Materials Science Forum Vol. 879

Abstract: This study carried out a die soldering test using both H13 and 1045 steel to investigate the different performances of these two substrate materials with regard to die soldering. Aluminum alloys with various amounts of silicon (0, 4.5, and 9 wt.%) were used to investigate the action of silicon in the soldering reaction, with the 0 wt.% material being commercial pure aluminum. Aluminum alloy samples of varying Si content were melted and held at 680oC and both H13 and 1045 steel were dipped for two hours in the melt. After the dipping test, the specimens were air cooled and analyzed using SEM and EPMA. The reaction layer of the H13 steel and the aluminum alloys were composed of Al₃Fe (ɵ), Al₅Fe₂(η) and Al₈Fe₂Si (τ5) phase. The reaction layer between the 1045 steel and the aluminum melt was composed AlFe (ζ), Al₅Fe₂ (η), Al₃Fe (ɵ), and Al₈Fe₂Si (τ5). The reaction layer thickness with the H13 substrate increased with the Si content of the aluminum; it deceased with increased Si content with the 1045 steel substrate.

Abstract: The precipitation and dissolution behavior of niobium carbo-nitrides is of particular interest for many technical applications. Niobium-microalloyed high strength low alloy (HSLA) steels are widely used in civil construction, automobile and line pipe applications. These steels rely on thermomechanical processing. In this context, coupled processes like thin slab casting and thermomechanical rolling of microalloyed steel grades require most precise information on the precipitation state at the individual processing steps. Reasonable equations for the solubility product at thermal equilibrium can be taken from literature but kinetics is largely unknown. Conventional X-ray technology is not able to detect small volume fractions below 0.1% of nanoscale precipitates. Investigation of nanoscale niobium precipitates by transmission electron microscopy (TEM) analysis or chemical extraction methods is common practice. However, TEM suffers from statistical relevance and chemical extraction will not give information on particle distribution and orientation. Investigation by high energy synchrotron X-ray of about 100 keV offers statistical relevance as volumes of several cubic millimeters are regarded. This large reflecting sample volume allows to detect nanometer-sized particles and provides very high angular resolution leading to an exact determination of the reflection peaks. The wavelength of around 0.12 Å is able to analyze nanometer-sized particles. Due to the high energy of the applied synchrotron radiation, precipitation and dissolution reactions could be observed during thermal treatment inside a soaking furnace. The results establish this technology for analysis of nanoscale niobium carbo-nitride precipitates

Abstract: A semi-empirical approach to the modeling of the microstructural evolution during the hot rolling of austenite including grain growth, hardening and softening has been discussed in the frame of a generalized energetic expression for related structural processes. The current concept suggests the activation energy of iron self-diffusion in austenite and its dependence upon the chemical composition of the steel for prediction of the particular phenomena. Additionally, the precipitation sequences, the size distribution, Oswald ripening and interaction with softening are also included in the model of the microstructural evolution. The simulation results are reliable to the structural evolution of the low carbon steels microalloyed with Nb and Ti during hot rolling.

Abstract: Superplasticity is considered as a special state of the polycrystalline material plastically deformed at the low level of the stress with the retaining of the ultrafine-grained structure – structural superplasticity received at the previous stage or arised during hot deformation independently from the initial grain size – dynamic superplasticity. For realization of the dynamic superplasticity it has to substitute an initial structural condition of material another, allowed to realize a superplasticity. The mentioned above changes are caused by the conforms of the proper strain rates and structural (phase) transformations of the evolutionary type in the open nonequilibrium systems. It is proposed an approach applying to the modelling of the deformation processes at the superplastic flow of commercial aluminum alloys taking into account the boundary regions in the framework the theory of self-organization of dissipative structures. An examples of the theoretical and experimental data correlation are given.

Abstract: The oxygen permeability of polycrystalline α-alumina wafers, which served as model alumina scales formed on heat-resistant alloys, was evaluated at a temperature of 1873 K. Mass transfer along grain boundaries (GBs) in an alumina wafer exposed to a large oxygen potential gradient (dμ_O), where both oxygen and aluminum mutually diffuse along GBs, was analyzed using ¹⁸O₂ and SIMS. ¹⁸O was concentrated at GB ridges on the high oxygen partial pressure (P_O2(hi)) surface and along the GBs near the P_O2(hi) surface. ¹⁸O adsorbed on the surface diffused almost immediately to surface GBs, resulting in the formation of new alumina by reaction with aluminum diffusing outward along the GBs. Oxygen GB diffusion coefficients in the vicinity of the P_O2(hi) surface were determined from the ¹⁸O depth profile along each GB for the ¹⁸O map of the cross section of the exposed alumina wafer. The oxygen GB diffusion coefficients were comparable to the values calculated from the oxygen permeability constants assuming an electronic conductivity and were obviously lower than those of oxygen GB self-diffusion without an oxygen potential gradient.

