Materials Science Forum Vol. 879

Abstract: The thermal conductivities of quaternary Mg-Zn-Ca-MM alloys have been investigated by evaluating the effect of MM on Mg-4Zn-0.5Ca alloys, with an emphasis to develop a new Mg alloy without compromising thermal conductivity, process-ability and mechanical property. As a result, the thermal conductivity of 0.5 wt.% MM-added Mg-Zn-Ca alloy was almost same as that of MM-free Mg-Zn-Ca alloy. However, with further increasing MM contents, thermal conductivities of MM-added alloys decreased. The tensile yield strength was improved with increasing MM contents. In addition, the average spiral flow lengths of Mg-Zn-Ca-xMM alloys were almost same levels with Mg-Zn-Ca alloy.

Abstract: Steady state and non-steady state thermo-mechanical fatigue failure is great concern in this work. At first steady state thermo-mechanical fatigue failure behavior was investigated using the round-bar TBC specimens, after getting basic data of mechanical properties of the bond/top coats and the substrate alloy. The failure behavior was compared with that during isothermal low cycle fatigue (LCF). Next non-steady state TMF tests were carried out in which non-steady state thermal stress was significant in the TBC specimen, compared with the properties under the steady state TMF. The experimental work clearly demonstrated that the TMF failure lives were significantly changed depending on the temperature regime during TMF and LCF. Of particular importance was found in the non-steady state TMF tests. The non-steady state TMF cycling promoted the delamination of ceramic top coat, resulting in a significant reduction in fatigue life.

Abstract: Surface hydrophilicity is considered to have a strong influence on the biological reactions of bone-substituting materials. However, the influence of a hydrophilic or hydrophobic surface on the osteoconductivity is not completely clear. In this study, we produced super-hydrophilic and hydrophobic surface on Ti-and Zr-alloys. Hydrothermal treatment at 180 ^oC for 180 min. in the distilled water and immersion in x5 PBS(-) brought the super-hydrophilic surface (water contact angle < 10 (deg.)) and heat treatment of as-hydrothermaled the hydrophobic surface. The osteoconductivity of the surface treated samples with several water contact angle was evaluated by in vivo testing. The surface properties, especially water contact angle, strongly affected the osteoconductivity and protein adsorbability, and not the surface substance.

Abstract: A Nb alloyed low carbon steel was processed by hot equal channel angular extrusion (ECAE) and following transformation. The workpieces were heated up to the 960°C in the furnace for 10 min within the container block. Before extrusion, the die was preheated to 400oC. The workpiece was cooled in the die after ECAE process. 1 pass and 2 pass via route C were conducted at a speed of 32mm/s, the inter-pass time is about 2 sec. The sample of average ferrite grain size of about 2μm, a tensile strength of 800MPa, a total elongation about 20% is produced after 2 pass ECAE processed and subsequent cooling.

Abstract: The microstructure and mechanical properties of a joint produced by laser brazing between A5052 and AZ31 with AZ61, AZ91 and AZ125 filler metal was investigated. The effects of filler metals on joint characteristics are also discussed. Measurement of microstructural factors in the laser brazed joint revealed that increasing the laser power results in a decrease in the weld toe angle and an increase in the bead width, which indicates superior wettability. A high strength laser brazed joint can be achieved through the combination of good wettability and a thin intermetallic layer produced by a laser power of 590 W in a brazed joint with AZ125 filler metal Any further increase in power, however, results in a rapid increase in the thickness of the intermetallic compound (IMC) reaction layer. The superiority of the brazed joint with AZ125 filler metal is due to its lower melting point than that of AZ61 and AZ91 filler metal.

Abstract: The aim of this work is to study the precipitation mechanism of the intermetallic phases present in duplex stainless steels (UNS S32205 and UNS S32750), as well as to find out the most suitable method for detecting and analyzing accurately these secondary phases, particularly Sigma-phase, Chi-phase, nitrides and carbides. The samples were characterized after a solution annealing at 1080^oC followed by an isothermal treatment at 830^oC from 1 min to 9 h, with the purpose of figuring out the mechanism of chi-phase nucleation and nitrides formation in relation with the sigma-phase. The study has two main objectives: 1) to find out the most suitable technique for the detection, identification and quantification of the secondary phases, obtaining the best results with the combination of field emission scanning electron microscopy (FESEM) and backscattered electron detector (BSE) in comparison with the optical microscopy (MO); 2) to study the influence of the chemical composition on the nucleation mechanism of the intermetallic phases. It has been concluded that molybdenum balance content in chi-phase related to sigma phase is close to two, consequently the kinetics of nucleation and growth of these phases is remarkably faster when this alloying element content in the steel is higher. Chromium nitrides and carbides were also observed to precipitate as a result of the heat treatments carried out to the specimen wherein chromium nitrides role is a favorable site for the nucleation of sigma and chi phases.

