous distribution and their coherency with the matrix are of primary importance for an effective strengthening of the alloys at room and elevated temperatures. Physically-based models are powerful tools to predict the influence of the mentioned parameters on the mechanical properties of the alloy after age hardening, and also to predict the effect of high temperature service conditions on microstructure evolution. Scope of this work is to model the dimensional kinetic evolution of plate shaped precipitates of an Al-based alloy during aging and after different overaging times at elevated temperature, and use these results to estimate the alloy yield strength. The alloy strengthening response is due to three terms, linearly summed: the intrinsic strength of Aluminum, the contribution from solute in solid solution and the contribution arising from precipitates. The consistency of the model is verified with experimental data obtained from a 2014 Al alloy.

Abstract: High-pressure studies on thermoelectric materials allow the study of the relationship between structural, elastic, and electronic properties. The High Pressure Science and Engineering Center (HiPSEC) at UNLV performs interdisciplinary research on a wide variety of materials at high pressures. One such system, CrSi₂ is an indirect band gap semiconductor that has potential applications in solar cells.

Abstract: Laser-matter interaction is commonly described regarding three main factors: laser beam, materials and environment. Conversion of absorbed energy via collision process into heat is the most important effect that occurs during laser interaction. Short-pulsed laser beam induces fast transition from the overheated liquid to a mixture of vapor and drops which allows the ablation of micrometric layers. Specific patterns can then be achieved using scanning and automation technology also called laser texturing. New materials with specific properties such as endurance life and/or lower environmental impact attract emerging technologies such as thermal spraying. However, adhesive bond strengths have to be high enough to play a key role in surface properties. A clean surface to enhance mechanical interlocking is a key element. Mechanical and physico-chemical bond strength for thick coatings elaborated by thermal spray process can then be developed using laser. The aim of the present paper is to show the potential of such emerging treatments through new results using various thermal spray processes (thermal spraying as well as cold spraying). Metal or organic materials were investigated implementing various powders.

Abstract: Mg/Al hydrotalcite-like materials containing ceria were synthesized as catalysts precursors for the reaction of dry methane reforming. The nickel species were introduced into the catalytic systems via adsorption from aqueous solution of [Ni (EDTA)]^2- complexes for 4 and 24h and the effect of adsorption time on the catalytic properties of obtained materials was evaluated. The mixed nanooxides were obtained by thermal decomposition of hydrotalcite-like materials at 550°C for 4h and the catalysts were subsequently characterized by XRD, elemental analysis, H₂-TPR and low temperature N₂ sorption techniques. The adsorption duration of [Ni (EDTA)]^2- influenced the properties of the prepared materials, such as textural properties, nickel crystallite size, and thus their catalytic activity in the reaction of dry reforming of methane. The sample which underwent adsorption for 24h turned out to be the most active in DRM reaction. However, over this catalyst RWGS reaction was well developed, which caused the excess of CO in the products of the reaction and faster deactivation of the catalyst.

Abstract: Pultrusion is a composite manufacturing technique for processing continuous composite profiles with a constant cross section. In such system, energy and mass balances are used to model the thermal and kinetic behavior of the material during processing. This work aims to compare the results obtained in the recent literature, regarding thermal optimization of pultrusion. In the present analysis, an alternative thermal configuration has been suggested, with the objective of maximizing the mean degree of cure. A general-purpose FE software, ANSYS-CFX^®, has been used to perform a three-dimensional (3D) conductive heat transfer analysis. Several case studies were conducted where the degree of cure was analyzed for varying heating scenarios. Results have shown that it is possible to get a higher cure in less process time if the die is isolated from the environment.

Abstract: High temperature piezoelectric materials have numerous potential applications, including high temperature ultrasound NDT, MEMS, sensors, or actuators. However, conventional piezoelectric materials are unsuitable for operation above 400°C. Lithium niobate (LiNbO₃) is a promising candidate because of its very high Curie temperature (approximately 1210°C) and reasonable piezoelectric coefficients. However, the piezoelectric properties are not sufficiently understood, partly due to the difficulties in characterizing this behavior at high temperature. Degradation mechanisms well below the Curie temperature, suspected to include phase transformations, oxygen loss, and excessive ionic conductivity, further deteriorate this property. In order to better understand these physical mechanisms, electrochemical impedance spectroscopy (EIS) is used to characterize monocrystalline LiNbO₃ from room temperature to 500°C, with excitations from 20 Hz to 20 MHz. An equivalent circuit model analysis, including resonant frequencies, is developed to investigate the temperature dependence of the piezoelectric behavior, as well as the mechanical elasticity and damping. Numerical values extracted from this analysis allows for numerical simulations to model device behavior.

Abstract: Two grades of Fe-Cr-Ni-Al-Ti-Mo maraging steels, with a different titanium content, were investigated. Particular attention was given to the correlation between the precipitated phases and the yield strength. Synchrotron X-ray diffraction, small-angle neutron scattering and atom probe experiments were performed to determine the crystal structure, shape, size distribution, chemical composition, particle number density and volume fraction of precipitates. Both alloys show a strong increase in strength after an aging treatment, which is attributed to the co-precipitation of two different intermetallic phases. Strengthening by a single precipitation of β-Ni (Al,Ti) particles induces a saturation of yield strength around 1600 MPa above a volume fraction of 6 %. The improvement of yield strength is then obtained by introducing a nanoscale co-precipitation of η-Ni₃(Ti,Al) phase.