Materials Science Forum Vol. 879

Abstract: The simple-perovskite system Bi_1-xLa_xFeO₃ (BLFO) is one of mixed-oxide systems having the multiferroic BiFeO₃ as an end material, which shows the ferroelectric and antiferromagnetic orders in its ground state. Because of the paraelectric nature of LaFeO₃ as another end material, the ferroelectric-to-paraelectric state change can be expected to occur in the mixed-oxide system BLFO. The interesting feature of BLFO is that there are both the PbZrO₃-type and incommensurately modulated (IM) states in the intermediate La-content range between the ferroelectric-R3c and paraelectric-Pnma states. Although the detailed features of these two states have not been understood sufficiently, in this study, we focus on the IM state around x = 0.20, and have investigated the crystallographic features of prepared BLFO samples with 0.15 ≤ x ≤ 0.35, mainly by transmission electron microscopy. It was found that six kinds of superlattice reflections were, for instance, present in the reciprocal lattice of the state at 300 K for x = 0.20, in addition to fundamental reflections due to the cubic simple-perovskite structure. To understand the appearance of these superlattice reflections, we regarded the state as a modulated-structure state in this study. Concretely, the modulated structure was assumed to be characterized by the appearance of both the incommensurate wave with q_I = <1/(4+δ) 1/(4+δ) 0>_c and the commensurate wave with q_II = <1/4 0 0>_c in the normal-Imma structure. In addition, the appearance of the two modulation waves could also produce the superlattice reflections at the <1/4 1/4 1/4>_c-, <1/2 0 0>_c-, and <1/2 1/2 0>_c-type positions in the reciprocal lattice. From the comparison with the experimental data obtained in this study, our modulated-structure model seems to be appropriate for the IM state in the vicinity of the PbZrO₃-type/IM state boundary.

Abstract: Grain refinement is attracting attention as a strengthening method which does not depend on the alloying elements added to steels. Many reports have described the manufacturing methods and mechanical properties of ultra-fine grained steels. In ultra-fine grained steels, it is well known that yielding stress drastically increases in accordance with the Hall-Petch relationship, while uniform elongation significantly decreases. These tendencies imply that grain size affects not only yielding but also work-hardening behavior. However, the influence of grain size on work-hardening behavior has not been clearly understood. Therefore, in this study, we investigated the work-hardening behavior during tensile deformation of 12Cr stainless steel with various grain sizes. Grain refining was conducted by cold-rolling of annealed and quenched steel specimens, followed by recrystallization annealing. The grain size of the specimens decreased as the cold-rolling reduction rate increased. The minimum grain size obtained by this method was approximately 5 μm. With decreasing grain size, 0.2% proof stress increased and the strain which reached the plastic instability condition decreased. In the session, we report the dislocation accumulation behavior estimated by grain hardness and XRD and the dynamic recovery behavior assessed by the Kocks-Mecking model.

Abstract: Paper has been retracted. Welding parameters such as current intensity, voltage, number of passes can affect the mechanical properties of the weld. In this paper the effect of these parameters on structure and mechanical properties of welded A105 and A106 steels has been evaluated. According to the mechanical and microstructure test results, increasing in welding pass number causes reduction in grain size and increasing in average hardness of HAZ. Also inter-pass slag inclusion defect occurred in high number of passes.

Abstract: Traditionally, Mg-Gd alloys have been strengthened by dispersed precipitates. Several reports are available about Sc addition to Mg alloys for improving a creep resistance. In this research, aging behavior of Mg-Gd, Mg-Sc and Mg-Gd-Sc alloys including the same amount of solute elements were investigated to understand the effect of Sc on microstructures and mechanical properties during aging. Hardness measurement revealed that Sc addition delayed to form precipitate. Close inspection of TEM micrographs, β” phase formed at an initial stage of aging and β’ phase was observed at a peak-aged stage in Mg-Gd and Mg-Gd-Sc alloys. In Mg-Sc alloy, there is no evidence of precipitate formation during aging at 473K.

Abstract: Self-annealing behaviors of the electrodeposited silver films which preferentially orient in (001) and (111) directions were investigated by in situ EBSP analysis. In the (001)-oriented film, self-annealing starts in storage for a few hours at R. T. and is almost complete after storage for 6 h at R. T. (001)- and (212)-oriented recrystallized grains mainly nucleate, and (001)-oriented grains mainly grow up. In the (111)-oriented film, self-annealing starts in storage for 15 min at R. T. and is almost complete after storage for 1 h at R. T. (111)-, (001)- and (212)-oriented recrystallized grains mainly nucleate, and (111)-oriented grains mainly grow up. The size of recrystallized grains induced in the (111)-oriented film by self-annealing is approximately half that in the (001)-oriented film although the rate of recrystallization in the (111)-oriented film is faster than that in the (001)-oriented one. The area fraction of the preferential orientation after completion of recrystallization saturates in approximately 70% and 50% in the (001)- and (111)-oriented films, respectively.

