Materials Science Forum Vol. 879

Abstract: A one-dimensional model of an elasto-plastic theory of dislocation fields is developed to model planar dislocation core structures. This theory is based on the evolution of polar dislocation densities. The motion of dislocations is accounted for by a dislocation density transport equation where dislocation velocities derive from Peach-Koehler type driving forces. Initial narrow dislocation cores are shown to spread out by transport under their own internal stress field and no relaxed configuration is found. A restoring stress of the lattice is necessary to stop this infinite relaxation and it is derived from periodic sinusoidal energy of the crystal. When using the Peierls sinusoidal potential, a compact equilibrium core configuration corresponding to the Peierls analytical solution is obtained. The model is then extended to use generalized planar stacking fault energies as an input and is applied to the determination of properties of planar dislocation cores in crystalline materials. Dissociations of edge and screw dislocation cores in basal and prismatic planes of Zirconium are shown.

Abstract: Recrystallization is a major means for controlling the grain size of steel during hot deformation. Usually, small grain sizes deliver superior mechanical properties. To aid the grain size controlling effect of recrystallization, small precipitates of carbo-nitride particles can be utilized to hinder the movement of grain boundaries. Interestingly, these particles are not only effective during grain growth, but also during recrystallization. In the present work, a recently developed state-parameter based model is introduced that is capable of describing both, the individual processes of static recrystallization, dynamic and static recovery and precipitation as well as the mutual interaction of these mechanisms in the course of elevated temperature processing. The evolution of state parameters within the model is discussed and the simulation results are compared to experimental information. Within our approach, a vast amount of experimental data for microalloyed steel is reproduced on basis of a single set of input parameters

Abstract: The effect of metal salt coating process on the bond strength of the bonded interface of 5052 aluminum alloy and 316L stainless steel was investigated by SEM observations of interfacial microstructures and fractured surfaces. Aluminum alloy surfaces were coated by boiling in 5% aqueous solution of NaOH for 5 s and 98% formic acid and 99.7% acetic acid for 20 s and 20 s respectively. Bonding process was performed at bonding temperature of 733 ~ 773 K under a pressure of 20 MPa (bonding time of 900 s). From this study, it is found out that the bonded strength of the joint increased with the rise in bonding temperature with or without metal salt coating process. However, it is understood that with metal salt coating process, high strength joint can be achieved with lesser deformation and lower bonding temperature. From the experimental results, it is found out that metal salt generation processing is effective at removing oxide film and substitution to a metal salt on the aluminum surface.

Abstract: We discuss the use of tension density for analyzing the electronic structure of a molecular system in a nonequilibrium steady state under the existence of electric current. By using the Rigged QED quantities defined at each point in space, such as tension density, local electric conductive properties are investigated. In particular, by computing benzenedithiol, it is numerically shown that the tension density serves as counter force to the Lorentz force density.

Abstract: Continuous solidification experiments were carried out with immiscible alloys under the effect of a direct current. The experimental results demonstrate that a direct current shows a significant effect on the migration of minority phase droplets (MPDs) in continuously solidified immiscible alloys. It can promote the formation of a well dispersed microstructure or a core/shell microstructure. A model describing the kinetics of the microstructure evolution in a continuously solidified immiscible alloy was developed. The microstructure formation in the alloys was calculated. The numerical results are in favorable agreement with the experimental ones. They demonstrate that a direct current may affect the microstructure development through changing the spatial motions of MPDs. The alloys show a well dispersed microstructure when they are solidified with such a direct current density that the direct current causing motion of the MPDs is almost equivalent to the radial component of the Marangoni migration velocity of the MPDs. The alloys show a core/shell microstructure when they are solidified with such a direct current density that the direct current causing motion of the MPDs dominates the migration of the MPDs along the radial direction of the sample. A wire or rod with well dispersed microstructure or a core/shell microstructure can be prepared by solidifying immiscible alloys under the effect of a direct current properly chosen.

Abstract: Titania and alumina photonic crystals were fabricated by using stereolithographic additive manufacturing to control electromagnetic waves in terahertz frequency. Micro ceramic patterns were designed spatially by graphic software. Photosensitive liquid resin with ceramic particles were spread onto a grass substrate by mechanical knife edge, and two dimensional (2D) images were drawn using fine pattern exposing to create a cross sectional solid layer. After stacking these layers, the obtained three dimensional (3D) structures of composite precursors are dewaxed and sintered.

