Materials Science Forum
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Vols. 638-642
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Materials Science Forum Vols. 638-642
Paper Title Page
Abstract: Tantalum-doped indium tin oxide films were deposited on glass substrate by co-sputtering with two-targets. Tantalum-doping strengthened the orientation of the (400) plane and resulted in better crystalline structure, larger grain size and lower surface roughness. Due to the better crystallizability of the tantalum-doping films, carrier concentration and the mobility were increased. Tantalum-doping revealed better optical–electrical properties. The environmental effects on electrical properties stability and long-term reliability of tantalum-doped films in NaCl, Na2SO4 and HCl solutions at 25°C were also investigated, which simulated corrosion behavior in marine, industrial and acidic environments. The relative resistance change (△R/R) for tantalum-doped films revealed that the films had the best electrical properties stability and long-term reliability in these aggressive environments. The pre-formation of a protective oxide layer on the surface of the films had an enhancing effect on the corrosion properties.
2897
Abstract: The evolution of phase composition and growth stresses in oxide scales growing on the polycrystalline Fe-15at.%Al alloy at 700°C in air was studied by in-situ synchrotron X-ray diffraction and X-ray photoelectron spectroscopy. The oxidation kinetics was determined by thermogravimetry. The results showed that, under these conditions, metastable -Al2O3 appears only during the first minutes of oxidation and the main oxides formed since the early oxidation are -Al2O3 and -Fe2O3. High volume fractions of -Fe2O3 caused accelerated oxidation rates in the first hours. -Al2O3 and -Fe2O3 grow epitaxially, evolving compressive and tensile growth stresses, respectively.
2903
Abstract: Thin films of CdTe semiconductors were prepared on sapphire single crystal and quartz glass substrates by a vacuum evaporation method. Crystallinity and photoluminescence properties of the obtained CdTe thin films on the substrates were semi-quantitatively compared concerning the difference of the substrate materials. Dependences of the properties on the substrate temperature in the preparations and indium doping to the thin films were also investigated.
2909
Abstract: Single crystalline a-axis Mg doped ZnO thin films (MgxZn1-xO) were successfully prepared by sol-gel spin coating method using Zinc acetate, Magnesium acetate as precursors with ethanol as a solvent. The prepared solutions were used to deposit the films on silicon (100) substrate for different mole concentrations (x = 0.1 to 0.33). All deposited films were annealed at 450 0C to get dense crystalline films. X-ray Diffractometer (XRD), Scanning Electron Microscopy (SEM) and Energy Dispersive Analysis by X-ray (EDAX), Fourier Transform Infrared Spectroscopy (FTIR), Ellipsometry and semiconductor characterization system with probe station were used to characterize the deposited films for structural, chemical, optical, mechanical and electrical properties. The intense absorption peak was observed in the IR spectra for all deposited films showing bond position of fundamental ZnO peak for all Mg mole concentrations. From the XRD spectra, it revealed that the deposited films were single crystalline and a-axis oriented. EDAX spectra clearly showed the peak of Mg along with Zn and O indicating the successful incorporation of Mg into the ZnO. The refractive index was successfully tailored from 1.6 to 1.11 corresponding to 0.1 to 0.33 Mg mole concentration. The refractive index was found to be decrease with an increase in Mg mole concentration. I-V characteristics shows decrease in current with increase in the Mg mole concentration. Significant effect was not observed on thickness of deposited films due to the varying Mg mole fraction. Through SEM image, it was noted that the uniform film of Mg doped ZnO was deposited on the silicon substrate. Our results explore the applicability of MgZnO as cladding layer material to form effective and efficient heterostructure with ZnO as an active layer for the optical wave-guide applications.
2915
Abstract: We have previously reported that -AlN crystallites with diameters of 0.5–1 µm were occasionally grown on sapphire(0001) by pulsed laser deposition, which implied that the migration mobility of the species deposited on the substrate surface might be an insufficient for the film growth of -AlN. In the present study, in order to enhance the crystal growth of -AlN, sapphire(0001) substrates with an atomically smoothness (step-sapphire) were employed. The growth conditions of - and -AlN extended to higher nitrogen-pressures, as compared to those using normal surface sapphire(0001) substrates (normal-sapphire). This is due to the enhancement in the mobility of the deposited species on the substrate surface.