Abstract: Influence of friction stir welding (FSW) on microstructure of an Al-4.57Mg-0.35Mn-0.2Sc-0.09Zr (wt. pct.) alloy was studied. Following parameters of FSW were used: the rotation speeds of 500, 650 and 800 rpm, the traverse speed of 75 mm/min and the tilt angle of 2.5°. Defect-free welds were obtained using all these parameters. FSW leads to the formation of fully recrystallized microstructures with average grain sizes less 2 μm and a moderate dislocation density of ~10¹³ m^–2 in the stir zone. No evidence for abnormal grain growth was found in the heat affected zone of the weld. The nanoscale Al₃(Sc,Zr) dispersoids coarsened to 21 nm but retained coherent interfaces and cube-cube orientation relationship with the matrix.

Abstract: Fe-based alloy modified layers were prepared on 304 stainless steels by high-energy pulse laser-like cold welding cladding technique. The microstructure, composition and phase constituents of the cladding layers were analyzed using SEM, EDS and XRD, respectively. The microhardness, friction-wear and cavitation erosion resistance were also investigated using microhardness tester, pin-on-disk wear-testing machine and ultrasonic vibrator. Experimental results showed that Fe-based alloy modified layer was mainly composed of α-Fe matrix phase and skeleton-like Cr₂₃C₆, Cr₇C₃ carbide reinforced phase, which was dispersively distributed into α-Fe matrix. The microhardness and friction coefficients of Fe-based alloy modified layer were 600HV and 0.4, respectively, indicating an improved wear resistance. The weight loss rate and average erosion depth of the modified layer was 1/5 and 1/10 that of 304 stainless steel in 3.5% NaCl solution after 5-h cavitation erosion test, respectively. The erosion crater depth of the modified layer was uniform, indicating that the cavitation erosion resistance of the modified layer was much better than that of the 304 stainless steel.

Abstract: Repetitive continuous extrusion forming was employed as a continuous severe plastic deformation route and both Al-Fe-Cu alloy and Al-Mg-Si alloy were involved. Evolution of microstructures and properties during this process is investigated by optical microscope, electron-backscatter diffraction, transmission electron microscope, and tensile testing. The results show that in the Al-Fe-Cu alloy an obvious mechanical softening and grain refinement were observed, while in the Al-Mg-Si alloy it shows a slightly rising in strength and ductility as the extrusion passes increasing.

Abstract: Stress serration patterns and kinematics of deformation bands associated with the Portevin-Le Chatelier (PLC) effect were examined for an Al–6%Mg–0.35%Mn–0.2%Sc–0.08%Zr–0.07%Cr (in wt.%) alloy with two grain sizes: 22 μm and 0.7 μm. The fine-grained structure of the alloy was obtained using equal-channel angular pressing (ECAP) at 320°C up to a total strain of ~12. Tensile tests were carried out at room temperature and strain rate ranging from 10^-5 s^-1 to 10^-2 s^-1. In addition, high-frequency local extensometry technique was applied to monitor the evolution of the axial strain distribution during deformation. Depending on the strain rate, conventional A, B, C, or mixed types of serrations were observed on the stress-strain curves. These types of behavior usually correspond to different kinematics of the PLC bands, including band propagation and localization. However, the propagation regime was found to dominate in the investigated alloy in the entire strain-rate range. This unusual behavior of deformation bands and their features depending on the grain size are discussed.

Abstract: Micro hydro deep drawing is a promising technology to fabricate micro metal products with complex 3D shapes. However, the size effects in the micro hydro deep drawing become considerable and significantly influence shape accuracy of drawn cups. In this study, a Voronoi micro scale simulation model was developed to consider the size effects of SUS304 foils. A surface layer model was additionally applied in the simulation to further explain the size effects. The micro hydro deep drawing experiments were conducted with annealed SUS304 foils and the drawn cups were examined. The wrinkling phenomenon was generally aggravated with the hydraulic pressure. Simulation results also show that the high hydraulic pressure does not improve the shape accuracy of the drawn cups as that in the normal scale hydro deep dawning process does. The simulation results are in accordance with the experimental results.