Solid State Phenomena
Vols. 131-133
Vols. 131-133
Solid State Phenomena
Vol. 130
Vol. 130
Solid State Phenomena
Vol. 129
Vol. 129
Solid State Phenomena
Vol. 128
Vol. 128
Solid State Phenomena
Vol. 127
Vol. 127
Solid State Phenomena
Vols. 124-126
Vols. 124-126
Solid State Phenomena
Vols. 121-123
Vols. 121-123
Solid State Phenomena
Vol. 120
Vol. 120
Solid State Phenomena
Vol. 119
Vol. 119
Solid State Phenomena
Vol. 118
Vol. 118
Solid State Phenomena
Vols. 116-117
Vols. 116-117
Solid State Phenomena
Vol. 115
Vol. 115
Solid State Phenomena
Vol. 114
Vol. 114
Solid State Phenomena Vols. 121-123
Paper Title Page
Abstract: Detailed investigations have been carried out [1,2] on the response of microparticles
and nanoparticles to lasers of various pulse durations and energies. A first principles model has
been developed that allows the prediction of all thermo-mechanical effects that will be generated
from any laser pulse, such as pressure generation and phase changes. This theoretical work also
predicts the thermo-mechanical effects transmitted to the surrounding transparent medium that
the nanoparticles are immersed in, such as water or a solid polymer. The use of short enough
pulses produces shock fronts in the surrounding medium. We calculate how short the laser pulse
must be as a function of nanoparticles properties. We also show that measurements of pressure
peaks in the medium can be used to determine the thermo-mechanical properties of the absorbing
nanoparticles, such as bulk modulus and thermal expansion coefficient. Because the
measurements can be made in the surrounding medium, they are easier to perform
experimentally. Using this approach on particles of decreasing size, measurements of the
pressure in the medium allow the determination of the size at which a nanoparticle is small
enough to deviate from its bulk behavior and manifest discrete atom, finite size effects. This
allows the prediction of how the thermo-mechanical properties of nanoparticles will change as
their size decreases.
1025
Abstract: Based on the higher order Cauchy-Born rule, a nanoscale finite deformation continuum
theory, which links interatomic potentials and atomic microstructure of carbon nanotubes to a
constitutive model, is presented for analysis of the mechanics of carbon nanotubes. By using of
Tersoff-Brenner potential with two sets of parameters, the energy and Young’s modulus of graphite
sheet and single-walled carbon nanotubes are studied based on the theory presented. The findings
are in good agreement with the existing experimental and theoretical results.
1029
Abstract: A computational model is proposed to analyze the nanoscale self-assembling
phenomenon of monolayers on heterogeneous surfaces. Morse potential is used to describe the pairpotential
between molecules or atoms. Minimization of free energy is used to regulate different
phases and lattices to form optimized heterogeneous structures of different sizes with periodical
patterns. A representative volume element (RVE) is first defined and an optimization algorithm is
developed to adjust the positions of particles in it to reduce its potential until global equilibrium is
reached. The pair-potential distribution in the monolayer and the substrate layers are studied. It is
interesting to observe that the pair-potential distribution in the substrate layers resumes uniformity
just a few layers away from the interfacial boundary.
1033
Abstract: We investigated the nucleation of SWNTs and the role of metallic catalyst using firstprinciples
calculations. To avoid dangling bonds a closed cap forms on a metal surface. 6 pentagonal
rings are introduced into the cap, which reduces the strain energy. A unique tube chirality then grows
from the cap, which is controlled by the metal lattice at the nucleation stage. We found that chirality
of nanotubes affects the bond energies, including dangling bonds, carbon-carbon bonds & carbonmetal
bonds.