2921
Abstract: Growth of ultrananocrystalline diamond (UNCD)/hydrogenated amorphous carbon (a-C:H) composite films without initial nucleation was realized by an coaxial arc plasma gun at a substrate-temperature of 550 °C and hydrogen-atmosphere of 53.3 Pa. The pulsed arc discharge was triggered at a repetition rate of 1 Hz. The deposition rate was 80 nm/min. X-ray diffraction measurements with 12-keV X-rays from synchrotron radiation indicated extremely broad rings from diamond and none from graphite. The UNCD crystallite diameters were estimated to be approximately 1.3 nanometers by using Scherrer’s equation. The sp3/(sp2+sp3) was estimated to be approximately 57% from the X-ray photoemission spectroscopy. The coaxial arc plasma gun is a new powerful method that might enable us to realize the supersaturated condition with highly energetic ions for the growth of UNCD.
2927
Abstract: The (Zr53Cu30Ni9Al8)99.5Si0.5 bulk metallic glass (BMG) rods, 3 mm in diameter, with different crystallization fraction for compression test were prepared by isothermal annealing the as-cast BMG rods at the temperature in the middle of supercooled temperature region for different time period in vacuum, respectively. The result of compression test revealed that the fracture strength of these samples increases with the crystallization ratio at the beginning, then decreases rapidly at 40 vol.% crystallization fraction. In addition, the best mechanical performance with 1970MPa yield strength and 3 % plastic strain occurs at the sample with 30 vol.% nanocrystalline phase (with an average size about 50 nm). This was suggested these homogeneous distributed nanocrystals which embedded in the matrix may act as obstacles to branch the primary shear band into multiple shear band and result in improving the ductility.
2933
Abstract: Thin Ni/Al and Ni/Ga layers of different atomic ratios were codeposited onto Si(001) at room temperature followed by subsequent annealing. Influence of annealing temperature on morphology and composition of ternary disilicide NiSi2-xAlx and NiSi2-xGax layers was investigated by transmission electron microscopy. Addition of Al or Ga leads to a decrease of the disilicide formation temperature from 700°C down to at least 500°C. Depending on the composition closed, uniformly oriented NiSi2-xAlx and NiSi2-xGax layers were observed after annealing at 900°C, whereas reaction of a pure Ni film with Si leads to the island formation with a mixture of A- and B-type orientations.
2938
Abstract: Intergranular exchange coupling between magnetic nano-grains is one of important parameters to develop magnetic recording media towards the areal density of 1000 Gbits/in2. In this presentation, various processings, involving oxide co-sputtering for perpendicular media, spontaneous phase separation for longitudinal media, and grain boundary (GB) diffusion derived from underlayer or overlayer to induce tunable exchange coupling, have been reviewed to tailor the exchange coupling, including their main principles, present achievements and engineering challenges. Much attention is paid to the physical origin of magnetically induced phase separation of Co-Cr-based alloy, which governs media noise and coercivity, and its applications to the longitudinal media. A proposal of GB diffusion is also highlighted in detail to show a feasibility to tailor the exchange coupling, including calculation results and experimental evidences.
2944
Abstract: Titanium and its conventional alloys reveal a high affinity for hydrogen, being capable to absorb up to 60 at.% hydrogen at 600°C, and even higher contents can be alloyed with titanium at lower temperatures. Hydrogen exhibits a low solubility in the low-temperature hexagonal closed-packed (hcp) α phase and a very high solubility (up to 50 at.%) in the high temperature body-centered cubic (bcc) β phase. The presence of hydrogen in the amount exceeding 200 ppm leads to formation of hydrides in α and α + β titanium alloys. While the aforementioned hydrogen behavior within bulk titanium has been well-established and reviewed, this is not the case with titanium thin films. The interpretation of results in these nanosized systems is complicated because the exact determination of the hydrogen concentration is difficult. However, using electrochemical hydrogen loading technique under the proper conditions, the hydrogen concentration can be accurately determined via Faraday’s law. In this study the thermodynamics of the titanium films during hydrogen absorption were investigated by electromotive force (EMF) measurements. Titanium films of different thicknesses were prepared on sapphire substrates in an UHV chamber with a base pressure of 10-8 mbar, using ion beam sputter deposition under Ar-atmosphere at the pressure of 1,5ּ10-4 mbar. The crystal structure was investigated by means of X-Ray diffraction using a Co-Kα radiation. For electrochemical hydrogen loading, the films were covered by a 30 nm thick layer of Pd in order to prevent oxidation and facilitate hydrogen absorption. The samples were step-by-step loaded with hydrogen by electrochemical charging, which was carried out in a mixed electrolyte of phosphoric acid and glycerin (1:2 in volume). An Ag/AgCl (sat.) and Pt wires were used as the reference and the counter electrode, respectively. XRD measurements were performed before and after hydrogenation in order to investigate the effect of hydrogen loading on the films microstructure. The role of varying thicknesses on the main characteristics of hydrogen's absorption behavior, as well as hydrogen-induced microstructural changes in titanium thin films, are discussed in detail.
2950