Abstract: Manganese-rich austenitic twinning-induced plasticity (TWIP) steels with high strength and superior ductility have received much attention in the past two decades. Tremendous efforts have been made to explore their unusual hardening behaviour which includes contributions from twins, dislocations, grain boundaries and solid solution. Nevertheless, the individual hardening effects of twins, dislocations, grain boundaries and solid solution on the high strength of TWIP steels are still unclear. In the present work, the flow stress of a TWIP steel was experimentally decomposed into the respective contributions of twins, dislocations, grain boundaries and solid solution. For the forest hardening, synchrotron X-ray diffraction experiments with line profile analysis were carried out to measure the dislocation density. It is found that the yield stress of the present TWIP steel is controlled by solid solution and grain boundary hardening, which contribute to 238.3 and 238.5 MPa, respectively. After yielding, the work-hardening rate is dominated by dislocation multiplication which accounts for up to 922 MPa at a true strain of 0.4, equal to about 60% of the flow stress. In comparison, twins contribute to only 118 MPa at the same true strain, equal to about 8% of the flow stress. In other words, twins have minor effect on the flow stress, in contrast to the current understandings in the literature.

Abstract: To develop high-performing extruded magnesium alloys, we had investigated the effect of zinc into Mg-5Gd-2Y-xZn-0.7Ca (x = 1, 2, 3, and 4) alloys. With increasing of zinc content up to 3 wt.%, the volume fraction of LPSO phases and strength increased, while the volume fraction of LPSO and strength rapidly decreased when zinc content was 4 wt.% in Mg-5Gd-2Y-xZn-0.7Ca alloys. Ignition temperature and corrosion rate were directly proportional to the increase of zinc content in this study. The optimum zinc content was 2 wt.% in Mg-5Gd-2Y-xZn-0.7Ca alloys and VWZO52207 alloy exhibited high strengths (TYS: 407 MPa and UTS: 424 MPa), adequate elongation (6.9 %), and high ignition temperature (934 ^oC).

Abstract: Superhydrophobic surfaces, with extremely high water contact angles (CAs) of more than 150° are of special interest due to their various anti-adhesive and self-cleaning properties. Recent studies demonstrate that the superhydrophobicity principally results from the presence of binary structures at both the micrometre and nanometre scales together with the low-energy wax-like materials on the surfaces. Materials with similar properties, to those of the lotus leaf structure are very useful in several areas, such as the aeronautical industry and civil engineering; so many methods have been developed to mimic the lotus leaf structure. Metals are very important and irreplaceable engineered materials in many industrial fields. An alternative method for enhancing superhydrophobicity on different metals is proposed. The method proceeds by coating the metallic surface with a superhydrophobic reactive such as dodecanoic acid being a common application its use in paints with eco-friendly properties. The goal of this study is to induce direct superhydrophobicity by a single step and coating process on prepared surfaces of pure commercial aluminium 99.9 wt %, pure commercial 99.9 wt % copper and stainless steel grade 316L (UNS S31603). The chemical reaction proceeds by etching the activated surface with lauric acid in ethanol solutions.

Abstract: Through many years, conventional material developments have emphasized on microstructural refinement and homogeneity. However, "nanoand Homogeneous "microstructures do not, usually, satisfy the need to be both strong and ductile, due to the plastic instability in the early stage of the deformation. As opposed to such a “nanoand homo-“microstructure design, we have proposed “Harmonic Structure” design. The harmonic structure has a heterogeneous microstructure consisting of bimodal grain size together with a controlled and specific topological distribution of fine and coarse grains. In other words, the harmonic structure is heterogeneous on micro-but homogeneous on macro-scales. In the present work, the harmonic structure design has been applied to SUS304L austenitic stainless steel via a ball milling process and a large size (50 mm in diameter) SPS sintering process. At a macro-scale, the harmonic structure SUS304Lcompacts exhibited significantly better combination of strength and ductility, under quasi-static tensile loadings, as compared to their homogeneous microstructure counterparts. High temperature tensile tests revealed that they also indicated high strength at elevated temperatures.