Abstract: An integral computer model STAN 2000 designed for of-line simulation and control of hot rolling on mill 2000 of SEVERSTAL was developed. The capabilities of the model include the following features: ‒ calculations of power parameters for all stands of mill 2000 for a given rolling schedule; ‒ strip temperature calculations depending on selected rolling and accelerated cooling regimes; ‒ follow-up of steel microstructure evolution at all stages of strip production and prediction of ultimate mechanical properties (yield stress, ultimate tensile stress, relative elongation and toughness); ‒ optimization of rolling regimes for existing steel grades and developing them for a new one. The STAN 2000 program is written in С++ programming language and can work on all modern Microsoft Windows family operating systems. The program has a well-designed and user-friendly interface facilitating its practical use. The integral model was calibrated using an extensive data base on rolling regimes and forces, measured temperatures and final mechanical properties for a number of steel grades rolled on mill 2000 of SEVERSTAL with chemical compositions covering the following range of alloying elements content (mass.%): С(≤0.65); Mn(≤2.0); Si(≤1.0); Cr(≤0.9); Ni(≤0.6); Cu(≤0.5); Mo(≤0.4); Nb(≤0.05); V(≤0.065); Ti(≤0.06); B(≤0.003). The examples of STAN 2000 program use in practice of industrial hot strip production on mill 2000 of SEVERSTAL are presented and discussed.

Abstract: The microstructural evolution and its effect on biocompatibility of TNTZ through HPT processing were investigated systematically in this study. TNTZ_AHPT shows an enhanced mechanical biocompatibility, which is characterized by a higher tensile strength (1375 MPa) and hardness (450 HV) than those of TNTZ_ST, TNTZ_AT, and Ti64 ELI while maintaining a relatively low Young’s modulus. In this study, such microstructural refinement of TNTZ and its effect on electrochemical biocompatibility through HPT processing are investigated systematically in this study. The microstructure of TNTZ_AT consists of randomly distributed needle-like α precipitates in the equiaxed β grains with a diameter of approximately 40 m. The microstructure of TNTZ_AHPT consists of nanograined (NG) elongated β grains that have subgrains of non-uniform morphologies resulting from distortion by severe torsional deformation. Furthermore, the β grains and subgrains are surrounded by non-equilibrium grain boundaries. The needle-like α precipitates are completely refined to a nanograined. TNTZ_AHPT exhibits an enhanced combination of excellent corrosion performance and improved cellular response compared to TNTZ_ST, TNTZ_AT, and Ti64 ELI.

Abstract: The main aim of this study is to analyze the effect of the severe plastic deformation (SPD) on the mechanical properties and defect structure of metastable beta Ti alloys. Experiments were performed on two different β-Ti alloys: Ti-15Mo and Ti-6.8Mo-4.5Fe-1.5Al which were subjected to severe plastic deformation (SPD) by high pressure torsion (HPT). The increase of hardness with increasing equivalent strain was determined by microhardness mapping. Dislocation density was studied by advanced techniques of positron annihilation spectroscopy (PAS). Microhardness and dislocation density increases with increasing equivalent strain inserted by severe plastic deformation.

Abstract: In this paper investigation results of behavior of promising superelastic alloys of Ti-Nb-Zr system in blood-vessel are presented. The possibility of their use in manufacturing of medical stents is examined. Based on analytical review of present scientific papers, four different alloys of Ti-Nb-Zr system are taken in consideration. A finite element modelling of stent behavior during delivery and opening stages is considered. These processes are done for two typical stent geometries and four alloys possessing different mechanical properties. Finite modelling results are analyzed to show the distribution of internal stresses, mechanical aspects of stent installation and effectiveness of various configurations to widen the narrowed vessel. Modeling has allowed to formulate recommendations for optimal mechanical characteristics of the superelastic alloy used for the manufacture of medical stents.