1037
Abstract: A large area perfect aligned carbon nanotubes (CNTs) thin film was grown directly on a stainless steel substrates by a
low cost bias-assisted hot-filament chemical-vapor deposition (BA HF-CVD) technology. The CNT’s / stainless steel field
emission array (FEA) cathode (CNT’s/FEA) has been fabricated. The field electron emission behavior of the CNT’s/FEA cathode
was characterized in a vacuum condition, a high electron emission of about 10mA/cm2 at a low electric field of 4V/μm implies
the promising the application as a cathode of the flat panel display device, so further assembled this cathode in a kind of vacuum
device, and the possibility of the operation from a flat panel character (Pictures) display tube FCT has been tested initially.
1041
Abstract: In the present paper, the size and temperature effects on lattice distortion of
Ag and Pt nanoparticles have been investigated in terms of atomic mean bond length
using the molecular dynamics simulations and the modified analytic embedded atom
method. It is found that the lattice contraction ratio decreases linearly with the
reciprocal of the particle size. The average value of lattice contraction over the whole
system is larger than that of the experimental data, and the average value of lattice
contraction in the inner core has a better agreement with the experiment results. This
phenomenon is mainly resulted by inhomogeneous lattice distortion. The surface
distortion and the size effect on the inner core distortion are remarkable. As the grain
size increases to a certain degree, the inhomogeneous surface lattice distortion is
mainly localized to the outer shell with a thickness of 2-3 lattice parameters.
1045
Abstract: A molecular dynamics simulation study has been performed for a large-sized system
consisting of 106 liquid metal Al atoms to investigate the evolution characteristics of nano-clusters
formed during rapid solidification processes. The cluster-type index method (CTIM) has been
applied to describe the structural configurations of the basic clusters and nano-clusters. The results
show that the icosahedral clusters (12 0 12 0) and their combinations play a critical role in the
microstructural transitions. The nano-clusters are mainly formed by combining basic and medium
sized clusters through continuous evolution. Their structural configurations are different from the
multi-shell structures obtained by gaseous deposition, ionic spray, and so on. The central atoms of
basic clusters composing the nano-cluster are bonded with each other, some central atoms are
multi-bonded, and others single-bonded.
1049
Abstract: Molecular dynamics simulation of the solidification behavior of liquid nickel nanowires
has been carried out based on the embedded atom potential with different cooling rates. The
nanowires constructed with a face-centered cubic structure and a one-dimensional (1D) periodical
boundary condition along the wire axis direction. It is found that the final structure of Ni nanowires
strongly depend on the cooling rates during solidification from liquid. With decreasing cooling rates
the final structure of the nanowires varies from amorphous to crystalline via helical multi-shelled
structure.
1053
Abstract: The electrical properties of metallic carbon nanotubes (CNT) can rival, or even exceed, the best
metals known. It is a potential candidate for future on-chip interconnect, whose performance will be
dominant in the next generation integrated circuits. In this paper, a study on the modeling and simulation
techniques for the CNT interconnect network is carried out. The frequency-independent models of CNT
interconnects in terms of resistance, inductance and capacitance are summarized. A novel frequencydependent
circuit model is proposed for CNT for various high-frequency applications. Preliminary analysis
shows a good match between numerical simulations and the compact model. The proposed modeling and
simulation techniques for CNT interconnect network are expected to play an important role in the future
CNT nanotechnology applications.
1057
Abstract: Ab initio molecular dynamics simulations were carried out to study low-k/ultra low-k
dielectric systems comprising Cu/Ta/SiLK-like polymer. A study of the motion of single metal
atoms of Cu and Ta in the SiLK-like polymer showed that Cu atom motions are effected by jumps
between cavities inside the polymer and that Ta is more sluggish than Cu not only because of its
larger mass but also because of stronger affinity to the polymer. It was also found that crosslinking
of the polymer did not affect the motion of the metal atoms. Simulations of deposition showed that
a thin Ta diffusion barrier does not have good structural integrity to prevent Cu-diffusion when
directly deposited onto the SiLK; the barrier performance was greatly improved after introducing a
Si-based film between the Ta and SiLK.
1061