Abstract: Axial suspension plasma spraying (ASPS) is a relatively new, innovative spraying technique which has produced thermal barrier coatings (TBCs) with attractive properties such as high durability and low thermal conductivity. Using a suspension, it is possible to spray with finer powder particles resulting in coatings that have a columnar microstructure and contain a wide range of pore sizes, both nm-and μm-sized pores. To optimize the thermal properties and to maintain them during service of the components, it will be important to design TBCs with optimal porosity. Hence, an important part in the assessment of ASPS coatings is therefore the characterization of the microstructure and how it is build up, and the determination of porosity. Both aspects are addressed by performing measurement on splats and ASPS-coating using electron backscatter diffraction (EBSD) technique and by measuring porosity by Mercury Intrusion Porosimetry (MIP).

Abstract: Additive technologies are replacing the conventional methods of casting and subsequent time-consuming machining because of its high productivity. Resent engineering development in the field of additive manufacturing allows increasing assortment of useful powder materials. Technology of high-speed direct laser deposition (HSDLD) is a one of most perspective new technologies. It allows realizing heterophase process during the manufacturing, which there is process of partial melting of used powder is realized. The product is formed from a metal powder, which is supplied by compressed gas-powder jet directly into the laser action zone, wherein the jet can be as coaxial and as non-coaxial. Ni-based alloys found their application in many industrial areas, mostly there are used engine systems, aircraft and shipbuilding, aeronautics. The unique combination of operational characteristics depending on the type of alloy makes them promising materials. Heating and cooling rates during direct laser deposition determine structure and affect on its properties. Research is focused on structure and phase formation within technological process of HSDLD for Ni-base superalloys. Mechanical tests were carried out on the static tensile test, microhardness was measured. Based on research results the high-speed direct laser deposition technology could be used for manufacturing of products from different Ni-based alloys without subsequent heat treatment.

Abstract: In the cold spray process, solid particles impact on a surface with high kinetic energy, deform plastically and form a coating. This enables the formation of pure and dense coating structures. Even more, coating performance and deposition efficiency can be improved by assisting the process with a laser. Laser-assisted cold spraying (LACS) has shown its potential to improve coating properties compared with traditional cold spraying. In this study, coating quality improvement was obtained by using a co-axial laser spray (COLA) process which offers a new, cost-effective laser-assisted cold spray technique, for high-quality deposition and repair. In the COLA process, the sprayed surface is laser heated while particles hit the surface. This assists the better bonding between particles and substrate and leads to the formation of tight coating structures. This study focuses on the evaluation of the microstructural characteristics and mechanical properties (e.g., hardness and bond strength) of LACS metallic coatings.

Abstract: Twelve experimental steels with a base composition 1.5wt% Mn, 0.01 wt% V and 0.1 wt% Nb and varying C (0.05, 010 and 0.20 wt%), Ti (20 – 260 ppm) and B (0 – 100 ppm) contents have been systematically examined to quantify the effects of composition on precipitation behavio-ur and hot ductility during simulated continuous casting conditions. Nb-rich precipitates were present in the alloys with 0.10 wt-% C and 0.20 wt-% C. Alloys with 0.05, 010 and 0.20wt% C contained 50 – 100 nm size Ti-Nb carbonitrides. Boron was bound in 20 – 100 nm size boronitrides located in prior austenite grain boundaries. A Gleeble 3800 was used to study hot ductility and strain induced precipitation processes in the alloys. Alloys without B and Ti additions exhibited poor hot ductility at 850°C and 950°C, whereas the 0.05 wt-% C and 0.10 wt-% C alloys showed improved hot ductility (reduction in area 40-50%) by the addition of either >50 ppm B or 250 ppm Ti. The 0.2 wt-% C alloys showed no improvement from B or Ti additions. Examination of fracture surfaces of hot ductility specimens showed that boronitrides were located at prior austenite grain boundaries in alloys containing 80 – 100 ppm of B. Compression-relaxation tests showed that alloying with boron caused a noticeable decrease of the start temperature of strain-induced precipitation in the alloys.

Abstract: Additive manufacturing (AM) is becoming one of the most discussed modern technologies. Significant achievements of the AM in metals today are mainly connected to the unprecedented freedom of component shapes this technology allows. But full potential of these methods lies in the development of new materials designed to be used specifically with AM. Proper understanding of the AM process will open up new possibilities, where material and component properties can be specifically tailored by controlling the parameters throughout the whole manufacturing process. Present paper discusses the issues related to the beam melting technologies AM and electron beam welding (EBW). We are speaking of new direction in material science that can be termed “non-stationary metallurgy”, using the examples from material and process development for EBW, electron beam melting (EBM^®) and other additive manufacturing methods.