Materials Science Forum Vols. 654-656

Abstract: The purpose of this research is to investigate effect of rare-earth elements (Y and Dy) on industrial pure Mg through the ignition point test and oxide film analysis. The results show that the 0.5%Y can make the ignition point of pure magnesium about 30°C higher. However, the ignition point of pure magnesium can be multiplied about 50°C by the mixed additions of 0.5wt%Y and 5wt%Dy. The SEM analysis indicates the oxide film of Mg-0.5Y-5Dy is more compact and tenacious than that of Mg-0.5Y. The XRD analysis indicates that the oxide film of Mg-0.5Y-5Dy consists of MgO, Y2O3 and Dy2O3. The most of all the three oxides are Dy2O3, which can prevent magnesium from further oxidizing.

Abstract: This study aims to produce magnesium alloy strip with boss and rib directly from molten metal. Magnesium alloy is the lightest structural material, so it is expected to widely use for small electronic device and etc. We studied about melt drag process. Melt drag process is one of single roll strip casting process. We use model melt drag experimental device to produce rapid solidified magnesium strip with boss and rib. Substrate is used on model experimental device instead of roll to easily research shape of substrate. Diameter of boss is 5 mm, 7.5 mm and 10 mm. Height of boss is 6 mm. We revealed on this study that the experimental conditions to get good shape boss and rib, improvement substrate shape for good boss and rib, microstructure and etc.

Abstract: Grain refinement of titanium alloys during solidification is believed to have many benefits for processing and properties. Recent work has emphasized the importance of solute elements in grain refining cast titanium and it was demonstrated that the growth restriction factor is useful for predicting the grain refining effectiveness of solute elements in titanium. Despite oxygen being the major impurity element present in titanium alloys and having been previously identified as a theoretical growth restricting solute, its effect as a β-grain refiner is still unexplored. This paper investigates the effect of oxygen on the grain size in cast titanium alloys.

Abstract: The Lattice Monte Carlo (LMC) method recently developed by the authors is an unusually powerful and flexible method in which a given phenomenological thermal or mass transport problem is mapped onto a fine-grained lattice which is then analyzed with discrete random walk methods. We provide an overview of the LMC method. For mass diffusion we highlight the addressing of diffusion with reversible reaction. For thermal transport we highlight a calculation of the effective thermal conductivity of sintered hollow sphere structures making use of CT scans of actual material as well as the determination of temperature profiles in phase-change composites.

Abstract: Ni3Al based superalloy has recently been used for the single crystal gas turbine blade. The grain selection behavior in grain selector directly determines the casting’s final microstructure and properties. A mathematical model based on the modified CA-FD method was developed for the three-dimensional simulation of directional solidification process of Ni3Al based single crystal superalloy castings. The microstructure evolution was simulated with the modified Cellular Automaton method. The grain selection process in the grain selector and final microstructure of casting were simulated. The results indicate that the stray grain is easy to nucleate at the middle part of the pigtail because of the discontinuous mushy zones formation. This agrees with previous published experimental results. Based on simulated results, a newly designed grain selector with optimized geometry was proposed to avoid stray grains.

Abstract: The recrystallization behavior of cold-rolled, commercial-purity titanium was studied experimentally and with Monte-Carlo (MC) modeling. Utilization of EBSD-OIM as input for MC modeling resulted in realistic predictions of recrystallization kinetics, microstructure and texture, which were in good agreement with experimental results. MC modeling of recrystallization kinetics predicted that the non-uniform stored energy distribution, heterogeneous nucleation of recrystallization and recovery in combination leads to a negative deviation from linear JMAK kinetics. It was found that concurrent recovery that takes place during recrystallization is an important process that controls both the overall recrystallization kinetics and the deviation of linear JMAK kinetics. On the other hand, the non-uniformly distributed stored energy itself has little effect on the negative deviation from JMAK kinetics but intensifies the deviation when heterogeneous nucleation is combined. Modeling results also revealed that heterogeneous nucleation of recrystallized grains and their early impingement in local areas of high deformation are essential for producing a log-normal distribution of grain size and a typical recrystallization texture of rolled titanium.

Abstract: A computational model coupling electromagnetic stirring with a macroscopic heat and fluid flow in semisolid A357 alloy slurry preparation by A-EMS was developed. Effects of electromagnetic field on flow field and temperature field were presented successfully. It is shown that more intensive magnetic field, velocity field and thereby temperature field were uniformly distributed in the stirred melt even at commercial frequency, and thus more uniformly fine microstructures were obtained in comparison with normal EMS.

Abstract: Cluster Variation Method (CVM) has been widely recognized as one of the most reliable theoretical tools to study phase equilibria in metallic alloy systems. The conventional CVM, however, does not allow atomic local displacements and, therefore, calculated results often encounter various inconveniences such as the overestimation of transition temperatures. Continuous Displacement Cluster Variation Method (CDCVM) was proposed to circumvent such deficiencies of the conventional CVM. Preliminary studies on an order-disorder phase diagram based on CDCVM indicate that the transition temperature is shifted downward reproducing experimental tendencies. In the present study, lattice thermal vibration effects are also incorporated through Morse potential. It is concluded that the local lattice distortion effects are quite effective to reduce the transition temperature.

Abstract: This work addresses the numerical analysis of anisotropic composite structures for thermal energy storage and temperature stabilization. The basic idea of heat sink composites is the combination of metallic matrices for fast energy transfer with phase change materials for thermal energy storage. Anisotropic matrices, such as lotus-type structures, allow for increased control of the thermal energy flow, without the necessity of additional thermal insulation. As an example, thermal energy can be directed towards a surface cooled by convection and excess energy is stored in the phase-change material. Computed tomography data of copper lotus-type material is used for the generation of the numerical calculation models. Due to its particular meso-structure, this material is characterised by strongly anisotropic properties. The void space of this cellular metal is filled with the phase-change material paraffin in order to enhance the energy storage capacity. A recently extended Lattice Monte Carlo method is used to evaluate the anisotropic thermal properties of these promising materials.

Abstract: This study presents the simulation of evolution of Ni4Ti3 variants during stress-assisted aging of NiTi alloys containing nano-scale pores with different sizes, by using phase field approach. The simulation shows that the higher level of applied stress can cause more Ni4Ti3 particles precipitated around pores than that of lower level stress, regardless of pore size; the large pores can “capture” more precipitates while less particles precipitated around the small pores. Moreover, the precipitation of Ni4Ti3 particles exhibits different regional preferences near pores, which means the unixial compressive stress can result in inhomogeneous Ni4Ti3 particle distribution.